摘要：To increase the service life of rechargeable batteries,transition metal oxide hosts with high structural stability for the intercalation of carrier ions are ***,we reconstruct the crystal structure of a commercial V_(2)O_(5)by pre-intercalating H^(+)and H_(2)O pillars using a facile hydrothermal reaction and obtain a bi-layer structured H_(0.642)V_(2)O_(5)·0.143H_(2)O(HVO)as an excellent host for aqueous Zn-ion *** from the structural reconstruction,the irreversible“layer-to-amorphous”phase evolution during cycling is considerably less,resulting in ultra-high cycling stability of HVO with nearly no capacity fading even after 500 cycles at a current density of 0.5Ag^(-1).Moreover,a synthetic proton and Zn^(2+)intercalation mechanism in the HVO host is *** work provides both a facile synthesis method for the preparation of V-based compounds and a new viewpoint for achieving high-performance host materials.

摘要：针对传统移动监控方式智能化程度低造成操控难度和工作强度大以及本地数据管理困难的问题,面向业界对室内外移动平台统一性的迫切需求,提出了一种云端服务资源和本地自主机器人结合的系统架构。首先,给出系统结构,包括:1)为系统提供自主行为能力的自主移动机器人端,实现室内/外无缝导航、图像/视频推送等;2)提供人机和远程交互的远程监控端;3)为室内/外运行提供统一数据传输和管理通路的云数据服务边。然后,对系统进行任务架构设计,根据监控数据传输特点,采用两套商用云平台实施云数据处理任务,并为两端子系统设计了带有云交互功能的任务栈。在此基础上,结合多项云服务设计了系统软件架构。最后,采用“上下位机-协处理器-功能模块”方式设计实现自主移动机器人端硬件系统,基于机器人操作系统(ROS)节点模型构建该端软件系统;远程监控端上,主要设计图形用户界面和信息交互逻辑。实验结果表明,所设计系统仅需少量控制指令便可远距离实现室内、外环境的连续监控,且操控工作强度被有效降低,压力测试中系统指令往返时延一般不超过160 ms,多时段测试中视频码率不低于1 Mb/s,均表明系统具备应用实时性和可靠性。