摘要：The development of a high-performing pseudocapacitor requires a comprehensive understanding of electrode materials from the aspects of electron transfer and electrolyte ion adsorption and ***,these factors are considered over the prototype TiO_(2),and a high pseudocapacitance is achieved via the introduction of various defects,i.e.,oxygen defect(V_(O))and co-doped defect(V_(O)+N_(O)).The study is based on joint explorations of first-principle calculations and the transfer matrix *** to pristine TiO_(2)(300 F g^(-1)),defective TiO_(2) produces pseudocapacitance as high as 1700 F g^(-1).Moreover,defects induce small barriers for electron transmission caused by surface band *** climbing image nudged elastic band diffusion of H ions displays a much higher barrier in TiO_(2)-V_(O) than in TiO_(2)-V_(O)+N_(O).Such a result indicates easy H diffusion in the co-doped *** work provides insights into the adsorption and diffusion of electrolyte ions and the influence of defects on electron *** results are also significant for the design and optimization of electrode materials for the next generation of supercapacitors.

摘要：本文围绕明代时期陶瓷中的人物题材展开研究,通过对青花瓷、五彩瓷、斗彩瓷等主要瓷器类型的人物画进行分析,揭示了这些在明代的发展与特点。明代陶瓷上的人物画题材,对后世工艺美术的传承与发展起到了举足轻重的推动作用。它不仅在陶瓷艺术领域内持续绽放光彩,产生深远的影响,而且其艺术精髓跨越媒介,波及并丰富了后世的漆器制作、织物设计等多样工艺形式,充分展现了这一历史时期艺术表达的广泛渗透力与深远的文化价值。

摘要：Nanofibers can mimic natural tissue structure by creating a more suitable environment for cells to grow,prompting a wide application of nanofiber *** this review,we include relevant studies and characterize the effect of nanofibers on mesenchymal stem cells,as well as factors that affect cell adhesion and osteogenic *** hypothesize that the process of bone regeneration in vitro is similar to bone formation and healing in vivo,and the closer nanofibers or nanofibrous scaffolds are to natural bone tissue,the better the bone regeneration process will *** general,cells cultured on nanofibers have a similar gene expression pattern and osteogenic behavior as cells induced by osteogenic supplements in *** involved in cell adhesion(focal adhesion kinase(FAK)),cytoskeletal organization,and osteogenic pathways(transforming growth factor-β(TGF-β)/bone morphogenic protein(BMP),mitogen-activated protein kinase(MAPK),and Wnt)are upregulated *** adhesion and osteogenesis may be influenced by several *** possess certain physical properties including favorable hydrophilicity,porosity,and swelling properties that promote cell adhesion and ***,nanofiber stiffness plays a vital role in cell fate,as cell recruitment for osteogenesis tends to be better on stiffer scaffolds,with associated signaling pathways of integrin and Yes-associated protein(YAP)/transcriptional co-activator with PDZ-binding motif(TAZ).Also,hierarchically aligned nanofibers,as well as their combination with functional additives(growth factors,HA particles,etc.),contribute to osteogenesis and bone *** summary,previous studies have indicated that upon sensing the stiffness of the nanofibrous environment as well as its other characteristics,stem cells change their shape and tension accordingly,regulating downstream pathways followed by adhesion to nanofibers to contribute to ***,additional experiments are needed to id

摘要：The multi-pass scheduling method is a key issue in die-less spinning for determining the quality of the final products, including their shape deviations and wall thicknesses, and has drawn increasing interest in recent studies devoted to trying to improve the accuracy of the formed parts. In this paper, two main parameters, roller path profiles and deformation allocations in each pass, are considered in newly proposed multi-pass scheduling and optimizing methods in die-less spinning. Four processing methods with different roller path profiles and with three deformation allocation methods are proposed for investigating the influence of scheduling parameters on product qualities. The ＇similar geometry principle for restraining shape deviation＇ and the ＇small curvature principle for maintaining wall thickness＇ are presented for optimal design of roller path profiles; in addition, the ＇uniform allocation principle for maintaining wall thickness＇ and the ＇large deformation principle for restraining shape deviation＇ are brought forward as suggestions for deformation allocations. Based on these principles, a scheduling method denoted by RF＋（FP ＆ EHS） is presented to improve the comprehensive quality of a product of die-less spinning.

摘要：针对现阶段运行状态下风力机叶片振动测量方法中,加速度传感器常布设到风力机机头靠近风轮处,导致测量结果易受干扰的问题。基于叶片受力分析和应变模态理论,将叶片上应变传感器采集的原始信号分解为叶片应变信号与振动信号的叠加,设计一种基于应变模态理论和变分模态分解的叶片振动感知方法。通过设计静态模态实验和模拟动态偏航的叶片振动实验,对叶片表面应变和机头振动信号进行对比分析,表明叶片振动感知方法在频域和时频域上均能正确识别叶片振动特征,且其谱线更清晰,受干扰更小,从而为动态偏航运行工况下风力机叶片振动测量提供了一种新方法,可为风力机叶片安全、可靠运行提供技术支持。

