Improving the performance of metal-organic frameworks for thermo-catalytic CO_(2)conversion:Strategies and perspectives

作     者：Leiduan Hao Qineng Xia Qiang Zhang Justus Masa Zhenyu Sun 郝磊端;夏启能;张强;Justus Masa;孙振宇

作者机构：State Key Laboratory of Organic-Inorganic CompositesCollege of Chemical EngineeringBeijing University of Chemical TechnologyBeijing 100029China College of BiologicalChemical Science and EngineeringJiaxing UniversityJiaxing 314001ZhejiangChina Department of ChemistryWashington State UniversityPullman 99164United States Department of ChemistryKyambogo UniversityP.O.Box 1KyambogoKampalaUganda 

基　　金：国家自然科学基金(21972010,21972056) 北京市自然科学基金面上项目(2192039) 有机-无机复合材料国家重点实验室基金(oic-201901001) 

出 版 物：《Chinese Journal of Catalysis》 (催化学报（英文）)

年 卷 期：2021年第42卷第11期

页      码：1903-1920页

摘      要：Climate change caused by the increasing emission of CO_(2)to the atmosphere has become a global *** ameliorate this issue,converting CO_(2)into valuable chemicals is highly desirable,enabling a sustainable low-carbon *** this end,developing efficient catalytic systems for CO_(2)conversion has sparked intense interests from both academia and *** advantage of their highly porous structures and unique properties,metal−organic frameworks(MOFs)have shown great potential as heterogeneous catalysts for CO_(2)*** transformations involving CO_(2)have been accomplished over MOFs-based *** we provide a comprehensive and up-to-date review on recent advances of heterogeneous CO_(2)thermocatalysis using MOFs,highlighting relationships between structures and *** attention is given to the design strategies for improving the catalytic performance of *** available to enrich the catalytic active sites in MOF structures are stressed and their respective impacts on CO_(2)conversion efficiency are *** synergistic effects between each active site within the structure of MOFs and derivatives are *** the end,future perspectives and challenges in CO_(2)conversion by heterogeneous catalysis with MOFs are described.

主 题 词：CO_(2) conversion Metal-organic frameworks Catalytic active sites Synergy Catalytic performance 

学科分类：081705[081705] 0817[工学-轻工类] 08[工学] 080502[080502] 0805[工学-能源动力学] 0703[理学-化学类] 

核心收录：

D　O　I：10.1016/S1872-2067(21)63841-X

馆 藏 号：203104761...