摘要：As future soft robotic devices necessitate a level of complexity surpassing current standards,a new design approach is needed that integrates multiple systems necessary to synchronize the motions of soft actuators and the response of signals,thereby enhancing the intelligence of flexible ***,we propose a liquid crystal elastomer unit cell-based platform that organizes the cells in a group to create expandable *** unit cell behaves like a flexible module that can expand biaxially into a specific,stable,and controllable *** the unit cells in different manners results in an adaptable soft grasper,a half-adder for information processing,and a tunable phononic *** implies a high level of reconfigurability and scalability in both structures and functions by elegantly reassembling the unit *** design strategy has the potential to integrate multiple functions that traditional soft actuators cannot accommodate,providing a platform for developing intelligent soft robotics.

摘要：The pore structure of porous scaffolds plays a crucial role in bone *** prevalent bone implant structure in clinical practice is the traditional cubic ***,the traditional cubic structure exhibits sharp edges and junctions that are not conducive to cell adhesion or *** this study,a double gyroid(DG)Ti6Al4V scaffold based on a triply periodic minimal surface(TPMS)structure was devised,and the osseointegration performance of DG structural scaffolds with varying porosities was *** tests revealed that the elastic modulus and compressive strength of DG structural scaffolds were sufficient for orthopedic *** vitro cellular experiments demonstrated that the DG structure significantly enhanced cell proliferation,vascularization,and osteogenic differentiation compared to the cubic *** DG structure with 55%porosity exhibited the most favorable *** vivo experiments in rabbits further demonstrated that DG scaffolds could promote neovascularization and bone regeneration and maturation;those with 55%porosity performed *** the surface area,specific surface area per unit volume,and internal flow distribution characteristics of gyroid and DG structure scaffolds,the latter are more conducive to cell adhesion and growth within *** study underscored the potential of DG scaffolds based on the TPMS structure in optimizing the pore structure design of titanium scaffolds,inducing angiogenesis,and advancing the clinical application of titanium scaffolds for repairing bone defects.

摘要：Covalent organic frameworks(COFs)are garnering significant interest in photocatalytic CO_(2) ***,their limited efficiency in separating photogenerated carriers and the scarcity of catalytic sites lead to suboptimal photocatalytic *** we develop a molecular engineering approach to design a pyrene-based COF(PyTa-H COF)confined cobalt single atoms photocatalyst(Co SACs)for CO_(2) *** moiety is introduced to enhance visible-light harvesting capability and improve charge separation in the ***,Co SACs enhance the photocatalytic activity by accelerating the migration of photo-induced carriers and reducing the reaction energy of the rate-determining ***,PyTa-H@Co achieves a CO production rate of 18.36 mmol g^(−1) h^(−1) and a selectivity of 94%in 4 h under visible light irradiation,which is comparable to the reported best-performing *** functional theory calculations reveal that the Co SACs greatly stabilize*COOH and significantly reduce the energy of the decisive step,leading to outstanding photocatalytic *** work,through molecular engineering design,highlights the critical relationship between catalyst structure and function in enhancing photocatalytic efficiency.

摘要：Lumbar degeneration leads to changes in geometry and density distribution of vertebrae,which could further influence the mechanical property and *** study aimed to quantitatively describe the variations in shape and density distribution for degenerated vertebrae by statistical models,and utilized the specific statistical shape model(SSM)/statistical appearance model(SAM)modes to assess compressive strength and fracture *** detailed SSM and SAM were developed based on the 75 L1 vertebrae of elderly men,and their variations in shape and density distribution were quantified with principal component(PC)*** vertebrae were classified into mild(n=22),moderate(n=29),and severe(n=24)groups according to the overall degree of *** computed tomography-based finite element analysis was used to calculate compressive strength for each L1 vertebra,and the associations between compressive strength and PC modes were evaluated by multivariable linear regression(MLR).Moreover,the distributions of equivalent plastic strain(PEEQ)for the vertebrae assigned with the first modes of SSM and SAM at mean±3SD were *** Leave-One-Out analysis showed that our SSM and SAM had good performance,with mean absolute errors of 0.335±0.084 mm and 64.610±26.620 mg/cm3,respectively.A reasonable accuracy of bone strength prediction was achieved by using four PC modes(SSM 1,SAM 1,SAM 4,and SAM 5)to construct the MLR ***,the PEEQ values were more sensitive to degeneration-related variations of density distribution than those of *** density variations may change the deformity type(compression deformity or wedge deformity),which further affects the fracture *** models can identify the morphology and density variations in degenerative vertebrae,and the SSM/SAM modes could be used to assess compressive strength and fracture *** above findings have implications for assisting clinicians in pathological dia

