摘要：Negative thermal expansion(NTE),as an abnormal physical behavior,has been followed by scientists’attention over the past 30 years,due to its fascinating physical mechanisms and the prospect of high-precision thermal expansion control[1-5].Although some NTE materials(alloys[6],cyanides[7],fluorides[8-10],nitrides[11],oxides[12,13],MOFs[14-16],etc.)have been found,their number and variety are still very small,limiting their *** and designing new NTE materials is an important and challenging topic for the development of the field of *** have been continually reviewing and summarizing obtained results to look to the future of NTE[17-23].