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Protecting-Group-Free Total Synthesis of(-)-Pallambins A-D

Protecting-Group-Free Total Synthesis of(-)-Pallambins A-D

作     者:Xiwu Zhang Yuan Wang Peng Chen Xinxian Cai Yanxing Jia Xiwu Zhang;Yuan Wang;Peng Chen;Xinxian Cai;Yanxing Jia

作者机构:State Key Laboratory of Natural and Biomimetic DrugsSchool of Pharmaceutical SciencesPeking University38 Xueyuan RoadBeijing100191 China 

基  金:This research was supported by the National Natural Science Foundation of China(Nos.21925101 and 21572008) 

出 版 物:《Chinese Journal of Chemistry》 (中国化学(英文版))

年 卷 期:2021年第39卷第7期

页      码:1983-1996页

摘      要:Main observation and conclusion A full account of the total synthesis of(-)-pallambins A-D(1-6)is *** strategy was devised by simulating their biosynthetic *** left-part bicyclo[3.2.1]octane system of pallambins C and D was efficiently constructed via a palladium-catalyzed oxidative cyclization.

主 题 词:Terpenoids Total synthesis Enantioselectivity Protecting-Group-Free Natural products 

学科分类:081704[081704] 07[理学] 08[工学] 0817[工学-轻工类] 070303[070303] 0703[理学-化学类] 

核心收录:

D O I:10.1002/cjoc.202100001

馆 藏 号:203103621...

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