摘要：Combining the stability of chemical crosslinking and the processability of physical crosslinking is a well-established strategy to design new materials with desirable stimuli–responsive properties. Herein, a series of azobenzenebased thermotropic liquid crystalline polyesters were synthesized by introducing mesogenic dial named 4,4＇-bis（6-hydroxyhexyloxy）azobenzene（BHHAB）, 2-phenylsuccinic acid（PSA）, and different contents of 1,2,3-propanetricarboxylic acid（PTA） as the chemical crosslinker. All these polyesters showed good thermal stability and smectic liquid crystalline phase. Wide-angel X-ray diffraction（WAXD） and the fluorescence emission spectra confirmed the existence of π–πstacking interactions as the physical crosslinking in the polymer chains, particularly at the lower content of PTA. However, when the PTA content increased, the chemical crosslinking changed the chain conformation, and thus the intensity of physical crosslinking slackened gradually. Combining the physical and chemical crosslinking, these polyesters showed the thermoplastic processability, thermal shape memory, heat-assisted healing and photoresponsive behaviors. Taking advantages of these features, these multiple stimuli–responsive polymers can bring more chances for smart materials such as soft actuator.

摘要：The flammability of thermoplastic polyesters and the subsequent heavy smoke and severe melt drips formed after ignition are the main obstacles hindering their widespread application. In this study, a novel ionic monomer containing sulfonate and benzimidazole was synthesized and incorporated into the main chain of poly(ethylene terephthalate)(PET, used as a model thermoplastic polyester) by melt copolymerization. The synergetic effect of ionic aggregation and carbonization endowed the obtained copolyester with high melt viscosity and excellent char-forming ability at high temperatures. The copolyester having a monomer content of 8 mol.% easily achieved the Underwriters Laboratories Inc 94(UL-94) V-0 flammability rating without dripping and the limiting oxygen index value reached 33.0 vol.%.In addition, the total smoke production, peak heat release rate,and maximum CO production decreased by 45.2%, 60.5%, and75.0%, respectively, compared with those of PET. In addition,the copolyester was spinnable, and showed greater adsorption efficiency(99.6%) for a cationic dye from solution compared to PET(6.5%), demonstrating the excellent affinity of the copolyester for the cationic dye. The obtained inherently firesafe PET copolyester has great potential for applications in flame retardant textiles, artwork base materials, and decorative materials for transportation applications.

摘要：With the prompt development in intellectualization nowadays, the smart materials with multifunctionality or multi-responsiveness are highly expected. But it is a big challenge to integrate the different actuating units into a single system in a synergy pattern. Herein, we put forward a new strategy to develop the polyurethane networks which can present shape-memory effect and self-healing effect in independent way as well as simultaneous acting mode. To realize this goal, poly(tetremethylene ether) glycol was chosen as the soft segment to ensure the polymer chains a good mobility, and disulfide bond as the dynamic covalent bond was embedded in the backbone of polyurethane to endow it with desirable self-healing capacity under mild condition. Moreover, a rational control of the architecture of the networks by adjusting the content of disulfide bond and the degree of cross-linking, a broad glass transition temperature(T_g) was achieved, which enabled the network a versatile shape-memory effect, covering from dual-, triple-so far as to quadrupleshape memory effect. More importantly, the shape recovery and healing process can be realized simultaneously because of the highly matched actuating condition in this system.

摘要：Self-healing materials have attracted considerable attention because of their improved safety, lifetime, energy efficiency and environmental impact. Supramolecular interactions have been extensively considered in the field of self-healing materials due to their excellent reversibility and sensitive responsiveness to environmental stimuli. However,development of a polymeric material with good mechanical performance as well as self-healing capacity is very challenging. In this study, we report a robust self-healing polyurethane(PU) elastomer polypropylene glycol-2-amino-5-(2-hydroxyethyl)-6-methylpyrimidin-4-ol(PPG-mUPy) by integrating ureidopyrimidone(UPy) motifs with a PPG segment with a well-defined architecture and microphase *** balance the self-healing capacity and mechanical performance, a thermal-triggered switch of H-bonding is introduced. The quadruple H-bonded UPy dimeric moieties in the backbone induce phase separation to form a hard domain as well as enable further aggregation into microcrystals by virtue of the stacking interactions, which are stable in ambient temperature. This feature endows the PU with high mechanical strength. Meanwhile, a high healing efficiency can be realized, when the reversibility of the H-bond was unlocked from the stacking at higher temperature. An optimized sample PPG1000-mUPy50%with a good balance of mechanical performance(20.62 MPa of tensile strength) and healing efficiency(93% in tensile strength) was achieved. This strategy will provide a new idea for developing robust self-healing polymers.

摘要：Non-pillar mining technology with automatically formed roadway is a new mining method without coal pillar reservation and roadway *** stability control of automatically formed roadway is the key to the successful application of the new *** order to realize the stability control of the roadway surrounding rock,the mechanical model of the roof and rib support structure is established,and the influence mechanism of the automatically formed roadway parameters on the compound force is *** this basis,the roof and rib support structure technology of confined lightweight concrete is proposed,and its mechanical tests under different eccentricity are carried *** results show that the bearing capacity of confined lightweight concrete specimens is basically the same as that of ordinary confined concrete *** bearing capacity of confined lightweight concrete specimens under different eccentricities is 1.95 times higher than those of U-shaped steel *** comparing the test results with the theoretical calculated results of the confined concrete,the calculation method of the bearing capacity for the confined lightweight concrete structure is *** design method of confined lightweight concrete support structure is established,and is successfully applied in the extra-large mine,Ningtiaota Coal Mine,China.

