摘要：随着地震监测工作的日益重要,巡检路线的规划对于提高巡检工作效率和确保产出准确连续的观测数据具有关键作用。本文通过介绍地震监测站点巡检的重要性和现有巡检方式的局限性,探讨地震监测站点巡检最优路线规划软件的设计与开发。文中阐述了软件的设计理念、主要功能和技术实现,对关键模块的设计进行了详细说明,指出优化巡检线路过程中应特别注意的问题,并展望了软件未来的应用前景。该软件的成功开发和应用,将为地震监测站点的巡检工作提供强有力的技术支持,同时也为其他领域的巡检路线规划提供了有益的参考。

摘要：Surface plasmon resonance(SPR)of metals may provide a way to improve light absorption and utilization of semiconductors,achieving better solar light conversion and photocatalysis *** study uses the advantages of SPR in metallic Bi and artificial defects to cooperatively enhance the photocatalytic performance of *** catalysts were prepared by partial reduction of BiOI to form Bi@defective BiOI,which showed highly enhanced visible photocatalytic activity for NOx *** effects of reductant quantity on the photocatalytic performance of Bi@defective BiOI were *** as-prepared photocatalyst(Bi/BiOI-2)using 2 mmol of reductant NaBH4 showed the most efficient visible light photocatalytic *** enhanced activity can be ascribed to the synergistic effects of metallic Bi and oxygen *** electrons from the valence band tend to accumulate at vacancy states;therefore,the increased charge density would cause the adsorbed oxygen to transform more easily into superoxide radicals and,further,into hydroxyl *** radicals are the main active species that oxidize NO into final *** SPR effect of elemental Bi enables the improvement of visible light absorption efficiency and the promotion of charge carrier separation,which are crucial factors in boosting *** adsorption and reaction processes on Bi/BiOI-2 were dynamically monitored by in situ infrared spectroscopy(FT-IR).The Bi/BiOI photocatalysis mechanism co-mediated by elemental Bi and oxygen vacancies was proposed based on the analysis of intermediate products and DFT *** present work could provide new insights into the design of high-performance photocatalysts and understanding of the photocatalysis reaction mechanism for air-purification applications.

摘要：氮氧化物(NO_(x))是大气的主要污染物之一,也是PM_(2.5)和O_(3)的重要前驱体,理想的去除方式之一是将其深度氧化至硝酸盐,避免中间毒副产物NO_(2)的生成1,2。低温等离子体技术作为NO_(x)氧化处理的备选技术,其能耗较高、产物主要为NO_(2)等问题制约了该技术的进一步发展和应用3。采用等离子体与催化协同使用是解决此问题的突破口,考虑到催化剂与等离子体之间可能的相互作用,设计制备可充分利用等离子体特性的催化剂至关重要。

摘要：空间光谱成像技术的发展使得探测器阵列与分光元件的集成成为一种趋势,长线阵拼接集成滤光片是空间多光谱成像仪实现焦平面集成分光的关键器件,在我国空间多光谱成像光学系统中需求明显。设计了4通道短中波红外长线阵拼接集成滤光片,采用离子束辅助轰击的电子枪蒸发方法制备了各通道窄带滤光片,利用专门研制的工装探索了拼接工艺,研制出了短中波红外长线阵拼接集成滤光片。测试结果表明:集成滤光片各通道平均透射率达到90%,最小带宽为230 nm (中心波长为4.95μm),光谱性能与设计结果吻合,满足性能指标要求。最小拼缝宽度仅为10μm,拼缝不平行误差为1μm,集成滤光片设计结构和拼接强度能够耐受抗振性试验。该集成滤光片已经在空间光学遥感仪器上成功应用。

摘要：为解决坑道钻机动力泵站重量大、搬迁运输难题,提出通过模块设计,将泵站进行拆分,采用小排量双动力双泵合流解决方案。化整为零,可有效减小单个泵站的运输尺寸及重量,并可根据工况需求选择单泵站或双泵合流提高钻机使用的灵活性,同时降低能耗。负载敏感系统具有节能、负载适应性好、调速方便等优点,然而双负载敏感泵系统合流时,2个泵的输出功率不平衡,钻机输出参数不符合设计要求是亟需解决的难题。理论分析指出,两个负载敏感泵与负载敏感阀之间的反馈管路差异影响2个泵的功率平衡,然后建立双动力双泵负载敏感系统动态模型。基于该模型,动态分析双负载敏感泵系统压力流量特性,重点分析反馈管路以及压力补偿器对双泵站功率平衡的影响,并提出双负载敏感泵系统功率匹配方法。通过台架实验对理论分析结果进行验证,结果表明,管路差异对双泵双动力负载敏感泵合流系统输出特性有较大的影响。在反馈管路中设置阻尼并根据管路匹配阻尼参数,可实现双泵输出参数的基本平衡。通过微调压力补偿器弹簧预压缩量,可使系统达到较好平衡,消除管路差异影响。该方法解决了2个泵站输出功率不平衡问题,该方法有较强的普适性和应用价值,对坑道钻机液压泵站的模块化设计具有重要的参考意义。

