摘要：Intrinsic and extrinsic ion migration is a very large threat to the operational stability of perovskite solar cells and is difficult to completely eliminate due to the low activation energy of ion migration and the existence of internal electric *** propose a heterojunction route to help suppress ion migration,thus improving the operational stability of the cell from the perspective of eliminating the electric field response in the perovskite absorber.A heavily doped p-type(p^(+))thin layer semiconductor is introduced between the electron transporting layer(ETL)and perovskite *** heterojunction charge depletion and electric field are limited to the ETL and p^(+)layers,while the perovskite absorber and hole transporting layer remain *** p^(+)layer has a variety of candidate materials and is tolerant of defect density and carrier mobility,which makes this heterojunction route highly feasible and promising for use in practical applications.

摘要：Bouc-Wen模型是一种可表征结构及构件刚度、强度退化等的多功能非线性光滑滞回模型,可广泛应用于各类结构滞回行为的描述。自复位摇摆墙(Self-centering rocking wall, SCRW)结构由于其优越的抗震和自复位性能,滞回曲线呈“旗帜型”。为了更好地表征这种“旗帜型”滞回特性,在Bouc-Wen模型的基础上,建立一种具有较高精度和较好实用性的改进Bouc-Wen滞回模型。改进的Bouc-Wen模型参数是决定结构滞回性能力学特征的关键。由于该模型参数众多且选择范围不明确,为适应该类模型参数高效识别的需求,通过在MATLAB/Simulink环境中搭建程序框图,实现了对该理论模型控制参数的定性及定量分析,并运用遗传算法对10个SCRW试验结果进行参数识别,对识别结果进行统计分析,建立各参数与滞回曲线关键点的关系式,基于统计结果给出了各参数的建议取值范围;最后,通过SCRW拟静力试验对改进的滞回模型和参数取值范围进行了验证。结果表明:这种单自由度改进的Bouc-Wen滞回模型能较好地反映SCRW在往复荷载作用下无残余变形和强度、刚度退化特点的“旗帜型”滞回特性。所提出的参数取值范围显著提升了改进Bouc-Wen模型的识别精度与效率,识别过程对类似模型的参数识别具有参考价值。