摘要：Metal corrosion causes billions of dollars of economic losses *** a smart and new energy-harvesting device,triboelectric nanogenerators(TENGs)can convert almost all mechanical energy into electricity,which leads to great prospects in metal corrosion prevention and cathodic *** this work,flexible TENGs were designed to use the energy harvested by flexible polydimethylsiloxane(PDMS)films with ZrB_(2)nanoparticles and effectively improve the dielectric constant by incorporating ZrB_(2).The open-circuit voltage and short-circuit current were 264 V and 22.9μA,respectively,and the power density of the TENGs reached 6 W·m^(-2).Furthermore,a selfpowered anti-corrosion system was designed by the rectifier circuit integrated with TENGs,and the open-circuit potential(OCP)and Tafel curves showed that the system had an excellent anti-corrosion effect on carbon ***,the system has broad application prospects in fields such as metal cultural relics,ocean engineering,and industry.

摘要：Parallel operation of distributed generation is an important topic for microgrids, which can provide a highly reliable electric supply service and good power quality to end customers when the utility is unavailable. However, there is a well-known limitation： the power sharing accuracy between distributed generators in a parallel operation. Frequency and voltage droop is a well-established control method for improving power sharing performance. In this method, the active and reactive power calcu- lations are used to adjust the frequency and amplitude of the output voltage. This paper describes the digital implementation of a droop method, and analyzes the influence of power calculation on droop method performance. According to the analysis, the performance of droop control in a digital control system is limited by the accuracy and speed of the power calculation method. We propose an improved power calculation method based onp-q theory to improve the performance of the droop control method, and we compare our new method with two traditional power calculation methods. Finally, simulation results and experimental results from a three single-phase l-kW-inverter system are presented, which validate the performance of our proposed method.

摘要：A series of novel 1,3,5-thiadiazine-2-thione derivatives bearing a hydrazide moiety were designed, synthesized and evaluated for their antifungal activities against Rhizoctonia solani (Rs), Fusarium graminearum (Fg), Botrytis cinerea (Bc) and Colletotrichum capsici (Cc). The in vitro antifungal bioassays indicated that most of title compounds displayed good selectivity and specificity aganist Rs relative to Fg, Bc and Cc. Strikingly, the title compound N'-(4-chlorophenyl)-2-(5-phenyl-6-thioxo-1,3,5-thiadiazinan-3-yl)acethydrazide (5b) obviously inhibited the Rs growth in vitro with the EC50 value of 0.24μg/mL, which is approximately 2-folds more effective than the commercialized fungicide carbendazim (0.55 μg/mL). The in vivo anti-Rs effects of title compound 5b were further evaluated on rice leaves with control efficacies of 98.58% at 200 μg/mL and 61.27% at 100 μg/mL. The above researches provide a significant reference for the further structural optimization of 1,3,5-thiadiazine-2-thione derivatives bearing a hydrazide moiety as potential fungicides.

摘要：近50年来,烯烃聚合的研究在学术界以及工业界都取得了巨大的成功.聚烯烃年产量巨大、用途广泛,但是其最大的缺点之一是其非极性的特点.在聚烯烃中引入少量的极性官能团可以极大地改善其性质、拓宽其用途、提高其商业价值.通过过渡金属催化剂来实现烯烃与极性单体的共聚反应是合成官能团化聚烯烃材料最直接的途径,但是也具有非常大的挑战性.针对极性单体这一科学问题,本专论主要围绕我们课题组的工作,从以下几个方面进行了论述:已知催化剂体系的改进、全新催化剂体系的发展、新型聚合调控手段的设计、特种聚烯烃以及官能团化聚烯烃材料的制备与性质研究.

