摘要：We propose a single-poly MTP （multi-time programmable） cell consisting of one capacitor and two transistors based on MagnaChip＇s BCD process. The area of a unit cell is 37.743 75μm^2. The proposed single-poly MTP cell is erased and programmed by the FN tunnelling scheme. We design a 256 bit MTP memory for PMICs （power management ICs） using the proposed single-poly MTP cells. For small-area designs, we propose a selection circuit between V10V and VSV, and a WL （word-line） driver by simplifying its logic circuit. We reduce the total layout area by using pumped internal node voltages from a seven-stage cross-coupled charge pump for V10V （=10 V） and V5V （=5 V） without any additional charge pumps. The layout size of the designed 256 bit MTP memory is 618.250 μm × 437.425μm.

摘要：气候变化威胁人类的生存.化石燃料的过度使用导致CO_(2)持续排放是引起全球变暖和气候变化的主要因素,须尽快减少CO_(2)排放.捕获CO_(2)并将其转化为高附加值的燃料和化学品从而循环利用是减少CO_(2)净排放的有效措施.其中,CO_(2)催化加氢制甲酸(HCOOH)是碳捕获与利用(CCU)的有效途径之一,其产物HCOOH可用于防腐剂、牲畜饲料抗菌剂和食品添加剂,也可作为氢载体和直接甲酸燃料电池的燃料.目前,工业上生产HCOOH的工艺包括两个步骤:甲醇和CO在强碱条件下反应生成甲酸甲酯(HCO_(2)CH_(3)),随后水解为HCOOH.该工艺利用来自化石燃料的两种原料,排放出大量CO_(2),同时在水解步骤中使用了过量的酸性水,因此对生态环境产生一定的危害.近年来,以CO_(2)为可再生原料合成HCOOH被广泛研究,人们探索了电化学、光化学、生物和热化学反应等多种途径将CO_(2)还原为HCOOH,以期实现CO_(2)循环利用.上述方法距实际应用尚有一定距离,其中,CO_(2)催化加氢制HCOOH过程最先进,它与当前许多化学工业过程相似.由于CO_(2)分子的化学稳定性,CO_(2)加氢生成HCOOH在热力学上不利,可通过有机碱和无机碱形成甲酸-碱配合物,推动反应向生成HCOOH方向移动.然而,从甲酸基配合物中提取HCOOH需要额外的分离步骤,因此在无碱条件下直接将CO_(2)加氢生成HCOOH非常重要.本课题组致力于研究无碱条件下g-C_(3)N_(4)负载的Pd(记为Pd/CN)催化剂催化CO_(2)加氢合成HCOOH,前期研究(***.,2016,52,14302-14305和***.,2021,396,395-401)发现,通过控制Pd负载量可改变催化剂中Pd单原子/Pd纳米团簇的比例,且当两种状态Pd达到最佳比例时,催化剂催化活性最高.这表明在无碱CO_(2)加氢过程中,Pd单原子与纳米团簇间存在协同作用.此外,最近有关于单原子和纳米团簇在负载金属催化剂中不同作用的报道,如NixMg1-xO催化逆水气变换反应,Ir1/In_(2)O_(3)和Pd/Fe_(3)O_(4)催化CO_(2)加氢制乙醇反应等,这些工作得出相似的结论:单原子金属对CO_(2)活化有效,而纳米团簇对H_(2)活化有效.这对于设计以CO_(2)和H_(2)为反应物的金属催化剂很重要.本工作旨在考察类似的机理是否适用于Pd/CN催化剂在无碱条件下催化CO_(2)加氢制HCOOH过程.通过控制Pd负载量,合成了含有不同比例Pd单原子和Pd纳米团簇的Pd/CN催化剂,Pd与g-C_(3)N_(4)表面碱性位间的强静电相互作用使合成含有大量Pd单原子的Pd/CN催化剂成为可能.在Pd/CN催化剂催化无碱CO_(2)加氢制HCOOH过程中,当两种状态Pd达到最佳比例时,Pd单原子和Pd纳米簇之间存在协同作用,此时催化剂活性最高.实验表明,Pd纳米簇主要通过解离吸附参与H_(2)活化,Pd单原子对CO_(2)活化更有效.在最佳单原子比(单原子数/(单原子数+纳米簇)为41%)时,该催化剂表现出最高的活性,优于文献报道的相似反应条件下Pd催化剂活性.这些发现将为以CO_(2)和H_(2)分子为反应物的反应的催化剂设计提供一定的参考.

摘要：As the first invention to efficiently harvest electricity from ambient mechanical energy by using contact electrification, the triboelectric nanogenerator has elicited worldwide attention because of its cost-effectiveness and sustainability. This study exploits a superhydrophobic nanostructured aluminum tube to estimate electrical output for solid-water contact electrification inside a tubular system. The linearly proportional relationship of short-circuit current and open-circuit voltage to the detaching speed of water was determined by using a theoretical energy harvesting model and experimentation. A pioneering stick-type solid-water interacting triboelectric nanogenerator, called a SWING stick, was developed to harvest mechanical energy through solid-water contact electrification generated when the device is shaken by hand. The electrical output generated by various kinds of water from the environment was also measured to demonstrate the concept of the SWING stick as a compact triboelectric nanogenerator. Several SWING sticks were connected to show the feasibility of the device as a portable and compact source of direct power. The developed energy harvesting model and the SWING stick can provide a guideline for the design parameters to attain a desired electrical output; therefore, this study can significantly increase the applicability of a water-driven triboelectric nanogenerator.

摘要：A DC-DC converter for flash memory IPs performing erasing by the FN (Fowler-Nordheim) tunneling and programming by the CHEI (channel hot electron injection) is designed in this paper. For the DC-DC converter for flash memory IPs using a dual voltage of VDD (=1.5V±0.15V)/VRD (=3.1V±0.1V), a scheme of using VRD (Read Voltage) instead of VDD is proposed to reduce the pumping stages and pumping capacitances of its charge pump circuit. VRD (=3.1V±0.1V) is a regulated voltage by a voltage regulator with an external voltage of 5V, which is used as the WL activation voltage in the read mode and an input voltage of the charge pump. The designed DC-DC converter outputs positive voltages of VP6V (=6V), VP8V (=8V) and VP9V(=9V);and a negative voltage of? VM8V (=-8V) in the write mode.