摘要：Exploration of new infrared(IR) nonlinear optical(NLO) materials is still in urgency owing to the indispensable roles in optoelectronic devices, resource exploration, and long-distance laser communication. The formidable challenge is to balance the contradiction between wide band gaps and large second harmonic generation(SHG) effects in IR NLO materials. In the present work, we proposed new kinds of NLO active units, d^0 transition metal fluorooxofunctional groups for designing mid-IR NLO materials. By studying a series of d^0 transition metal oxyfluorides(TMOFs),the influences of fluorooxo-functional groups with different d^0 configuration cations on the band gap and SHG responses were explored. The results reveal that the fluorooxo-functional groups with different d^0 configuration cations can enlarge band gaps in mid-IR NLO materials. The first-principles calculations demonstrate that the nine alkali/alkaline earth metals d^0 TMOFs exhibit wide band gaps(all the band gaps >3.0 e V), large birefringence Δn(> 0.07), and two W/Mo TMOFs also exhibit large SHG responses. Moreover, by comparing with other fluorooxo-functional groups, it is found that introducing fluorine into building units is an effective way to enhance optical performance. These d^0 TMOFs with superior fluorooxo-functional groups represent a new exploration family of the mid-IR region, which sheds light on the design of mid-IR NLO materials possessing large band gap.

摘要：冰川监测是冰冻圈科学研究中的一项重要基础内容,获取高质量冰川DEM和DOM数据是研究的基础。随着无人机技术的兴起,给冰川监测提供了全新的技术手段,然而冰川区开展无人机摄影测量时,地面控制点的布设与测量成为能否获取高精度数据产品的关键,而山地冰川往往伴随着地形复杂,行走困难,野外实地测量难以全面实施等不利因素。本研究中以位于祁连山西段大雪山地区的老虎沟12号冰川末端部分为研究区域,设计实施了多种控制点布设方案,使用低空微型无人机飞行3个架次,获取研究区航摄影像。通过对比控制点在不同分布情况及数量情况下,DEM和DOM数据检查点的精度,评价不同控制点布设方案的可行性。对比结果显示,在航飞过程中使用单格网模式即可获取高精度的影像数据;实施地面控制作业时,使用5—7个控制点均匀分布在测量区即可获取较高精度的图像数据;当冰川区不能满足均匀布设控制点时,可沿冰川主流线布设足够数量的控制点,所得图像精度也可以满足冰川学研究要求;若只能在冰川中下部或者中上部布设控制点,则控制点应覆盖冰面起伏较大的区域。