摘要：Electrocatalytic reduction of CO_(2)(CO_(2)RR)to multicarbon products is an efficient approach for ad-dressing the energy crisis and achieving carbon *** H-cells,achieving high-current C_(2)products is challenging because of the inefficient mass transfer of the catalyst and the presence of the hydrogen evolution reaction(HER).In this study,dendritic Cu/Cu_(2)O with abundant Cu^(0)/Cu^(+)interfaces and numerous dendritic curves was synthesized in a CO_(2)atmosphere,resulting in the high selectivity and current density of the C_(2)*** Cu/Cu_(2)O achieved a C_(2)Faradaic efficiency of 69.8%and a C_(2)partial current density of 129.5 mA cm^(-2)in an *** element simulations showed that a dendritic structure with a high curvature generates a strong electric field,leading to a localized CO_(2)***,DRT analysis showed that a dendritic struc-ture with a high curvature actively adsorbed the surrounding high concentration of CO_(2),enhancing the mass transfer rate and achieving a high current *** the experiment,the impact of the electronic structure on the performance of the catalyst was investigated by varying the atomic ratio of Cu^(0)/Cu^(+) on the catalyst surface,which resulted in improved ethylene *** the optimal atomic ratio of Cu^(0)/Cu^(+),the charge transfer resistance was minimized,and the desorption rate of the intermediates was low,favoring C_(2) *** functional theory calculations indicated that the Cu^(0)/Cu^(+) interfaces exhibited a lower Gibbs free energy for the rate-determining step,enhancing C_(2)H_(4) *** Cu/Cu_(2)O catalyst also exhibited a low Cu d-band center,which enhanced the adsorption stability of *CO on the surface and facilitated C_(2)*** observa-tion explained the higher yield of C_(2) products at the Cu^(0)/Cu^(+) interface than that of H_(2) under rapid mass *** results of the net present value model showed that the H-c

摘要：实现高效、低成本的太阳能光催化全分解水制氢是解决当前环境污染和化石能源过度使用等问题的理想方案.然而,目前光催化分解水的转化效率(低于10%)普遍较低,这成为其实际应用的主要障碍.从太阳光谱的响应范围来看,现有的光催化剂大多局限于紫外光或可见光区域,而近红外光区的光催化剂开发仍然非常有限.尽管近红外光在太阳光谱中占比超过一半,蕴含着巨大的能源潜力,但遗憾的是,目前大部分光催化剂无法在该波段实现高效的光催化反应.根据理论预测,光分解水的转化效率有望随着催化剂响应太阳光波长范围的扩大而显著提高.因此,如何最大限度地利用太阳能,特别是近红外光区域的光能,开发高效的近红外光响应光催化全解水制氢催化剂,已成为当前能源、环境、化学工程领域研究的热点.本文综述了近红外光驱动全分解水光催化剂在材料设计和调控方面的最新进展,涉及窄带隙半导体、带隙工程、上转换效应、局域表面等离子体效应和光敏化作用等策略.首先,从热力学和动力学的角度分析了近红外光驱动全分解水的难点:对于大多数半导体而言,要实现近红外驱动全分解水不仅要求理论带隙窄于1.77 eV,而且必须超过水氧化还原分解电位(1.23 eV),同时由于存在电位损失和动力学过电位,实际的带隙结构应在1.6–2.4 eV,这对半导体的能带结构提出了较为苛刻的要求.此外,全分解水反应的可逆性、溶解氧的影响以及材料的光稳定性问题也是实现近红外光驱动全分解水的挑战.其次,总结了各方法制备的催化剂全分解水制氢的性能,分析了其近红外光子捕获方法的优缺点,特别指出了如何在每种方法的基础上进一步促进光生载流子的分离以及近红外光子的捕获能力(比如:负载贵金属单原子助催化剂、多种方法结合构筑多元复合体系以及光催化剂表面优化等).同时,强调了在近红外驱动全分解水过程中材料特征、催化性质与功能机理三者之间的关系.尤其是利用等离子体效应和光敏化作用来实现近红外光驱动全分解水的机理,目前尚不明确,需要结合理论计算以及先进的时空分辨仪器进一步研究电荷转移机制.另外,总结了全光谱响应的全分解水制氢光催化剂在材料设计和调控方面的最新进展,包括:光敏化作用的应用、带隙调控的策略、局域表面等离子体效应的研究,以及乌尔巴赫带尾吸收捕获技术的探索.最后,归纳并展望了未来近红外驱动全分解水光催化剂所面临的挑战与机遇.尽管近年来国内外学者们围绕着近红外驱动全分解水制氢光催化剂开展了系列研究工作,取得了一些突破性进展,但近红外驱动全分解水制氢效率仍然较低以及对于近红外响应光催化剂的设计和调控方面仍然面临着许多挑战.如何设计和开发廉价、稳定且高效的近红外驱动全分解水制氢光催化剂仍需进一步探索.因此,未来需要结合不同构筑方法的优势来加强近红外区的光捕获能力、实现多元复合材料界面间的精准调控、通过高端原位时空分辨仪器以及理论计算剖析近红外驱动全分解水的过程等方面对近红外响应光催化材料进行深入研究.

