Conductive metal-organic frameworks with redox activity as electrode materials for rechargeable batteries
作者机构：College of Chemistry and Materials ScienceGuangdong Provincial Key Laboratory of Supramolecular Coordination ChemistryJinan UniversityGuangzhou 510632China School of Materials and EnergyGuangdong University of TechnologyGuangzhou 510006China
基 金：supported by the National Natural Science Foundation of China(22109052,52202221,22150004) Guangdong Basic and Applied Basic Research Foundation(2022B1515020001,2024A1515010277) Guangzhou Science and Technology Program(2024A04J3899)
出 版 物：《Science China Materials》 (中国科学(材料科学)(英文版))
年 卷 期：2025年第68卷第3期
页 码：724-743页
摘 要：Two-dimensional conductive metal-organic frameworks(2D c-MOFs)with high flexibility in structure design and functionalization have inspired numerous research interests as promising multifunctional materials due to their porous structure,high conductivity,and rich redox active *** review offers a concise overview of 2D c-MOF syntheses and their applications in rechargeable *** electron transport mechanism of 2D c-MOFs will be briefly introduced *** we discuss the designs and syntheses of 2D c-MOFs,emphasizing the conjugate structure for high conductivity and the redox activity for efficient energy *** electrochemical behaviors of the 2D c-MOFs in different rechargeable battery systems are summarized with attention to their structure-performance correlations and storage *** attention is paid to the significant applied potential of 2D c-MOFs in the Na-ion batteries(NIBs)and Kion batteries(KIBs),which are more sustainable battery chemistries but are plagued by the dissatisfactory battery performances due to the large size of the Na^(+)and K^(+).The challenges and opportunities regarding their efficient synthesis and rechargeable battery applications are also *** expect this review will spark new endeavors to promote the further development of 2D c-MOFs for advanced rechargeable batteries.
主 题 词：2D c-MOFs rechargeable batteries redox activity charge storage mechanism
学科分类：081704[081704] 07[理学] 08[工学] 0817[工学-轻工类] 070303[070303] 0703[理学-化学类]
核心收录：
D O I：10.1007/s40843-024-3109-5
馆 藏 号：203144414...
