摘要：Anodic urea oxidation reaction(UOR)is an intriguing half reaction that can replace oxygen evolution reaction(OER)and work together with hydrogen evolution reaction(HER)toward simultaneous hydrogen fuel generation and urea-rich wastewater purification;however,it remains a challenge to achieve overall urea electrolysis with high ***,we report a multifunctional electrocatalyst termed as Rh/Ni V-LDH,through integration of nickel-vanadium layered double hydroxide(LDH)with rhodium single-atom catalyst(SAC),to achieve this *** electrocatalyst delivers high HER mass activity of0.262 A mg^(-1) and exceptionally high turnover frequency(TOF)of 2.125 s^(-1) at an overpotential of100 m ***,exceptional activity toward urea oxidation is addressed,which requires a potential of 1.33 V to yield 10 mA cm^(-2),endorsing the potential to surmount the sluggish *** splendid catalytic activity is enabled by the synergy of the Ni V-LDH support and the atomically dispersed Rh sites(located on the Ni-V hollow sites)as evidenced both experimentally and *** selfsupported Rh/Ni V-LDH catalyst serving as the anode and cathode for overall urea electrolysis(1 mol L^(-1) KOH with 0.33 mol L^(-1) urea as electrolyte)only requires a small voltage of 1.47 V to deliver 100 mA cm^(-2) with excellent *** work provides important insights into multifunctional SAC design from the perspective of support sites toward overall electrolysis applications.

摘要：Amidst the development of photoelectrochemical(PEC)CO_(2) conversion toward practical application,the production of high-value chemicals beyond C1 compounds under mild conditions is greatly desired yet ***,through rational PEC device design by combining Au-loaded and N-doped TiO_(2) plate nanoarray photoanode with Zn-doped Cu_(2)O dark cathode,efficient conversion of CO_(2) to CH3COOH has been achieved with an outstanding Faradaic efficiency up to 58.1%(91.5%carbon selectivity)at 0.5 V ***/*** programmed desorption and in situ Raman spectra reveal that the Zn-dopant in Cu_(2)O plays multiple roles in selective catalytic CO_(2) conversion,including local electronic structure manipulation and active site modification,which together promote the formation of intermediate*CH2/*CH3 for C-C *** from that,it is also unveiled that the sufficient electron density provided by the Au-loaded and N-doped TiO_(2) plate nanoarray photoanode plays an equally important role by initiating multi-electron CO_(2) *** work provides fresh insights into the PEC system design to reach the multi-electron reduction reaction and facilitate the C-C coupling reaction toward high-value multicarbon(C2+)chemical production via CO_(2) conversion.

摘要：根据核燃料组件骨架技术条件要求,完成三坐标测量机测针配置、工装夹具设计和测量程序设计,建立了一套高效、准确的骨架自动化检测方法。通过对测量系统进行重复性和再现性分析及人工检测结果比对,证明该检测方法能高效、准确地完成骨架检测。

摘要：The thermal expansion coefficient(TEC)and thermal conductivity(k)of thermal fillers are key factors for designing thermal management and thermal protection composite *** to its unique advantages,hexagonal boron nitride(h-BN)is one of the most commonly used thermal ***,its TEC and k values are still unclear due to the inconsistency of characterization techniques and sample *** this work,these disputes were addressed using the quasi-harmonic approximation(QHA)method and phonon Boltzmann transport equation(BTE)theory based on the density functional theory(DFT),*** accuracy of our calculated TEC and k values was confirmed by previously reported experimental results,and the underlying physical principles were analyzed from the phonon *** TEC results show that the h-BN has small in-plane negative value and large cross-plane positive value,which are-2.4×10^(-6) and 36.4×10^(-6) K^(-1) at 300 K,*** the anisotropic TEC is mainly determined by the anisotropic isothermal bulk modulus and the low-frequency out-of-plane longitudinal phonon *** found that the convergence of cutoff radius and q-grid size have significant effect on the accuracy of k of *** results show that the in-plane k is much higher than the cross-plane k,and the values at 300 K are 286.6 and 2.7 W m^(-1) K^(-1),*** anisotropic phonon group velocity arising from the vibration behaviors of acoustic phonon modes should be primarily responsible for the anisotropic *** calculated TEC and k values will provide important references for the design of h-BN composite materials.

摘要：受新媒体形式的发展及新媒体展示载体的进步所带来的影响,各行业都涤故更新不再拘泥于单一的形式。作为信息传播途径之一的广告业,从传统的广告传播形式招贴、海报、喷绘等,逐渐向互联网、移动端、户外彩屏、装置艺术等方向发展。新媒体的出现,使得户外广告中充分、有机地融合了多学科知识,武装起来的户外广告变得更加科学、富有创新性和内涵。广告人现在所探寻的问题应是多学科的,可结合心理学中的“条件反射行为”对户外广告进行分析探讨,研究如何针对某一条件反射行为设计对应的户外广告,激发消费者的购买动机,促使其产生消费行为,达到企业盈利的最终目的。

摘要：根据云南松EST序列设计了32对SSR引物,从中随机选取7对引物,对不同群体云南松及细叶云南松、马尾松等近缘种进行了PCR,研究云南松EST-SSR引物在近缘物种中的通用性。结果表明:所选择的7对引物对云南松不同群体及其近缘种的扩增成功率均为100%;且7对引物在云南松不同群体的多态性比例均为100%,在细叶云南松、马尾松、高山松、油松和思茅松等近缘种中分别为71.43%、85.71%、85.71%、85.71%和100%;云南松EST-SSR引物具有较高的通用性,且这些引物可用于分析云南松及其近缘种间的遗传关系。

摘要：非晶SiBCN陶瓷是一类独特的结构材料,具有低比重、高比强度、优异的高温损伤容限等特殊结构和性能,因此在高温防热结构部件上极具应用潜力。通过合理的结构与化学成分协同设计,可探索陶瓷形貌/微观结构演化及断裂行为的基本特征,从而进一步提高其力学性能,以满足实际应用需求。因此,文章以石墨、六方氮化硼、立方硅和硼等元素粉末为原料,提出了采用机械合金化结合高压烧结技术(1 000°C/3~5 GPa/30 min)制备致密非晶Si2ByC2N(y=1.5~4)块体陶瓷的方法。通过XRD、SEM、TEM、TG等表征手段,研究了烧结压力诱导该系非晶陶瓷的组织结构演化、相变及热稳定性,并对其力学性能,特别是断裂行为进行了详细讨论。结果表明,提高烧结压力促使陶瓷基体由完全非晶态向晶态转变,部分块体陶瓷由大量非晶相、少量c-Si和/或t-BN(C)纳米晶相组成,显示出依赖于硼含量的物相组成。高压烧结有效地促进了陶瓷的烧结致密化,导致材料内自由体积的湮灭和"河流状"断裂形貌的产生。随着烧结压力的提高,陶瓷材料的体积密度、纳米硬度和杨氏模量单调增加。在相同烧结条件下,硼含量的增加削弱了非晶Si2ByC2N(y=1.5~4)块体陶瓷的力学性能和热稳定性。1 000°C/5 GPa/30 min烧结制备的致密非晶Si2B1.5C2N块体陶瓷的体积密度、纳米硬度和杨氏模量分别为2.69 g/cm3、33.6±2.2GPa和414.2±16.5 GPa。