P-doped mesoporous carbons for high-efficiency electrocatalytic oxygen reduction
作者机构：National Institute for Advanced MaterialsSchool of Materials Science and EngineeringNankai UniversityTianjin 300350China Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education)Collaborative Innovation Center of Chemical Science and Engineering (Tianjin)Nankai UniversityTianjin 300071China
基 金：supported by the National Natural Science Foundation of China(21421001 21573115)
出 版 物：《Chinese Journal of Catalysis》 (催化学报（英文）)
年 卷 期：2019年第40卷第9期
页 码：1366-1374页
摘 要：Chemically modified carbonaceous materials have attained utmost attention in the fields of renewable energy storage and conversion,due to the controllable physicochemical properties,tailorable micro-/nanostructures,and respectable ***,P-doped mesoporous carbons were synthesized by using F127 as the soft template,organophosphonic acid as the P source and phenolic resin as the carbon *** amounts of iron species were introduced to act as a graphitization *** synthesized carbons exhibit the well-defined wormhole-like pore structure featuring high specific surface area and homogenously doped P ***,introducing iron species during the synthesis process can optimize the textural properties and the degree of graphitization of carbon *** doping amount of P has an important effect on the porous structure and the defect degree,which correspondingly influence the active sites and the oxygen reduction reaction(ORR)*** resultant material presents superior catalytic activity for the ORR,together with remarkably enhanced durability and methanol tolerance in comparison with the commercial Platinum catalyst,demonstrating the possibility for its use in electrode materials and electronic nanodevices for metal-air batteries and fuel cells.
主 题 词：P-doping Mesoporous carbons Electrocatalyst Oxygen reduction reaction
学科分类：081705[081705] 08[工学] 0817[工学-轻工类] 080502[080502] 0805[工学-能源动力学]
核心收录：
D O I：10.1016/S1872-2067(19)63363-2
馆 藏 号：203691948...
