摘要：As the main component of wearable electronic equipment,flexible pressure sensors have attracted wide attention due to their excellent sensitivity and their promise with respect to applications in health monitoring,electronic skin,and human-computer ***,it remains a significant challenge to achieve epidermal sensing over a wide sensing range,with short response/recovery time and featuring seamless conformability to the skin *** is critical since the capture of minute electrophysiological signals is important for health care *** this paper,we report the preparation of a nacre-like MXene/sodium carboxymethyl cellulose(CMC)nanocomposite film with a“brick-and-mortar”interior structure using a vacuum-induced self-assembly *** synergistic behavior of the MXene“brick”and flexible CMC“mortar”contributes to attenuating interlamellar self-stacking and creates numerous variable conductive pathways on the sensing *** resulted in a high sensitivity over a broad pressure range(i.e.,0.03-22.37 kPa:162.13 kPa^(-1);22.37-135.71 kPa:127.88 kPa^(-1);135.71-286.49 kPa:100.58 kPa^(-1)).This sensor also has a low detection limit(0.85 Pa),short response/recovery time(8.58 ms/34.34 ms),and good stability(2000 cycles).Furthermore,we deployed pressure sensors to distinguish among tiny particles,various physiological signals of the human body,space arrays,robot motion monitoring,and other related applications to demonstrate their feasibility for a variety of health and motion monitoring use cases.

摘要：Cortical electrodes are a powerful tool for the stimulation and/or recording of electrical activity in the nervous ***,the inevitable wound caused by surgical implantation of electrodes presents bacterial infection and inflammatory reaction risks associated with foreign body ***,inflammation of the wound area can dramatically worsen in response to bacterial *** consequences can not only lead to the failure of cortical electrode implantation but also threaten the lives of ***,we prepared a hydrogel made of bacterial cellulose(BC),a flexible substrate for cortical electrodes,and further loaded antibiotic tetracycline(TC)and the anti-inflammatory drug dexamethasone(DEX)onto *** encapsulated drugs can be released from the BC hydrogel and effectively inhibit the growth of Gram-negative and Gram-positive ***,therapeutic cortical electrodes were developed by integrating the drug-loaded BC hydrogel and nine-channel serpentine arrays;these were used to record electrocorticography(ECoG)signals in a rat *** to the controlled release of TC and DEX from the BC hydrogel substrate,therapeutic cortical electrodes can alleviate or prevent symptoms associated with the bacterial infection and inflammation of brain *** approach facilitates the development of drug delivery electrodes for resolving complications caused by implantable electrodes.

摘要：Aqueous zinc-ion batteries(AZIBs)show great potential for applications in grid-scale energy storage,given their intrinsic safety,cost effectiveness,environmental friendliness,and impressive electrochemical ***,strong electrostatic interactions exist between zinc ions and host materials,and they hinder the development of advanced cathode materials for efficient,rapid,and stable Zn-ion *** and their derivatives possess a large interlayer spacing,excellent hydrophilicity,outstanding electronic conductivity,and high redox *** materials are considered“rising star”cathode candidates for *** comprehensive review discusses recent advances in MXenes as AZIB cathodes from the perspectives of crystal structure,Zn-storage mechanism,surface modification,interlayer engineering,and conductive network design to elucidate the correlations among their composition,structure,and electrochemical *** work also outlines the remaining challenges faced by MXenes for aqueous Zn-ion storage,such as the urgent need for improved toxic preparation methods,exploration of potential novel MXene cathodes,and suppression of layered MXene restacking upon cycling,and introduces the prospects of MXene-based cathode materials for high-performance AZIBs.

摘要：Modern medicine is increasingly interested in advanced sensors to detect and analyze biochemical *** sensors based on potentiometric methods are a promising platform for monitoring physiological ions in biological *** semi-implantable devices are mainly based on single-parameter *** semi-implantable electrodes for multiparameter sensing have more restrictions on the electrode size due to biocompatibility considerations,but reducing the electrode surface area could potentially limit electrode *** study developed a semi-implantable device system comprising a multiplexed microfilament electrode cluster(MMEC)and a printed circuit board for real-time monitoring of intra-tissue K^(+),Ca^(2+),and Na^(+)*** electrode surface area was less important for the potentiometric sensing mechanism,suggesting the feasibility of using a tiny fiber-like electrode for potentiometric *** MMEC device exhibited a broad linear response(K^(+):2–32 mmol/L;Ca^(2+):0.5–4 mmol/L;Na^(+):10–160 mmol/L),high sensitivity(about 20–45 mV/decade),temporal stability(>2weeks),and good selectivity(>80%)for the above *** vitro detection and in vivo subcutaneous and brain experiment results showed that the MMEC system exhibits good multi-ion monitoring performance in several complex *** work provides a platform for the continuous real-time monitoring of ion fluctuations in different situations and has implications for developing smart sensors to monitor human health.

摘要：近年来,光催化产氢与有机物氧化的偶联反应备受关注,如何设计高效双功能光催化剂实现偶联反应成为研究重点.在众多光催化剂中,ZnIn_(2)S_(4)以其优异的可见光吸收能力、本征的极化电场以及较强的氧化还原能力成为双功能催化剂的热点备选材料.然而,电子空穴分离效率低以及光生电子空穴复合率高的问题限制了ZnIn_(2)S_(4)光电转化效率的进一步提高.针对这一问题,我们采用了具有较高导电性和独特结构的金属相1T-MoS_(2)作为助催化剂与花状ZnIn_(2)S_(4)复合形成“海胆状”的1T-MoS_(2)/ZnIn_(2)S_(4)欧姆结复合材料.理论计算结合XPS数据揭示了欧姆结与内建电场的形成,一系列光谱表征表明由欧姆结所形成的强内建电场促进了ZnIn_(2)S_(4)体内光生电子快速向1T-MoS_(2)转移,同时活性测试与EPR表征证明了苯甲醇的氧化反应可以作为光生空穴的有效捕获剂.最终,1T-MoS_(2)/ZnIn_(2)S_(4)复合光催化剂实现了4.6倍光催化性能的提高,420 nm波长下表光量子效率达6.75%.本项工作通过精确调节电荷转移机制,实现了ZnIn_(2)S_(4)双功能催化剂光电效率的进一步提高,为光催化剂载流子调控设计提供了新思路.