摘要：Inorganic-organic composite electrolyte is proved an effective way to enhance the overall performance of the ***,simply combining powder fillers with polymers is not sufficient for the application of composite *** this work,we designed an ultrathin organic-inorganic composite solid electrolyte with high mechanical strength and ionic conductivity,in which the inorganic Li1.5Al0.5Ge1.5(PO_(4))3(LAGP)solid electrolyte is prefiberized into a three-dimensional nanofiber network to serve as a self-supporting skeleton for the polyethylene oxide(PEO)*** continuous skeleton structure not only significantly improves the mechanical strength of the PEO-based electrolyte,but also forms a continuous lithium-ion conduction path,promoting the rapid migration of lithium *** fiber-reinforced composite electrolyte has an ionic conductivity of 8.27×10^(−4) S cm^(-1) at 60°C and a tensile strength of up to 4.29 ***,it exhibits a reduced overpotential and stable long-term cycling performance over 1700 h when used in Li/Li symmetric *** LiFePO_(4)(LFP)|Li cell assembled with the fiber-reinforced composite electrolyte also delivers a specific capacity of about 142 mAh g^(−1) over 300 cycles at 0.5 C and maintains good cycling *** work provides a novel idea for designing the next generation of safe and reliable organic-inorganic composite solid-state electrolyte membranes.

摘要：A plasma injection ion source has been de-veloped for the photoelectron velocity imag-ing studies of metal-containing *** source employs a pulse discharge nozzle for generating a plasma beam that perpendicu-larly crosses the master supersonic jet beam from a home-made pulsed piezo *** discharge nozzle is designed for high voltage gas discharge with efficient metal sputtering of the cathode,and thus plays a role in met-al atom and ion *** jet-cooled anions can be produced in the master gas jet via reactions of the plasma *** source is integrated into a photoelectron ve-locity imaging *** mass spectrometry experiments show that the ion source can efficiently produce transition metal containing anions,such as FeO_(m)^(-),CuO_(m)^(-),CuC_(n)^(-),CuC_(n)O_(m)^(-).The photoelectron imaging results by photodetachment of O-show that the pho-toelectron energy resolution of the whole instrument isΔE/E≈2.3%,and the results of FeO^(-)indicate that internal temperatures of anions from the source could be efficiently cooled down.

摘要：Molecular constructs define the elementary units in porous materials for efficient CO_(2)*** design of appro-priate interpore and intermolecular space is crucial to stabilize CO_(2)molecules and maximize the *** the molecular construct usually has a fixed dimension,whether its inter-molecular space could be self-adjustable during CO_(2)capture and release,behaving as a balloon,has captured *** we report a flexible intermolecular space of the double chain structure of self-assembled 1,4-pheny-lene diisocyanide(PDI)molecules on Ag(110)surface,which dynamically broadens and recovers during the CO_(2)capture and *** incipient PDI double chains organize along the[001]direction of Ag(110),in which individual PDI molecules stand up in a zigzag order with the interchain width defined by twice the Ag lattice distance along_([110])direction(2α_([110])).When CO_(2)molecules are introduced,they assemble to occupy the interchain spaces,expanding the interchain width to 3α_([110]),4α_([110])and 5α_([110]):Warming up the sample leads to the thermally-driven CO_(2)desorption that recovers the original interchain ***-resolution scanning tunneling microscopy(STM)jointly with density functional theory(DFT)calculations determine the structural and electronic interactions of CO_(2)molecules with the dynamical PDI structures,providing a molecular-level perspective for the design of a self-adjustable metal-organic construct for reversible gas capture and release.

