Recent advances in glycerol valorization via electrooxidation:Catalyst,mechanism and device

作     者：Jianxiang Wu Xuejing Yang Ming Gong 吴建祥;杨雪晶;龚鸣

作者机构：Department of ChemistryFudan UniversityShanghai 200438China National Engineering Laboratory for Industrial Wastewater TreatmentEast China University of Science and TechnologyShanghai 200237China 

基　　金：国家自然科学基金(22172036,21876049) 国家重点基础研究发展计划项目(2019YFC1604602) 中国博士后科学基金(2020M681149) 

出 版 物：《Chinese Journal of Catalysis》 (催化学报（英文）)

年 卷 期：2022年第43卷第12期

页      码：2966-2986页

摘      要：Glycerol is one of the most important biomass-based platform molecules,massively produced as a by-product in the biodiesel *** high purification cost from the crude glycerol raw material limits its application and demands new strategies for *** to the conventional thermocatalytic strategies,the electrocatalytic strategies can not only enable the selective conversion at mild conditions but also pair up the cathodic reactions for the co-production with higher *** this review,we summarize the recent advances of catalyst designs and mechanistic understandings for the electrocatalytic glycerol oxidation(GOR),and aim to provide an overview of the GOR process and the intrinsic structural-activity correlation for inspiring future work in this *** review is dissected into three *** will first introduce the recent efforts of designing more efficient and selective catalysts for GOR,especially toward the production of value-added ***,we will summarize the current understandings about the reaction network based on the ex-situ and in-situ spectroscopic studies as well as the theoretical ***,we will select some representative examples of creating real electrochemical devices for the valorization of *** summarizing these previous efforts,we will provide our vision of future directions in the field of GOR toward real applications.

主 题 词：Glycerol electrooxidation Reaction mechanism Design of electrocatalyst Real application Biomass conversion 

学科分类：081702[081702] 081705[081705] 08[工学] 0817[工学-轻工类] 

核心收录：

D　O　I：10.1016/S1872-2067(22)64121-4

馆 藏 号：203115479...