摘要：采用浸渍法制备了一系列用于甲烷选择催化还原(CH4-SCR)氮氧化物的Co/MOR催化剂。采用XRD、BET、TG-MS、H2-TPR、NH3-TPD和NO-TPD等手段对催化剂进行表征,并对其在甲烷选择催化还原氮氧化物反应中的活性进行评价。结果表明,钴物种以Co3O4尖晶石形态存在于Co/MOR催化剂中;与MOR载体相比,引入钴物种后,催化剂的酸性、氧化还原能力和对NO的吸脱附能力均发生了变化。在甲烷选择催化还原氮氧化物反应中,Co/MOR的催化活性与其氧化还原性能和对NO的吸脱附性能直接相关;其中,Co负载量为10%的Co(10)/MOR催化剂的CH4-SCR脱硝活性最好,在330℃下NO的转化率达54.2%。

摘要：Recently, resonant AC/DC converter has been accepted by the industry. However, the efficiency will be decreased at light load. So, a novel topology with critical controlling mode combined with resonant ones is proposed in this paper. The new topology can correspond to a 90 plus percent of power converting. So,a novel topology of an state of art integrated circuit, which can be used as power management circuit, has been designed based on the above new topology. A simulator which is specifically suitable for the power controller has been founded in this work and it has been used for the simulation of the novel architecture and the proposed integrated circuit.