摘要：利用太阳能将CO_(2)光转化为化学燃料是前沿研究的热点.当前,科研的重点在于开发和优化各类光催化材料的性能.异质结构不仅用于增强无机半导体催化剂的活性,而且用于金属-有机框架(MOFs)光催化剂的构建.随着异质结技术的不断进步,新的相结概念应运而生.尽管关于无机半导体中的相结研究已取得一定进展,但是MOFs相结结构的探索尚处于起步阶段.本文中,我们成功设计并构建了一种具有卓越光催化CO_(2)还原性能的MOFs相结杂化材料.这种材料由具有高度连接性的卟啉配体(TCPP-Ni)与Zr6团簇紧密结合而成,在溶剂热反应条件下,PCN-222-Ni能够快速且均匀地成核.通过精准调控调节剂的用量,我们实现了同分异构体PCN-224-Ni在类似条件下较慢的晶体形成过程.最终制得的P@P杂化材料展现出高表面积、多孔性和卓越的结晶度.由于PCN-222-Ni和PCN-224-Ni之间的带隙匹配,光生载流子的分离和迁移得以促进,从而使P@P杂化材料展现出卓越的光还原CO_(2)性能.这一重大突破不仅标志着MOFs相结结构研究的重大进展,还拓宽了MOFs相结在CO_(2)光转化领域的应用前景.

摘要：研究Zr_(55)Cu_(30)Ni_(5)Al_(10)(摩尔分数,%)金属玻璃在深冷循环处理过程中的回春行为。实验发现,随着循环次数的增加,样品的回春程度更高,表现为更高的弛豫焓与更低的密度。回春程度经200次循环后逐渐饱和,这可能与非晶结构中有限的自由体积含量有关。同时,高循环次数下的样品硬度更低,塑性更好,这与其剪切转变区体积增大有关。此时,更低的剪切面形成能有利于多重剪切带的形成。此外,还发现自由体积含量与样品塑性应变及剪切转变区体积呈线性关系。分子动力学模拟结果还表明,在高冷速下回春程度高的样品会发生原子体积的饱和。

摘要：受到水合镁离子的高脱溶能垒和不良界面水分解行为的限制,水系镁离子电池通常受制于缓慢的离子传输动力学和严重的阴极溶解.为了克服这些障碍,受细胞膜两亲性结构的启发,我们成功构建了一种由疏水性聚(3,4-乙二氧基噻吩)(PEDOT)和亲水性α-MnO_(2)基底组成的MnO_(2)碳基阴极.结合实验和理论计算结果分析,PEDOT层可以有效提高整体电极的导电性,降低水合Mg^(2+)的脱溶能垒,并抑制阴极溶解,从而提高复合电极的性能.因此,本文所制备的复合电极表现出优越的速率性能(58.4mA hg^(-1),3Ag^(-1))和增强的长期循环稳定性(1000个循环后85.92mA hg^(-1),2Ag^(-1)),优于原始的α-MnO_(2)阴极.这项基于生物启发设计理念的工作将为水合镁离子电池的发展提供创新方向.

摘要：近红外(NIR)光驱动水分解产生氢气(H_(2))一直以来都是光催化领域备受关注的问题,但由于其动力学和热力学方面的缺陷,迄今为止仍是一项艰巨的挑战.为了突破这一限制,我们通过简便的水热法设计出了富含硫空位的无贵金属二维(2D)ZnIn_(2)S_(4)-基光催化剂,并首次使用单组分ZnIn_(2)S_(4)-基材料实现了波长大于800 nm的近红外驱动制氢性能.根据价带光谱、紫外-可见-近红外DRS光谱、稳态PL光谱、瞬态光电流响应和EPR表征,我们揭示了存在一个高效的Urbach带尾吸收用于捕获近红外光.硫空位在ZnIn_(2)S_(4)纳米片中的成功构建不仅扩展了光谱吸收范围,而且具有出色的载流子扩散特性和丰富的活性位点.因此,我们的研究结果可能会为未来开发近红外响应的ZnIn_(2)S_(4)-基光催化剂用于实现高效近红外驱动制氢提供一定的指导.

摘要：石墨烯因其高载流子迁移率和宽光谱吸收范围而广泛应用于光电探测。然而,其低光吸收率导致的高暗电流严重限制了它的光电探测性能。钼基二硫族化合物(MoX_(2),X=S、Se和Te)具有高的吸收系数,能够弥补石墨烯基光电探测器中暗电流较高的劣势,因此基于石墨烯/MoX_(2)范德华异质结的光电探测器能够表现出优异的光电子特性。本综述首先回顾了光电探测器的工作原理、性能指标和结构。之后,从材料基础的角度突出了石墨烯/MoX_(2)范德华异质结光电探测器的重要性。接着,总结了石墨烯/MoX_(2)范德华异质结光电探测器的制备方法和性能增强策略。最后,强调了这类异质结光电探测器当前面临的挑战及未来的发展方向。本综述将为这类高性能范德华异质结光电探测器的设计提供一定的指导和参考。