摘要：Ni/TiO_(2) catalyst is widely employed for photo-driven DRM reaction while the influence of crystal structure of TiO_(2) remains *** this work,the rutile/anatase ratio in supports was successfully controlled by varying the calcination temperature of anatase-TiO_(2).Structural characterizations revealed that a distinct TiO_(x) coating on the Ni nanoparticles(NPs)was evident for Ni/TiO_(2)-700 catalyst due to strong metal-support *** is observed that the TiOx overlayer gradually disappeared as the ratio of rutile/anatase increased,thereby enhancing the exposure of Ni active *** exposed Ni sites enhanced visible light absorption and boosted the dissociation capability of CH4,which led to the much elevated catalytic activity for Ni/TiO_(2)-950 in which rutile ***,the catalytic activity of solar-driven DRM reaction was significantly influenced by the rutile/anatase ***/TiO_(2)-950,characterized by a predominant rutile phase,exhibited the highest DRM reactivity,with remarkable H2 and CO production rates reaching as high as 87.4 and 220.2 mmol/(g·h),*** rates were approximately 257 and 130 times higher,respectively,compared to those obtained on Ni/TiO_(2)-700 with *** study suggests that the optimization of crystal structure of TiO_(2) support can effectively enhance the performance of photothermal DRM reaction.

摘要：本文设计了系列基于二酮基吡咯并吡咯的四配位有机硼化合物，利用密度泛函理论（DFT）和含时密度泛函理论（TD-DFT）方法系统研究了吸电子和推电子基团对所设计化合物的电子和光学性质的影响。研究结果表明，引入吸电子或推电子基团可有效调节所设计化合物的前线轨道能级(ELUMO和EHOMO),HOMO-LUMO能隙（Eg）,吸收光谱和荧光光谱.在母体化合物HBDPP(2,5-二（二苯基硼基）-3,6-二（2-吡啶基）吡咯[3,4-c]并吡咯-1,4（2H,5H）-二酮)分子中引入吸电子基团可使ELUMO,EHOMO和Eg降低，而引入推电子基团使ELUMO,EHOMO和Eg升高。相对于母体化合物HBDPP的吸收光谱和荧光光谱，引入吸电子基团的化合物的吸收光谱和荧光光谱发生红移，而引入推电子基团的化合物的吸收光谱波长和和荧光光谱发生蓝移。另外，吸电子（推电子）基团的吸电子（推电子）能力越强，对化合物的电子和光学性质的影响越显著。

摘要：Crimping is widely adopted in the production of large-diameter submerged-arc welding pipes. Traditionally, designers obtain the technical parameters for crimping from experience or by trial and error through experiments and the finite element(FE) method. However, it is difficult to achieve ideal crimping quality by these approaches. To resolve this issue, crimping parameter design was investigated by multi-objective optimization. Crimping was simulated using the FE code ABAQUS and the FE model was validated experimentally. A welding pipe made of X80 high-strength pipeline steel was considered as a target object and the optimization problem for its crimping was formulated as a mathematical model and crimping was optimized. A response surface method based on the radial basis function was used to construct a surrogate model; the genetic algorithm NSGA-II was adopted to search for Pareto solutions; grey relational analysis was used to determine the most satisfactory solution from the Pareto solutions. The obtained optimal design of parameters shows good agreement with the initial design and remarkably improves the crimping quality. Thus, the results provide an effective approach for improving crimping quality and reducing design times.

摘要：Cobalt nanoparticles(NPs)catalysts are extensively used in heterogeneous catalytic reactions,and the addition of alkali metal promoters is a common method to modulate the catalytic performance because the catalyst's surface structures and morphologies are sensitive to the addition of ***,the underlying modulation trend remains ***,the adsorption of alkali metal promoters(Na and K)on the surfaces of face-centered-cubic(FCC)and hexagonal-closest packed(HCP)polymorphous cobalt was systematically investigated using density functional ***,the effect of alkali promoters on surface energies and nanoparticle morphologies was revealed on the basis of Wulff *** FCC-Co,the exposed area of the(111)facet in the nanoparticle increases with the adsorption coverage of alkali metal ***,the(311),(110),and(100)facets would disappear under the higher adsorption coverage of alkali *** HCPCo,the Wulff morphology is dominated by the(0001)and(1011)facets and is independent of the alkali metal adsorption *** work provides insights into morphology modulation by alkali metal promoters for the rational design and synthesis of cobalt-based nanomaterials with desired facets and morphologies.

