摘要：Because of public safety problems in construction of urban surroundings,this paper expounds the necessity of the study on public safety-based urban design in perspective of modern *** brings forward the concept of safety-based urban design and attempts to explore the basic connotation and contents with framework for studies.

摘要：The selective hydrogenation of quinolines to 1,2,3,4-tetrahydroquinolines(py-THQ) and its derivatives has attracted a considerable amount of attention as they show great versatility in many pharmaceuticals, agrochemicals, and fine chemicals. Over the past few decades, great breakthroughs have been achieved in the controlled synthesis of efficient heterogeneous catalysts used for the selective hydrogenation of functionalized quinoline compounds, which allow one to correlate the structure-property relationships. In this review, we will summarize the recent significant progress achieved in this field covering the synthetic strategies, microstructural and chemical features, catalytic performance, and internal relationships. State-of-the-art noble metal-based single(Pd, Pt, Ru, Rh, Ir and Au) and bi/multi-metallic catalysts(RuCu, AuPd, and PdNi) are first introduced, followed by a summary of earth-abundant metal-based catalysts(Co, Fe, Ni, and Cu). Finally, the dehydrogenation of N-heterocycles is introduced to form a reversible hydrogenation/dehydrogenation system for H2 storage, which can be employed in a liquid organic hydrogen system. Furthermore, the reaction mechanism and future research direction in these areas are also discussed. This review will deepen our understanding of the catalytic transformation of N-heterocycles and provide guidance for researchers on the rational design of catalysts.

摘要：Active-phase engineering is regularly utilized to tune the selectivity of metal nanoparticles （NPs） in heterogeneous catalysis. However, the lack of understanding of the active phase in electrocatalysis has hampered the development of efficient catalysts for CO2 electroreduction. Herein, we report the systematic engineering of active phases of Pd NPs, which are exploited to select reaction pathways for CO2 electroreduction. In situ X-ray absorption spectroscopy, in situ attenuated total reflection-infrared spectroscopy, and density functional theory calculations suggest that the formation of a hydrogen-adsorbed Pd surface on a mixture of the α- and β-phases of a palladium-hydride core （α＋β PdHx@PdHx） above -0.2 V （vs. a reversible hydrogen electrode） facilitates formate production via the HCOO intermediate, whereas the formation of a metallic Pd surface on the β-phase Pd hydride core （β PdHx@Pd） below -0.5 V promotes CO production via the COOH＂ intermediate. The main product, which is either formate or CO, can be selectively produced with high Faradaic efficiencies （〉90%） and mass activities in the potential window of 0.05 to -0.9 V with scalable application demonstration.

摘要：H‐ZSM‐5 zeolite is a typical catalyst for methanol‐to‐olefins(MTO)*** the performance of zeolite catalysts for MTO conversion is related to the actual location of acid sites in the zeolite framework,the catalytic roles of the acid sites in different pore channels of the H‐ZSM‐5 zeolite are not well *** this study,the MTO reaction network,involving the aromatic cycle,alkene cycle,and aromatization process,and also the diffusion behavior of methanol feedstock and olefin and aromatic products at different acid sites in the straight channel,sinusoidal channel,and intersection cavity of H‐ZSM‐5 zeolite was comparatively investigated using density functional theory calculations and molecular dynamic *** results indicated that the aromatic cycle and aromatization process occurred preferentially at the acid sites in the intersection cavities with a much lower energy barrier than that at the acid sites in the straight and sinusoidal *** contrast,the formation of polymethylbenzenes was significantly suppressed at the acid sites in the sinusoidal and straight channels,whereas the alkene cycle can occur at all three types of acid sites with similar energy barriers and ***,the catalytic performance of H‐ZSM‐5 zeolite for MTO conversion,including activity and product selectivity,can be regulated properly through the purposive alteration of the acid site distribution,viz.,the location of Al in the zeolite *** study helps to elucidate the relation between the catalytic performance of different acid sites in the H‐ZSM‐5 zeolite framework for MTO conversion,which should greatly benefit the design of efficient catalyst for methanol conversion.

