摘要：α-Diimide catalysts have attracted widespread attention due to their unique chain walking characteristics.A series ofα-diimide nickel/palladium catalysts with different electronic effects and steric hindrances were designed and synthesized for olefin *** this work,we synthesized a series of asymmetricα-diimide nickel complexes with different steric hindrances and used them for ethylene *** nickel catalysts have high ethylene polymerization activity,up to 6.51×10^(6)g·mol^(−1)·h^(−1),and the prepared polyethylene has a moderate melting point and high molecular weight(up to 38.2×10^(4)g·mol^(−1)),with a branching density distribution between 7 and 94 branches per 1000 *** importantly,the polyethylene prepared by these catalysts exhibits excellent tensile properties,with strain and stress reaching 800%and 30 MPa,respectively.

摘要：定量分析减少径流和改变水沙关系在泥沙调控中的不同作用,对于深刻理解径流调控措施的水土保持效益具有重要意义。以黄土区工程堆积体陡坡坡面(36°)为例,探讨了野外模拟径流冲刷试验条件下,不同工程措施及其组合调控坡面径流的水沙效应及其作用效率。结果表明:1)不同工程措施均能较好地调控坡面径流侵蚀过程,不同情形下的产流时间控制比为2~20,径流量控制比为0.45~0.78,产沙量控制比为0.20~0.59;平均含沙量控制比为0.38~0.79;2)减流控沙作用是工程措施调控坡面侵蚀产沙的主要原因,水沙关系调沙作用则受减流控沙作用的制约;3)水平阶类措施的水沙关系调沙量与减流控沙量呈线性正相关,当减流控沙量超过一定临界值时,水沙关系才开始发挥调沙作用;水平沟类措施的水沙关系调沙量与减流控沙量呈二次函数关系,水沙关系调沙量存在极大值;4)水平沟类措施调控泥沙的作用效率高于水平阶类措施,水平沟+鱼鳞坑的组合可很好地发挥减流控沙和水沙关系调沙作用的潜力(55%),使二者在较高的水平上维持相对平衡;因此,不同工程措施与组合的实际应用应以具体的水土保持效益和防治目标为布设依据。研究可为堆积体陡坡治理的工程措施优化提供理论参考。