Photodeposition of earth‐abundant cocatalysts in photocatalytic water splitting:Methods,functions,and mechanisms

作     者：Hui Zhao Qinyi Mao Liang Jian Yuming Dong Yongfa Zhu 赵辉;茅沁怡;蹇亮;董玉明;朱永法

作者机构：Key Laboratory of Synthetic and Biological ColloidsMinistry of EducationSchool of Chemical and Materials EngineeringJiangnan UniversityWuxi 214122JiangsuChina International Joint Research Center for Photo‐responsive Molecules and MaterialsJiangnan UniversityWuxi 214122JiangsuChina Department of ChemistryTsinghua UniversityBeijing 100084China 

基　　金：国家自然科学基金(22136002 22172064 21806059 21676123) 

出 版 物：《Chinese Journal of Catalysis》 (催化学报（英文）)

年 卷 期：2022年第43卷第7期

页      码：1774-1804页

摘      要：Photocatalytic water splitting based on semiconductor photocatalysts is a promising approach for producing carbon‐neutral,sustainable,and clean H_(2) *** loading,which is an appealing strategy,has been extensively employed to improve the photocatalytic efficiency *** view of the high cost and rare preservation of noble metal cocatalysts that significantly hinder their utilization for large‐scale energy production,various cocatalysts comprising earth‐abundant ele‐ments have been developed as noble‐metal‐free candidates using different methods to boost pho‐tocatalytic water *** these preparation strategies,photodeposition has attracted tre‐mendous attention in the deposition of earth‐abundant cocatalysts owing to its simplicity and mod‐erate availability,improved interfacial charge separation and transfer,and abundant active sites on the *** this review,we first summarize the deposition principles,deposition advantages,categories of cocatalysts,roles of cocatalysts,influencing factors,modification strategies,and design considerations in the photodeposition of earth‐abundant *** photodeposited earth‐abundant cocatalysts for the photocatalytic H_(2) evolution half reaction,photocatalytic O_(2) evo‐lution half reaction,and overall photocatalytic water splitting are ***,some perspec‐tives on the challenges and possible future directions for the photodeposition of earth‐abundant cocatalysts in photocatalytic water splitting are presented.

主 题 词：Photodeposition Noble‐metal‐free cocatalyst Photocatalysis Water splitting 

学科分类：081702[081702] 081704[081704] 081705[081705] 07[理学] 070304[070304] 08[工学] 0817[工学-轻工类] 0703[理学-化学类] 

核心收录：

D　O　I：10.1016/S1872-2067(22)64105-6

馆 藏 号：203111741...