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3D Se-doped NiCoP nanoarrays on carbon cloth for efficient alkaline hydrogen evolution

3D Se-doped NiCoP nanoarrays on carbon cloth for efficient alkaline hydrogen evolution

作     者:LIU Zi-xuan WANG Xiao-long HU Ai-ping TANG Qun-li XU Ya-li CHEN Xiao-hua 刘紫轩;王晓龙;胡爱平;唐群力;徐亚利;陈小华

作者机构:College of Materials Science and EngineeringHunan UniversityChangsha 410082China 

基  金:Projects(51772086,51872087,51971089)supported by the National Natural Science Foundation of China Project(2018TP1037-202102)supported by Open Fund of Hunan Provincial Key Laboratory of Advanced Materials for New Energy Storage and Conversion,China Project supported by Student National SIT Innovation Program,China Project(2020CB1007)supported by Hunan Joint International Laboratory of Advanced Materials and Technology for Clean Energy,China 

出 版 物:《Journal of Central South University》 (中南大学学报(英文版))

年 卷 期:2021年第28卷第8期

页      码:2345-2359页

摘      要:The exploration of stable and highly efficient alkaline hydrogen evolution reaction(HER)electrocatalysts is imperative for alkaline water ***,Se-doped NiCoP with hierarchical nanoarray structures directly grown on carbon cloth(Se-NiCoP/CC)was prepared by hydrothermal reaction and phosphorization/selenization *** experimental results reveal that Se doping could increase the electrochemical active sites and alter the electronic structure of *** optimized Se-NiCoP/CC electrode exhibits outstanding HER activity in alkaline electrolyte,which only needs a low overpotential of 79 mV at the current density of 10 mA/cm^(2).When serving as anode and cathode electrode simultaneously,the Se-NiCoP/CC electrodes achieve current density of 50 mA/cm^(2) at a low voltage of only 1.62 *** work provides a feasible way to rationally design high active HER electrocatalysts.

主 题 词:Se-NiCoP nanorods multi-level array structure hydrogen evolution reaction alkaline solution water splitting 

学科分类:0810[工学-土木类] 081702[081702] 081705[081705] 0806[工学-电气类] 08[工学] 0817[工学-轻工类] 0805[工学-能源动力学] 080502[080502] 0703[理学-化学类] 0812[工学-测绘类] 

核心收录:

D O I:10.1007/s11771-021-4774-y

馆 藏 号:203104975...

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