新型鹅去氧胆酸分子裂缝的设计合成

作     者：刘兴利 赵志刚 陈淑华 LIU Xing-li;ZHAO Zhi-gang;CHEN Shu-hua

作者机构：西南民族大学化学与环境保护工程学院四川成都610041 四川大学化学学院四川成都610064 

基　　金：国家自然科学基金(20272038)资助项目 

出 版 物：《化学研究与应用》 (Chemical Research and Application)

年 卷 期：2007年第19卷第3期

页      码：330-333页

摘      要：A novel type of chiral molecular clefts was designed and synthesized by using chenodeoxycholic acid as spacer and aromatic compounds as *** structures were confirmed by 1H NMR,IR,MS spectra and elemental *** recognition properties of these molecular clefts for amino acid methyl esters were investigated by UV-vis spectra titration. The results indicated that these molecular clefts not only recognize all amino acid methyl esters examined but also possess higher selectivity for L-amino acid methyl esters than for D-amino acid methyl esters.

主 题 词：鹅去氧胆酸 分子裂缝 合成 分子识别 

学科分类：081704[081704] 07[理学] 070304[070304] 08[工学] 0817[工学-轻工类] 0703[理学-化学类] 

核心收录：

D　O　I：10.3969/j.issn.1004-1656.2007.03.025

馆 藏 号：203137800...