Rational design of Cu-based electrocatalysts for electrochemical reduction of carbon dioxide

作     者：Baohua Zhang Jintao Zhang 

作者机构：Key Laboratory for Colloid and Interface Chemistry of State Education MinistrySchool of Chemistry and Chemical EngineeringShandong UniversityJinan 250100ShandongChina 

基　　金：financially supported by the Natural Scientific Foundation of China(no.21503116) the Open Funds of the State Key Laboratory of Organic-Inorganic Composites,Beijing University of Chemical Technology(oic-201601008) the Qingdao Basic&Applied Research Project(15-9-1-100-jch) Taishan Scholars Program of Shandong Province(no.tsqn20161004) the Youth 1000 Talent Program of China 

出 版 物：《Journal of Energy Chemistry》 (能源化学（英文版）)

年 卷 期：2017年第26卷第6期

页      码：1050-1066页

摘      要：The recent development of Cu-based electrocatalysts for electrochemical reduction of carbon dioxide（CO） has attracted much attention due to their unique activity and selectivity compared to other metal catalysts. Particularly, Cu is the unique electrocatalyst for COelectrochemical reduction with high selectivity to generate a variety of hydrocarbons. In this review, we mainly summarize the recent advances on the rational design of Cu nanostructures, the composition regulation of Cu-based alloys, and the exploitation of advanced supports for improving the catalytic activity and selectivity toward electrochemical reduction of CO. The special focus is to demonstrate how to enhance the activity and selectivity of Cubased electrocatalyst for COreduction. The perspectives and challenges for the development of Cu-based electrocatalysts are also addressed. We hope this review can provide timely and valuable insights into the design of advanced electrocatalytic materials for COelectrochemical reduction.

主 题 词：Electrocatalysts Copper Alloy Selectivity CO_2 electrochemical reduction Electrocatalytic activity Faradaic efficiency 

学科分类：081705[081705] 08[工学] 0817[工学-轻工类] 

核心收录：

D　O　I：10.1016/j.jechem.2017.10.011

馆 藏 号：203278526...