摘要：Sudden earthquakes pose a threat to the running safety of trains on high-speed railway bridges,and the stiffness of piers is one of the factors affecting the dynamic response of train-track-bridge *** this paper,a experiment of a train running on a high-speed railway bridge is performed based on a dynamic experiment system,and the corresponding numerical model is *** reliability of the numerical model is verified by ***,the experiment and numerical data are analyzed to reveal the pier height effects on the running safety of trains on *** results show that when the pier height changes,the frequency of the bridge below the 30 m pier height changes greater;the increase of pier height causes the transverse fundamental frequency of the bridge close to that of the train,and the shaking angle and lateral displacement of the train are the largest for bridge with 50 m pier,which increases the risk of derailment;with the pier height increases from 8 m to 50 m,the derailment coefficient obtained by numerical simulations increases by 75% on average,and the spectral intensity obtained by experiments increases by 120% on average,two indicators exhibit logarithmic variation.

摘要：稀疏码多址接入(SCMA)技术是一项备受重视的基于码域的非正交多址接入(NOMA)技术。针对现有SCMA码本设计中未能结合数据和解码器性质以及MPA复杂度较高的问题,该文提出一种压缩感知辅助的低复杂度SCMA系统优化设计方案。首先以系统误码率为优化目标,设计一种码本自更新方法用于实现低复杂度检测器,该方法在稀疏向量重构训练过程中使用梯度下降法实现码本的自更新。其次,设计一种压缩感知辅助的多用户检测算法:符号判决正交匹配追踪(SD-OMP)算法。通过在发射端对发射信号进行稀疏化处理,在接收端利用压缩感知技术对多用户的稀疏信号进行高效的检测和重构,达到减少用户间的冲突和降低系统复杂度的目的。仿真结果表明,在高斯信道条件下,压缩感知辅助的低复杂度SCMA系统优化设计方案能够有效降低多用户检测的复杂度,且在系统用户部分活跃时能够表现出较好的误码率性能。

摘要：为解决考虑结构随机的设计震致轨道几何不平顺等效问题,建立了高速铁路轨道-桥梁系统的数值仿真模型,基于短时傅里叶变换和假设检验原理构造了设计震致轨道几何不平顺,建立了设计震致轨道几何不平顺的等效拟合模型和等效幅值反应谱,提出了考虑结构随机的等效幅值反应谱修正方法,结合震后实测轨道几何不平顺对设计震致轨道几何不平顺等效方法的合理性展开了评价。分析结果表明:在不同墩高条件下,采用正弦函数和一次函数的组合作为等效拟合模型可将设计震致轨道几何不平顺的拟合误差控制在10%以内;在设防地震和罕遇地震作用下,当修正系数分别取为3.0和1.5时,等效拟合模型与修正系数相乘得到的修正拟合模型可以满足随机结构的适用性需求;地震前后实测轨道几何不平顺形状和幅值均无明显差异,对应的横向车体加速度幅值误差小于5%,当地震强度较小时列车可正常运行,无需大幅度减速;与震后实测轨道几何不平顺相比,设计震致轨道几何不平顺使横向车体加速度幅值提升了近50%,基于设计震致轨道几何不平顺计算得到的震后行车速度阈值具有合理安全余量;建立的高速铁路桥上设计震致轨道几何不平顺等效方法可为高速铁路震后行车速度阈值确定与基于震后行车性能的抗震设计提供快速准确的手算方法。

摘要：解决高分子材料的可持续发展,不仅要考虑生产高分子材料的原料的持续来源问题,而且还要考虑其废弃后对生态环境的影响问题.有效的高分子材料的回收循环利用,不仅可以解决其废弃物焚烧和泄漏至环境中对生态环境的负面影响,而且可以减少生产高分子材料的化石资源消耗,有利于减少碳排放.本文在提出的高分子材料回收方法分类的基础上,重点讨论了化学回收,特别是以提高回收产物的品质、性能和价值为导向的化学升级回收,总结和评述了量大面广的典型热塑性高分子材料、热固性高分子材料和混杂高分子材料体系的化学升级回收的研究现状,介绍了作者团队近年来在该领域的研究新进展,并对未来发展进行了展望.与高分子材料的物理回收相比,化学回收具有方法多样化、可设计性强,回收产物因高分子结构和条件控制不同(化学键的选择性断裂)而异等特点,因此化学回收比物理回收更具实现升级回收的潜力.

摘要：2023年9月24日,第三届文化产业学术年会“人文经济高质量发展专题论坛”在南京召开,来自经济学、管理学、文学、艺术学等领域的众多专家学者围绕“人文经济”这一核心议题,从学理层面和实践层面展开了深入而富有成效的探讨,为人文经济的高质量发展之路贡献智识。人文与经济,如同双翼,共同助力社会文明的持续进步。人文经济的高质量发展,融合了人文精神的深邃内涵与经济发展的活力动力,其不仅关乎文化产业的繁荣,更是推动中国式现代化实践的重要引擎。2023年第9期,本刊曾策划刊发《人文经济学:高质量发展的人文密码》笔谈。为进一步推动人文经济领域的学术研究与实践创新,本刊特选编论坛专家观点精华,以期激发学界对人文经济高质量发展的更多关注与思考。