摘要：Empowering the value realization of ecological products with a digital economy is an important path for achieving the transformation of“two mountains”and the construction of ecological *** on the panel data of 30 provinces in china from 2011 to 2022,a fixed-effects model was used to empirically test the impact,heterogeneity and mechanism of the effects of the digital economy on the value realization of ecological *** analysis revealed three key findings.(1)The digital economy has a significant driving effect on improving the ability to realize the value of ecological products,and this effect is still applicable in a variety of robustness tests such as shrinking the years,replacing explanatory variables,and endogeneity tests.(2)The rise of the digital economy affects the value realization of ecological products to different degrees in different regions,especially in the eastern region,while the effect in the central region is not obvious.(3)The analysis of mechanistic variables indicated that the digital economy has an impact on the value realization of ecological products through the development of green finance and government ***,the government should design differentiated and multi-level support policies for the realization of ecological product value according to the heterogeneity of natural resources,ecological potential and the levels of digital economy development in different regions,and it should strengthen the control of non-environmental protection behaviors of the *** should accelerate the digital transformation of the entire production,distribution,circulation and consumption chain of ecological products,and actively develop financial products and services that meet the characteristics and needs of ecological products.

摘要：ZnO-based catalysts have been widely used in hydrogenation reactions,but less attention has been paid to the electrocatalytic hydrogenation process on ZnO *** this work,the preparation of hydrogen species and the associ-ated reduction properties under electrochemi-cal processes in aqueous solutions have been in-vestigated on ZnO and Au/ZnO *** measurements of cyclic voltammetry(CV),X-ray diffraction,and electron paramagnetic resonance(EPR)confirm the formation of hydro-gen species on the interstitial sites(Hi)or on the oxygen vacancy sites(H_(O)).The hydrogena-tion reaction of p-nitrophenol(pNP)at 40μmol/L occurs on both ZnO and Au/ZnO elec-trodes,and the hydrogenation reduction performance of Au/ZnO electrode is better than that of ZnO *** show H_(O)species is much more reactive with pNP than Hi *** with the ZnO electrode,the presence of Au on ZnO promotes the formation of H_(O)species and improves the electro-reduction performance to *** results help us to un-derstand the reaction processes related to the electrochemical hydrogenation on ZnO and Au/ZnO surfaces and shed new light on the design of new catalytic hydrogenation systems.

摘要：Advanced programmable metamaterials with heterogeneous microstructures have become increasingly prevalent in scientific and engineering disciplines attributed to their tunable ***,exploring the structure-property relationship in these materials,including forward prediction and inverse design,presents substantial *** inhomogeneous microstructures significantly complicate traditional analytical or simulation-based ***,we establish a novel framework that integrates the machine learning(ML)-encoded multiscale computational method for forward prediction and Bayesian optimization for inverse *** prior end-to-end ML methods limited to specific problems,our framework is both load-independent and *** means that a single training session for a constitutive model suffices to tackle various problems directly,eliminating the need for repeated data collection or *** demonstrate the efficacy and efficiency of this framework using metamaterials with designable elliptical holes or lattice honeycombs *** accelerated forward prediction,we can precisely customize the stiffness and shape of metamaterials under diverse loading scenarios,and extend this capability to multi-objective customization ***,we achieve topology optimization for stress alleviation at the crack tip,resulting in a significant reduction of Mises stress by up to 41.2%and yielding a theoretical interpretable *** framework offers a general,efficient and precise tool for analyzing the structure-property relationships of novel metamaterials.