摘要：设计并研究了一种周期性多层金属/介质层结构以获得太赫兹频段的阻带滤波器.通过利用极化综合效应实现了一个大带宽的阻带.这一阻带滤波器的带宽可以通过调制银层的电磁耦合作用进行调节.同时还研究了金属层的数量、晶格常数和介质层的介电常数对阻带滤波器的中心频率和带宽的影响.通过合理调配这些因素可以调制中心频率蓝移和带宽增大.通过耦合作用调制带宽的方法可为设计大带宽阻带滤波器提供好的思路.

摘要：采用Gleeble-1500D热模拟试验机根据设计的轧制工艺对7055合金进行多道次热压缩试验,模拟其企业热轧过程,采用电子背散射衍射和透射电镜研究了再结晶特征。在不同变形条件下,表现出不同的再结晶机制,主要动态再结晶机制有连续动态再结晶和几何动态再结晶。前者的形核机制主要为原始晶界弓出形核和亚晶合并形核;后者归因于严重的不均匀变形。在道次间的间隙期间,静态再结晶发生。另外,尺寸大于1μm的第二相也促进再结晶。

摘要：设计和合成一个基于3，5-二叔丁基水杨醛-P-硝基苯腙含酚羟基的新型阴离子受体1．在加入AcO-和F-后，受体1发生从深黄色到紫色的颜色变化．然而，在加入其它阴离子（H2PO4-，cl-，Br-，I-）没有明显的颜色变化．通过紫外和荧光滴定研究，受体与AcO-和F-结合的性质．结果表明受体1与AcO和F-较高的结合能力，且通过氢键的相互作用形成了一个1：1客体配合物．

摘要：为了实现具有多频或宽频特性的太赫兹超材料滤波器,通常将相同或不同的谐振结构在同一平面内进行组合或者进行多层堆叠.通过将尺寸相同的C-型谐振单元分别置于中间介质层的两端,实现了基于金属-介质-金属结构的太赫兹超材料宽阻带滤波器,该滤波器具有较宽的阻带和较好的频率选择性.基于对该太赫兹超材料宽阻带滤波器C-型谐振结构表面的电场和电流分布的仿真分析,深入探讨了入射太赫兹波的传输机理,揭示了滤波器的滤波机制.基于对金属-介质-金属结构和金属-介质结构的超材料滤波器的滤波特性的仿真研究,揭示了宽阻带的形成机理.最后,采用PDMS薄膜制备工艺和金属磁控溅射方法对该超材料滤波器的样品进行了加工制备,并采用传输型的太赫兹时域光谱系统对其滤波特性进行了实际测试,验证了该超材料滤波器的结构设计、仿真和制备的正确性,为今后宽频带超材料滤波器的设计、制备和特性研究提供了参考.

摘要：为了估计一个人群总体中具有敏感属性个体的未知比例,本文提出了一种简便易行的随机化回答技术.提出的方法不需要对样本个体直接询问敏感问题.每个响应者要求根据抽自两个卡片包的两张卡片的颜色和响应者是否具有敏感属性作出一个序对的回答.通过设计参数的适当选择,说明提出的方案比已有的一些随机化策略具有更高的效率.另外,这一策略对个体隐私具有很好的保护性且容易实施.

摘要：采用滑模控制对非线性系统进行控制时,抖振是不可避免的现象,如何抑制抖振成为研究的重点。介绍了一种反演自适应滑模控制方案,它可以解决非线性系统中的不确定性问题,保证系统的鲁棒性。为此,首先介绍了反演设计的原理,通过在反演设计中引入滑模控制,并采用自适应算法对不确定性进行估计,有效的降低了抖振。最后给出了一个应用此方法进行控制的实际例子,结果表明了这种方法的有效性。