Metal-support interactions in designing noble metal-based catalysts for electrochemical CO_(2) reduction: Recent advances and future perspectives

作     者：Zhao Li Rui Wu Lei Zhao Pingbo Li Xinxin Wei Junjie Wang Jun Song Chen Tierui Zhang Zhao Li;Rui Wu;Lei Zhao;Pingbo Li;Xinxin Wei;Junjie Wang;Jun Song Chen;Tierui Zhang

作者机构：School of Materials and EnergyUniversity of Electronic Science and Technology of ChinaChengdu611731China Key Laboratory of Photochemical Conversion and Optoelectronic MaterialsTechnical Institute of Physics and ChemistryChinese Academy of SciencesBeijing100190China College of Chemistry and Chemical EngineeringChongqing University of TechnologyChongqing400054China 

基　　金：This work was financially supported by National Key Research and Development Program(No.2018YFB1502503)and Sichuan Science and Technology Program(No.2020YJ0299) 

出 版 物：《Nano Research》 (纳米研究（英文版）)

年 卷 期：2021年第14卷第11期

页      码：3795-3809页

摘      要：Electrochemical CO_(2) reduction reaction (CO_(2) RR) offers a practical solution to current global greenhouse effect by converting excessive CO_(2) into value-added chemicals or fuels. Noble metal-based nanomaterials have been considered as efficient catalysts for the CO_(2) RR owing to their high catalytic activity, long-term stability and superior selectivity to targeted products. On the other hand, they are usually loaded on different support materials in order to minimize their usage and maximize the utilization because of high price and limited reserve. The strong metal-support interaction (MSI) between the metal and substrate plays an important role in affecting the CO_(2) RR performance. In this review, we mainly focus on different types of support materials (e.g., oxides, carbons, ligands, alloys and metal carbides) interacting with noble metal as electrocatalysts for CO_(2) RR. Moreover, the positive effects about MSI for boosting the CO_(2) RR performance via regulating the adsorption strength, electronic structure, coordination environment and binding energy are presented. Lastly, emerging challenges and future opportunities on noble metal electrocatalysts with strong MSI are discussed.

主 题 词：electrochemical CO_(2)reduction metal-support interaction noble metal catalysts support materials 

学科分类：081704[081704] 07[理学] 070304[070304] 08[工学] 0817[工学-轻工类] 0703[理学-化学类] 

核心收录：

D　O　I：10.1007/s12274-021-3363-6

馆 藏 号：203102949...