摘要：The mobile APP for medication guidance related to pharmacogenomic is developed to solve various practical problems, such as inconvenient reading of English database, slow updating of paper reference books and lack of shortcut for *** extracted the medication guidance information related to the pharmacogenomic from ‘Dosing Guidelines’(http://***), ′Table of Pharmacogenomic Biomarkers in Drug Labeling′(http://***/drugs/scienceresearch) and relevant authoritative *** was used to build the medication guidance information *** designed and implemented a mobile APP for medication guidance by JavaScript programming *** APP contained 197 drugs that have been extensively studied and have high levels of *** covered 25 categories, such as anticoagulant and antiplatelet drugs, general antitumor, immunosuppressant drugs, targeted antitumor drugs, antipsychotic drugs, antiepileptic drugs, and proton pump inhibitors and so *** can obtain clinical significance and guidance information related to the genotype of the drug by entering the pinyin initials of the generic name of the *** mobile APP for medication guidance related to pharmacogenomic based on APICloud could provide practical and convenient pharmaceutical information service for clinical use.

摘要：为了提升机器人通信系统多时钟同步性能,通过对分布式时钟同步补偿方案进行研究,设计时钟误差定量补偿与动态补偿算法,采用基于IgH EtherCAT通信协议栈实现同步补偿方案,最后在六轴机械臂上开展轨迹跟踪与通讯性能测试。结果表明,与非IgH同步方案相比,该同步方案的应用提高了机械臂末端执行器的轨迹圆精度。时钟同步误差降至54 ns,同步误差容许范围在±200 ns以内。可见补偿方案提高了时钟同步性能,满足机械臂的应用需求。

摘要：声动力治疗是在光动力治疗基础上发展起来的一种新型癌症无创治疗技术,相对于光动力治疗具有无创、穿透性强、特异性好、安全性高等诸多优点.声动力治疗利用声敏剂与氧在超声作用下产生具有生物毒性的活性氧,起到杀伤肿瘤细胞的作用,但其具体作用机制还在进一步的研究中.声动力治疗目前在治疗超声参数设置、肿瘤定位及定点治疗、温度监测以及活性氧检测等方面还存在诸多问题.为使声动力治疗方法在科研和临床应用中取得更好的效果,科学合理的声动力治疗装置是不可或缺的.目前声动力治疗大多采用具有普适性的超声治疗仪,缺乏针对性.因此,根据声动力治疗的特点改进已有的超声设备,或设计专用的声动力治疗装置有利于更好地监测和调控声动力治疗过程,使声动力治疗得到更加稳定可靠的效果,推动其在科研和临床中的应用.本文从上述声动力治疗中存在的问题出发,介绍了声动力治疗装置的关键结构及其技术发展,对声动力治疗装置的研究现状进行了分析和展望.

摘要：In this paper, we extend a novel unconstrained multiobjective optimization algorithm, so-called multiobjective extremal optimization （MOEO）, to solve the constrained multiobjective optimization problems （MOPs）. The proposed approach is validated by three constrained benchmark problems and successfully applied to handling three multiobjective engineering design problems reported in literature. Simulation results indicate that the proposed approach is highly competitive with three state-of-the-art multiobjective evolutionary algorithms, i.e., NSGA-11, SPEA2 and PAES. Thus MOEO can be considered a good alternative to solve constrained multiobjective optimization problems.