摘要：The development of low-cost,highly active platinum(Pt)-based electrocatalysts for oxygen reduction reaction(ORR)is crucial for widespread applications of fuel *** effective approach lies in alloying Pt with non-noble transition metals to modulate the physicochemical state of the Pt ***,fundamental challenges remain in understanding the structure-performance relationship due to the complexity of composition,crystal type,and surface structure during the alloying *** this study,we synthesized a series of PtCo bimetallic solid solutions with varying ratios using a liquid-phase synthesis *** exploiting the characteristics of solid solutions,the resulting PtCo bimetallic alloy maintains the face-centered cubic crystal structure of pure platinum,minimizing the complexities introduced during alloying and facilitating mechanism ***,under controlled alloy composition and crystal structure,we investigated the dependence of the electrocatalytic activity for the oxygen reduction reaction on the surface strain of the platinum *** s-PtCo-sNPs cathode designed accordingly endows both proton exchange membrane fuel cell(PEMFC)(2.08 W cm^(−2) at 4 A cm^(−2))and Zn-air battery(ZAB)(143.1 mW cm^(−2) at 214.5 mA cm^(−2))with outstanding performance.

摘要：Ab initio total energy calculations are used to determine the interface structure of GaN films grown on 6H-siC(0001)with different substrate *** results indicate that GaN films grown on bare siC(0001)are of the Ga-polarity,while GaN films grown on siC(0001)with si adlayer are of the N-polarity if there is no N-si interchange at the *** the interchange,the GaN films are of the Ga-polarity.