摘要：大理地处苍山之麓、洱海之滨,地形西高东低,自古拥有“风花雪月”的美誉。作为以白族为主体的少数民族聚居区,大理地域建筑特色明显,历史古迹得到较好的保护。但古城建设在严格的设计导则规范下,街道建筑面貌也出现了风格趋同现象,雷同有余,传承扬弃不够。

摘要：中国当下的“生态文明建设”和高质量发展理念对建筑业可持续发展提出了更高要求和挑战,建筑业作为我国第一碳排放大户,其碳中和关乎国家“双碳”战略的顺利实施。如何实现传统建筑材料、结构、建造的低碳转型,如何发展“以人为本”的低碳人居环境的能源环境新技术,如何平衡人类生产生活与自然环境的关系等,成为当前亟待解决的问题。本文立足全球视野,基于国家“双碳”目标达成的战略需求和顶层设计,阐述建筑学科的发展现状、趋势和挑战,尝试凝练建筑“双碳”路径相关的关键科学问题,从全过程、全领域、数字化和工程的视角提出未来中国建筑“双碳”的可能实现路径、战略研判和研究重点,以期助力我国生态文明高质量建设与中国式现代化进程。

摘要：基于压电层合结构的有限元方程,运用ANSYS/APDL语言,编制了力-电耦合有限元分析程序(MPFEMP).以该程序为计算基础,采用遗传算法和一阶梯度优化算法,以压电片尺寸为设计变量,以压电层合梁和板的预期位移或最小重量为目标函数,给定初始变量和适应度函数,通过循环迭代MPFEMP计算程序,研究了多点控制的压电层合梁板结构的形状最优控制.结论对比分析证明了两种优化方法分析压电层合结构的有效性,同时,对复杂多层智能结构的最优形状控制和主动控制研究具有一定的参考价值.

摘要：Obtaining a detailed understanding of the surface modification of supports is crucial;however,it is a challenging task for the development and large-scale fabrication of supported electrocatalysts that can be used as alternatives to Pt-based catalysts for the oxygen reduction reaction(ORR).In this study,commercial silicon carbide(SiC)was modified through surface oxidization(O-SiC)to support the use of Pd nanoparticles(Pd NPs)as electrocatalysts for *** obtained Pd/O-SiC catalysts exhibited better ORR activity,stronger durability,and higher resistance to methanol poisoning than that exhibited by commercial Pt/*** role of the support in enhancing the ORR performance,especially the oxidization of SiC surfaces,was discussed in detail based on the experimental characterizations and density functional theory *** underlying mechanism of the superior ORR performance of Pd/O-SiC catalysts was attributed to the charge transfer from SiC_(x)O_(y)to Pd NPs on the surfaces of SiC and the strong metal–support interactions(SMSIs)between Pd and SiC_(x)O_(y).The charge transfer enhanced the ORR activity by inducing electron-rich Pd,increased the adsorption of the key intermediate OOH,and decreased the Gibbs free energy of the critical ORR ***,SMSIs enhanced the ORR stability of the Pd/O-SiC *** study provided a facile route for designing and developing highly active Pd-based ORR electrocatalysts.

摘要：为解决北衙金矿在使用预裂爆破技术时整体爆破效果不佳的问题,基于RHT损伤本构模型,利用ANSYS/LS-DYNA数值模拟软件,开展了不同孔距下预裂爆破的数值模拟研究。结果表明:当预裂孔炮孔间距为120 cm时,孔间裂纹存在较为明显的分叉,且裂纹扩展范围较大;当炮孔间距为130 cm时,裂纹向四周扩展的范围减小,且炮孔周围岩石的损伤程度明显降低;当炮孔间距增加至140 cm时,相邻预裂孔连线上的裂纹仅在局部连通,无法实现孔间贯穿。上述结果说明,130 cm的炮孔间距在降低预裂爆破自身对岩体的扰动与实现有效爆破成缝之间达到了平衡。基于数值模拟试验结果开展了现场试验,爆破效果良好。研究结果可为矿山的预裂爆破设计和施工提供参考。

摘要：Electrocatalytic ammonia synthesis under mild conditions is an attractive and challenging process in the earth’s nitrogen cycle,which requires efficient and stable catalysts to reduce the *** N2 activation and reduction overpotential of different Ti3C2O2-supported transition metal(TM)(Sc,Ti,V,Cr,Mn,Fe,Co,Ni,Cu,Zn,Mo,Ru,Rh,Pd,Ag,Cd,and Au)single-atom catalysts have been analyzed in terms of the Gibbs free energies calculated using the density functional theory(DFT).The end-on N2 adsorption was more energetically favorable,and the negative free energies represented good N2 activation performance,especially in the presence Fe/Ti3C2O2(﹣0.75 eV).The overpotentials of Fe/Ti3C2O2,Co/Ti3C2O2,Ru/Ti3C2O2,and Rh/Ti3C2O2 were 0.92,0.89,1.16,and 0.84 eV,*** potential required for ammonia synthesis was different for different TMs and ranged from 0.68 to 2.33 *** possible potential-limiting steps may be involved in the process:(i)hydrogenation of N2 to*NNH and(ii)hydrogenation of*NH2 to *** catalysts can change the reaction pathway and avoid the traditional N–N bond-breaking *** also simplifies the understanding of the relationship between the Gibbs free energy and overpotential,which is a significant factor in the rational designing and large-scale screening of catalysts for the electrocatalytic ammonia synthesis.