摘要：Heterostructured photocatalysts provide an effective way to achieve enhanced photocatalytic performances through efficient charge *** both wide-and narrow-band-gap photocatalysts have been widely investigated,the charge separation and transfer mechanism at the contacting interface of the two has not been fully ***,a novel SrTiO3/BiOI(STB)heterostructured photocatalyst was successfully fabricated by using a facile *** heterostructure in the photocatalyst extends the photoabsorption to the visible light range,and thus,high photocatalytic NO removal performance can be achieved under visible light irradiation.A combination of experimental and theoretical evidences indicated that the photogenerated electrons from the BiOI semiconductor can directly transfer to the SrTiO3 surface through a preformed electron delivery *** electron transfer was expected between the SrTiO3 and BiOI surfaces under light irradiation,and leads to efficient ROS generation and thus a high NO conversion ***,in situ diffused reflectance infrared Fourier transform spectroscopy revealed that STB can better inhibit the accumulation of the toxic intermediate NO2 and catalyze the NO oxidation more *** work presents a new insight into the mechanism of the interfacial charge separation in heterostructures and provides a simple strategy to promote the photocatalytic technology for efficient and safe air purification.

摘要：在可持续碳资源利用的研究中,光催化CO_(2)转化为高附加值化学品的前景日益凸显.相较于常见的CO_(2)还原产物如甲烷、一氧化碳或甲酸,具有两个或更多碳原子的C_(2+)化合物因其具有更高的附加值而备受关注.然而,目前的研究面临着C–C偶联过程和多质子耦合电子转移效率的限制,导致光催化CO_(2)的还原反应产物主要为C1化合物.常规光催化剂难以突破这些动力学和热力学壁垒,导致目标产物C_(2+)化合物的生成量远低于实际工业应用所需要的水平.因此,开发具有良好性能的光催化剂,以实现C_(2+)化合物的高效制备,仍是当前面临的重要科学挑战.本文系统性地概述了光催化CO_(2)还原为C_(2+)化合物领域的最新研究进展.首先,从光催化的基本原理及C_(2+)产物的生成路径出发,在光催化剂设计方面,为突破C–C偶联和多质子耦合电子转移的限制,需要解决以下问题:(1)关键中间产物的生成与吸附转移;(2)活性位点对于中间产物的选择性;(3)光生电子的寿命与定向转移.随后,详细介绍了高效、高选择性光催化剂的合理设计策略,包括缺陷工程、双金属位点、表面等离子体共振以及异质结构造等.同时,深入探讨了C–C偶联和多电子偶联的质子转移过程的催化机制.最后,展望了光催化CO_(2)还原制C_(2+)高附加值产物的未来研究方向,催化剂设计与机制研究的关键方向包括:(1)设计高选择性和高效吸附*CO中间体的活性位点,以提升催化性能;(2)设计具有轨道匹配的双活性位点以减少邻近*CO中间体间的静电排斥,促进C–C耦合;(3)从分子轨道相互作用角度深入理解C–C耦合和电子转移过程,揭示反应机制;(4)鉴别反应过程中的自由基组分,阐明多质子耦合电子转移过程的机理.综上所述,本文系统地梳理了光催化CO_(2)还原制C_(2+)高附加值产物的研究进展、关键问题、催化剂设计原理以及未来研究方向,旨在为开发设计高效、高选择性催化剂提供有益的参考.

摘要：Charge separation and transformation are some of the key requirements for high-efficiency photocatalysis. The photocatalytic reaction mechanism provides a guideline for the development and commercialization of high-efficiency photocatalysts. In this study, we designed and favorably synthesized BMO@BOC heterojunctions via a facile solvothermal route and applied the heat treatment method for application in high-efficiency photocatalytic NO removal. More importantly, both continuous stream and intermittent stream methods with in situ diffuse reflectance infrared Fourier transform spectroscopy were applied to intuitively and dynamically investigate the adsorption process and oxidation process of NO removal over the photocatalyst surface. The intermediate products(NO-, NO2-, and NO2) were explicitly detected in both the adsorption process and oxidation process, whilst the final product(NO3-) appeared only in the oxidation process, owing to the separation, migration, and conversion of photoinduced electron-hole pairs.

摘要：Ternary Ag/AgC l/BiO IO3 composite photocatalysts are prepared by a facile method. Enhanced visible-light absorption and charge carrier separation are achieved after the introduction of Ag/AgC l particles into BiO IO3 systems,as revealed by ultraviolet-visible diffuse-reflectance spectrometry,photocurrent response and electrochemical impedance spectroscopy. The Ag/AgC l/BiO IO3 composites are applied to the visible-light photocatalytic oxidization of NO in air and exhibit an enhanced activity for NO removal in comparison with Ag/AgC l and pure BiO IO3. A possible photocatalytic mechanism for Ag/AgC l/BiO IO3 is proposed,which is related to the surface plasmon resonance effects of Ag metal and the effective carrier separation ability of BiO IO3. This work provides insight into the design and preparation of BiO IO3-based materials with enhanced visible-light photocatalysis ability.

摘要：全液压动力头式车载钻机可满足垂直井、水平对接井、羽状分支井等多种型式钻井的施工需要,是地面煤层气抽采钻孔施工的理想机型。ZMK5530TZJ60型车载钻机针对地面煤层气抽采钻孔施工需而研制,具备施工1 200 m钻孔的施工能力。介绍了钻机动力头和给进装置等主要执行机构的设计特点和在山西晋城寺河矿区施工远端对接井的工程实例。