摘要：Formic acid(FA)has attracted extensive attention as a hydrogen storage ***,we develop two heterogeneous catalysts based on porous organic polymers(POPs).After loading the Ru species,the catalyst bearing the triphenylphosphine ligand showed excellent performance in terms of activity and stability for the decomposition of FA to produce hydrogen.

摘要：In contrast to heterogeneous network frameworks(e.g.,covalent organic frameworks and metal‐organic frameworks)and porous organic polymers,porous organic cages(POCs)are soluble molecules in common organic solvents that provide significant potential for homogeneous ***,we report a triphenylphosphine‐derived quasi‐porous organic cage(denoted as POC‐DICP)as an efficient organic molecular cage ligand for Rh/PPh_(3) system‐catalyzed homogeneous hydroformylation ***‐DICP not only displays enhanced hydroformylation selectivity(aldehyde selectivity as high as 97%and a linear‐to‐branch ratio as high as 1.89)but can also be recovered and reused via a simple precipitation method in homogeneous reaction *** speculate that the reason for the high activity and good selectivity is the favorable geometry(cone angle=123.88°)and electronic effect(P site is relatively electron‐deficient)of POC‐DICP,which were also demonstrated by density functional theory calculations and X‐ray absorption fine‐structure characterization.

摘要：为保证压电柔顺微操作器的精准性和稳定性,以压电纤维驱动的单自由度柔性微操作器为例,首先,通过在传统Prandtl-Ishlinskii(简称PI)迟滞模型上串联死区算子,建立改进PI迟滞模型并设计相应前馈控制器;其次,将系统模型分解为线性可逆分量和有界分量,并构建权重函数和增广模型设计H_(∞)反馈控制器,以保证系统的稳定性和精准性;最后,以压电纤维驱动的单自由度柔性微操作器为例,搭建实验测控系统。实验结果表明:在前馈控制下,压电柔顺微操作器的迟滞量从16.5%下降到4.4%,改进PI迟滞模型是可行的。当参考轨迹为阶跃和不同频率的正弦信号、甚至改变微操作器结构参数时,H_(∞)反馈控制均能有效跟踪给定参考信号且相对控制误差较小,验证了所设计H_(∞)反馈控制器的有效性。