摘要：气凝胶是一类兼具重要科学研究意义和巨大工程化应用价值的纳米多孔材料,其制备过程涉及溶胶-凝胶化学转变、结构调控、界面张力消除等基础科学问题,在理化性能方面同时具有超低密度和超低热导率特性,是一类理想的轻量化超级隔热保温材料,在航空航天、交通运输等对重量要求严苛的应用领域极具吸引力.此外,得益于气凝胶的高比表面积、高孔隙率、连续开孔等结构特征,其在吸附、催化、药物载体、能源和环境修复等领域也具有重要应用潜力.因此,近年来气凝胶及其应用获得国内外学术和产业界的极大研究兴趣.本综述调研了自气凝胶首次报道以来相关文献与知识产权的概况,而后以制备方法、气凝胶种类、维度结构设计、新型应用为轴,系统概括了气凝胶的制备方法,新型气凝胶的种类,以维度为特色的气凝胶材料,以及气凝胶的独特应用.如近五年来涌现的新型超分子气凝胶、智能响应气凝胶、气凝胶纤维、气凝胶的增材制造等,都在一定程度上颠覆了传统材料、突破了传统制备方法的局限.最后对气凝胶近年来的发展做了简要总结和展望.

摘要：目的:探究错距旋压仿真模型关键特性参数影响,改进建模方法,克服现有模型方案的缺陷,构建更准确、可靠和稳定的错距旋压有限元仿真模型。创新点:1.提供包括全模型、六面体离散、速度边界、全仿真、双精度和无干涉模型等在内的改进有限元模型构建方法;2.基于所构建的改进模型,完善错距值对成型过程影响的现有结论。方法:1.通过能量、网格独立性和过程参数分析,验证改进有限元模型的可行性和可靠性;2.通过对比仿真和数据分析,获得边界模式、精度模式、时间截断和错距干涉对仿真结果的影响;3.通过仿真模拟,完善现有受干涉、单精度、时间截断和位移边界影响的错距值研究成果。结论:1.速度边界模式较之位移边界模式具有更高的计算精度和效率;2.时间截断不能确保获取稳态结果,不利于计算的准确性和稳定性;3.截断误差对错距旋压成型结果影响显著,计算过程中应采用双精度模式;4.错距干涉严重干扰计算的正确性和可靠性,应在实验设计阶段予以排除;5.针对现有错距值研究受干涉、单精度、时间截断和位移边界影响的现状,基于改进模型,完善错距影响结论(表11)。

摘要：The differential distribution between cancer cells and normal adult tissues makes survivin a very attractive cancer drug target. We have previously reported a series of novel selective survivin inhibitors with the most potent compound MX 106 reaching nanomolar activity in several cancer cell lines. Further optimization of the MX 106 scaffold leads to the discovery of more potent and more selective survivin inhibitors. Various structural modifications were synthesized and their anticancer activities were evaluated to determine the structure activity relationships for this MX 106 scaffold. In vitro anti-proliferative assays using two human melanoma cell lines showed that several new analogs have improved potency compared to MX 106. Very interestingly, these new analogs generally showed significantly higher potency against P-glycoprotein overexpressed cells compared with the corresponding parental cells, suggesting that these compounds may strongly sensitize tumors that have high expressions of the Pglycoprotein drug efflux pumps. Western blotting analysis confirmed that the new MX 106 analogs maintained their mechanism of actions by selectively suppressing survivin expression level among major inhibitors of apoptotic proteins and induced strong apoptosis in melanoma tumor cells.

摘要：磁流变介质在服役过程中受温升、磁场、持续剪切的多场耦合作用,其作用引起流变学行为规律不明并难以准确预测。由于反向传播(BP)神经网络存在容易收敛于局部极值的问题,通过建立麻雀搜索算法(SSA)优化BP神经网络的高温热效应磁流变脂流变性能预测模型,用于表征和预测实验温度、磁场、热效应时间、剪切速率与磁流变脂流变学性能之间的关系。结果表明:高磁场下,磁链大量聚拢受到皂纤维的阻碍较小,磁流变脂剪切应力大幅增加。高温热效应对磁流变脂复合结构造成了一定破坏,表现为MRG-24h在各实验条件下的剪切速率曲线整体较低。BP预测模型在评估局部离散性较大的数据时,出现R2为负值的低泛化性能表现,而SSA-BP预测模型对于整体不同数据集和局部离散性较小、较大的数据进行预测性能评估时,仍具有较高的预测精度。SSA-BP预测模型可以为磁流变脂流变性能预测,并为磁流变器件的设计和研发提供数据支持。

摘要：本研究以微量碳纳米管(CNT)构建导电弹性体,采取少量被修饰后的CNT与硅橡胶(PDMS)复合成弹性温敏传感材料。研究发现,经KH570修饰后的CNT表面范德华力被降低,其与PDMS具有良好的界面作用力。微观表征显示,CNT均匀地分散在PMDS中。在添加3%的修饰后的CNT时,复合材料的电导率达到0.625 mS·m^(-1)。相对于纯PDMS材料,含有少量被修饰后CNT的复合材料的拉伸断裂率没有出现显著下降。在60~100℃,复合材料的温度传感性能呈现高线性度。