摘要：Restraining the aggregation and polysulfide dissolution of edge-enriched metal sulfides is of significance for their applications as anode materials of lithium-ion batteries(LIBs)with high capacity and long *** this work,we have reported the incorporation of MoS2 nanocrystals into amorphous carbon on the surface of reduced graphene oxide(rGO)by balancing the decomposition rates of phenolic resin(PF)-impregnated ammonium thiomolybdate(ATM),which subsequently forms the MoS2@C/rGO film through redispersion and vacuum *** structural design effectively avoids the aggregation of MoS2 nanocrystals and Li2S loss,and meanwhile ion enrichment in amorphous carbon and diffusion reinforcement can greatly accelerate the electrochemical reaction *** applied as the selfstanding anode,the MoS2@C/rGO film possesses high reversible capacities of 1164 mA h g^-1 at the current density of 0.2 A g^-1 and 810 mA h g^-1 at 6.4 A g^-*** also exhibits quite a high capacity retention after 1000 cycles at 3.2 A g^-*** work develops the formation theory of incorporation structures and promotes their applications in energy storage devices.