Design and synthesis of two coordination polymers for the rapid detection of ciprofloxacin based on triphenylpolycarboxylic acid ligands

作     者：YANG Dongdong XUE Jianhua YANG Yuanyu WU Meixia BAI Yujia WANG Zongxuan MA Qi 杨冬冬;薛建华;杨元宇;武美霞;白雨佳;王宗璇;马琦

作者机构：College of Chemistry and Chemical EngineeringShanxi Datong UniversityDatongShanxi 037009China 

出 版 物：《无机化学学报》 (Chinese Journal of Inorganic Chemistry)

年 卷 期：2024年第40卷第12期

页      码：2466-2474页

摘      要：Two coordination polymers were synthesized by hydrothermal reaction,namely,[Cd(H_(3)cpbda)(2,2′‑bipy)(H_(2)O)]_(n)(1)and[Mn(H_(3)cpbda)(phen)(H_(2)O)]_(n)(2),where H_(5)cpbda=5,5′‑[(5‑carboxy‑1,3‑phenyl)bis(oxy)]triisophthalic acid,2,2′‑bipy=2,2′‑bipyridine,phen=1,10‑*** two complexes were characterized by single‑crystal X‑ray diffraction,powder diffraction,infrared spectroscopy,and thermogravimetric *** 1 and 2 are“V”‑shaped 1D chains,and the molecules form 2D(1)and 3D framework(2)structures through weakπ…π***,complex 1 was dispersed in an aqueous solution and its fluorescence intensity demonstrated excellent *** 1 can specifically detect ciprofloxacin in urine with a detection limit of 1.91×10^(-8)mol·L^(-1).CCDC:2359498,1;2359499,2.

主 题 词：coordination polymer flexible ligand fluorescence ciprofloxacin detection 

学科分类：081704[081704] 07[理学] 08[工学] 0817[工学-轻工类] 0703[理学-化学类] 070301[070301] 

D　O　I：10.11862/CJIC.20240266

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