摘要：As a non-specific modulator of macrophage, multiplied muramyl dipeptide (MMD) is solid-phase synthesized by application of standard Fmoc chemistry strategy. Tarn's multiple antigen system (MAS) is used as our four branched-linker on Lysine.

摘要：The design and synthesis of highly active non-noble metal oxide catalysts, such as transition- and rare-earth-metal oxides, have attracted significant attention because of their high efficiency and low cost and the resultant potential applications for the degradation of volatile organic compounds(VOCs). The structure-activity relationships have been well-studied and used to facilitate design of the structure and composition of highly active catalysts. Recently, non-noble metal oxides with porous structures have been used as catalysts for deep oxidation of VOCs, such as aromatic hydrocarbons, aliphatic compounds, aldehydes, and alcohols, with comparable activities to their noble metal counterparts. This review summarizes the growing literature regarding the use of porous metal oxides for the catalytic removal of VOCs, with emphasis on design of the composition and structure and typical synthetic technologies.

摘要：Hierarchical heterostructure photocatalysts with broad spectrum solar light utilization,particularly in the nearinfrared(NIR)region,are emerging classes of advanced photocatalytic materials for solar-driven CO2 conversion into value-added chemical ***,a novel two-demensional/three-demensional(2 D/3 D)hierarchical composite is hydrothermally synthesized by assembling vertically-aligned ZnIn2 S4(ZIS)nanowall arrays on nitrogen-doped graphene foams(NGF).The prepared ZIS/NGF composite shows enhancement in photothermal conversion ability and selective CO2 capture as well as solar-driven CO2 ***273 K and 1 atm,the ZIS/NGF composite with 1.0 wt%NGF achieves a comparably high CO2-to-N2 selectivity of 30.1,with an isosteric heat of CO2 adsorption of 48.2 kJ mol^-*** in the absence of cocatalysts and sacrificial agents,the ZIS/NGF composite with cyclability converts CO2 into CH4,CO and CH3 OH under simulated solar light illumination,with the respective evolution rates about 9.1,3.5,and 5.9 times higher than that of the pristine ***-depth analysis using in-situ irradiated X-ray photoelectron spectroscopy(ISI-XPS)in conjunction with Kelvin probe measurements reveals the underlying charge transfer pathway and process from ZIS to NGF.

摘要：声爆抑制是发展新一代超声速民机必须突破的关键技术。飞行器总体布局参数对其声爆特性有重要影响。数据挖掘(DM)可以从大量的数据中通过算法搜索隐藏的信息,是飞行器设计知识提取的有力工具。选取后掠角、展弦比、梢根比、上反角、机身长细比5个总体布局参数作为设计变量,目标函数定义为远场感知噪声级,同时计算升、阻力系数作为气动力衡量指标。基于总变差分析(ANOVA)、决策树算法、自组织映射(SOM)网络组成的数据挖掘体系提取低声爆设计知识库。获得所选设计变量与声爆/气动力的相关度,并实现对设计变量的分层与降维。后掠角有最高设计优先级,长细比、上反角重要程度次之,展弦比与梢根比为低敏感变量。对于算例中的飞行器,在合理区间内选择较大的后掠角、上反角能够使声爆最小化的同时,设计适于超声速巡航的小展弦比布局。

摘要：Common solar-driven photoelectrochemical(PEC) cells for water splitting were designed by using semiconducting photoactive materials as working photoelectrodes to capture sunlight. Due to the thermodynamic requirement of 1.23 eV and kinetic energy loss of about 0.6 eV, a photo-voltage of 1.8 V produced by PEC cells is generally required for spontaneous water splitting. Therefore, the minimum bandgap of1.8 eV is demanded for photoactive materials in single-photoelectrode PEC cells, and the bandgap of about 1 eV for back photoactive materials is appropriate in tandem PEC cells. All these PEC cells cannot effectively utilize the infrared light from 1250 to 2500 nm. In order to realize the full spectrum utilization of solar light, here, we develop a solar-driven PEC water splitting system integrated with a thermoelectric device. The key feature of this system is that the thermoelectric device produces a voltage as an additional bias for the PEC system by using the temperature difference between the incident infrared-light heated aqueous electrolyte in the PEC cell as the hot source and unirradiated external water as the cold source. Compared to a reference PEC system without the thermoelectric device, this system has a significantly improved overall water splitting activity of 1.6 times and may provide a strategy for accelerating the application of full spectrum solar light-driven PEC cells for hydrogen production.

