Metal-mediated catalysis in the gas phase: A review

作     者：Xiao‐Na Li Xiu‐Ping Zou Sheng‐Gui He 李晓娜;邹秀平;何圣贵

作者机构：Beijing National Laboratory for Molecular Sciences State Key Laboratory for Structural Chemistry of Unstable and Stable Species Institute of Chemistry Chinese Academy of Sciences Beijing 100190 China School of Chemistry and Chemical Engineering South China University of Technology Guangzhou 510641 Guangdong China 

基　　金：supported by the National Natural Science Foundation of China(21303215,21325215,21573246) the Major Research Plan of China(No.2013CB834603) the grant from the Youth Innovation Promotion Association,Chinese Academy of Sciences(2016030) 

出 版 物：《Chinese Journal of Catalysis》 (催化学报（英文）)

年 卷 期：2017年第38卷第9期

页      码：1515-1527页

摘      要：This review summarizes a variety of experimentally identified gas‐phase catalytic cycles,all of which are mediated by atomic metal ions,bare metal clusters,metal oxide clusters or metal *** is placed on the latest advances in the unique catalytic reactivity of cluster‐confined single noble metal *** cycles discussed in this paper cover a wide range of inorganic and organic *** use of start‐of‐the‐art mass spectrometric instrumentation in conjunction with quantum chemistry calculations is also reported,as these techniques have determined the mechanistic details of the elementary steps of such catalytic *** important role of gas‐phase data in guiding the rational design of better‐performing catalysts in related condensed phase reactions is also *** particular,this review focuses on the following three topics:(1)the catalytic oxidation of carbon monoxide,(2)the catalytic functionalization of methane,and(3)catalytic decarboxylation.

主 题 词：Metal catalysis Clusters Single atom catalysts Carbon monoxide Methane 

学科分类：081705[081705] 08[工学] 0817[工学-轻工类] 

核心收录：

D　O　I：10.1016/S1872‐2067(17)62782‐7

馆 藏 号：203263518...