Selective oxidation of C–H bonds with Fe-N-C single-atom catalyst

作     者：Xingwei Li 李兴伟

作者机构：Chinese Academy of Sciences Dalian 116023 Liaoning China 

出 版 物：《Chinese Journal of Catalysis》 (催化学报（英文）)

年 卷 期：2018年第39卷第1期

页      码：1-3页

摘      要：Activation of C–H bonds has received considerable attentionin the past decade as this provides an efficient and atom‐economy strategy to access a plethora of value‐addedchemicals from easily available substrates[1].Nevertheless,the high stability of C–H bonds poses significant challenge for selective *** instance,the selective oxidation of C–H bonds in hydrocarbons has proved to be high useful in synthesis of alcohol/ketone feedstocks in both areas of C1chemistry[2]and organic synthesis[3,4].However,given the generally high dissociation energy of C–H bonds and possible over‐oxidation,it remains challenging to realize both high reactivity and selectivity.

主 题 词：选择性氧化反应 均相催化剂 单原子 中科院大连化学物理研究所 烃类化合物 吸电子基团 多相催化剂 脂肪族化合物 

学科分类：081705[081705] 08[工学] 0817[工学-轻工类] 

核心收录：

D　O　I：10.1016/S1872‐2067(17)63002‐X

馆 藏 号：203282107...