摘要：An efficient and low-cost supported Pt catalyst for hydrogenation of niroarenes was prepared with colloid Pt precursors andα-Fe2O3 as a *** catalyst with Pt content as low as 0.2 wt%exhibits high activities,chemoselectivities and stability in the hydrogenation of nitrobenzene and a variety of *** conversion of nitrobenzene can reach 3170 molconv h^–1 molPt^–1 under mild conditions(30°C,5 bar),which is much higher than that of commercial Pt/C catalyst and many reported catalysts under similar reaction *** spatial separation of the active sites for H2 dissociation and hydrogenation should be responsible for the high chemoselectivity,which decreases the contact possibility between the reducible groups of nitroarenes and Pt *** unique surface properties ofα-Fe2O3 play an important role in the reaction *** provides active sites for hydrogen spillover and reactant adsorption,and ultimately completes the hydrogenation of the nitro group on the catalyst surface.

摘要：为探索车路云一体化系统建设的可行性,本研究应用探索性案例研究方法,设计了一款包含二维界面与三维界面的系统管理软件,并配合智能网联车辆进行实地试验验证,重点解决数字孪生与道路场景仿真实现等问题。本研究建立了系统的人机交互设计流程,探索了基于数字地图接口结合高精度侧位地图、实时数字孪生场景重建的二三维系统人机交互设计框架,提供明确高效的交互机制支撑交通态势显示。通过在开放自动驾驶测试路段实地试验,验证了车路云一体化交通管理系统二三维人机交互设计方案的可用性,为提升面向智能网联车辆的交通管理提供了探索方案。

摘要：Fast migration and efficient spatial separation of photogenerated charges in photocatalytic materials are indispensable to efficient solar water splitting ***,we construct a three-phase heterostructure of CdS/PbTiO_(3)/TiO_(2)by selectively depositing CdS and TiO_(2)at oppositely poled crystal facets of PbTiO_(3)using single-domain ferroelectric PbTiO_(3).The heterostructure has matching band edge alignments and strong interfacial connections at different *** heterostructure combines the interfacial electrical and ferroelectric fields because of their peculiar microstructures,which provide a strong driving force throughout the whole bulk to separate photogenerated *** two orders of magnitude improvement of visible-light-driven photocatalytic H_(2) production has been realized in CdS/PbTiO_(3)/TiO_(2)compared with bare PbTiO_(3)/TiO_(2),showing the efficiency of charge separation in the *** idea of combining ferroelectrics with potential light capture semiconductor provides a paradigm to accurately design charge migration pathways,bringing a step closer to efficient solar water splitting.

摘要：针对现有取苗试验台不能满足多种型号钵盘和取苗机构进行取苗试验的需求,设计了一种由多个步进电机驱动、可调取苗机构倾角、可编程控制系统的多功能取苗试验台。该试验台通过调节取苗机构安装支架的位姿、改变钵盘驱动鼠笼钢丝间距以及所在圆周直径,可以适应不同型号钵盘和满足多种取苗机构的试验要求;通过编写控制器程序可控制3个步进电机联动并实现送苗装置的横、纵向送苗与取苗机构取苗进程相匹配。在三维软件中对试验台进行了建模、装配和虚拟仿真,在加工制造的物理样机上进行了2种型号钵盘和3种取苗机构的取苗试验。3次试验结果表明:在此试验台上能够顺利完成取苗试验,证明该试验台满足多种型号钵盘和多种类型取苗机构的试验需求。

摘要：Semiconductor heterostructures mediated by electrical conductors are very promising for Z-scheme photocatalytic water *** contrast to conventional particulate heterostructures,alternate TiO_(2)and Cu_(2)O film stripes patterned parallel on a fluorine-doped tin oxide(FTO) conductive substrate was fabricated as a model film photocatalyst to study the characteristics of the photogenerated charge transfer *** Z-scheme transfer process with an effective transport distance of up to 5 μm occurs only in regions distant from the TiO_(2)/Cu_(2)O strip edges through the FTO substrate from the *** contrast,the transfer of charge around their contact regions follows the conventional transfer process through the TiO_(2)/Cu_(2)O strip *** results indicate that the Z-scheme transfer process occurring in such a large region dominates the charge transfer processes in the TiO_(2)/FTO/Cu_(2)O pattern film ***,unlike the single component film,which is inactive for photocatalytic overall water splitting,the modified TiO_(2)/Cu_(2)O pattern film can induce photocatalytic overall water splitting at a stoichiometric H_(2)/O_(2) ratio close to 2:*** findings have significant implications in designing efficient heterostructures by employing a Z-scheme charge transfer process.