摘要：We construct a holographic p-wave superconductor model in the background of quintessence AdS black hole with an SU（2） Yang-Mills gauge field and then probe the effects of quintessence on the holographic p-wave superconduc- tor. We investigate the relation between the critical temperature and the state parameter of quintessence, and present the numerical results for electric conductivity. It is shown that the condensation of the vector field becomes harder as the absolute value of the state parameter increases. Unlike the scalar condensate in the s-wave model, the condensation of the vector field in p-wave model can occur in the total value range of the state parameter wq of quintessence. These results could help us know more about holographic superconductor and dark energy.

摘要：A complex micelle as a hemoglobin functional model with the biaoactive function of reversible oxygen transfer has been constructed through the hierarchical assembly of the diblock copolymer poly（ethylene glycol）-block- poly（4-vinylpyridine-co-N-heptyl-4-vinylpyridine） （PEG-b-P（4VP-co-4VPHep））, tetrakis（4-sulfonatophenyl）porphinato iron（II） （Fe（II）TPPS） and β-cyclodextrin （β-CD）. The μ-oxo dimer of Fe（II）TPPS was successfully inhibited because the Fe（II）TPPS was included into the cavities of β-CDs through host-guest interaction. Fe（II）TPPS coordinated with pyridine groups functions as the active site to reversibly bind dioxygen. In adition, the host-guest inclusion （β-CD/Fe（II）TPPS） was encapsulated in the hydrophobic core of the complex micelle and tightly fixed by P4VP chains. The hydrophilic PEG blocks stretched in aqueous solution to constitute the shells which stabilize the structure of the complex micelle as well as endow the complex micelle with sufficient blood circulation time. Dioxygen can be bound to the Fe（II）TPPS located in the confined space and excellent reversibility of the binding-release process of dioxygen can be achieved. The quaternary amine N-heptyl-4-vinylpyridine can coerce abundant S2O4^2- ions into the core of the complex micelle to facilitate the self-reduction process. Dioxygen adducts （Fe（II）TPPS（O2）） were effectively protected by the double hydrophobic barriers constructed by the cavity of the cyclodextrin and the core of the complex micelle which enhances the ability to resist nucleophilic molecules. Therefore, the rationally designed amphiphilic structure can work as a promising artificial O2 carrier. Potentially, the complex micelle can be expected to improve the treatment of diseases linked with hypoxia.

摘要：We study the thermodynamics of a charged AdS black hole in the special f(R)correction with the constant Ricci scalar *** results show that the f(R)correction influences the Gibbs free energy and the phase transition of *** ratioρc occurring at the critical point increases monotonically with the derivative term f'(R0).We also disclose that the critical exponents are the same as those of the liquid-gas phase transition in the van der Waals model,which does not depend on the f(R)correction considered here.

摘要：Three low bandgap non-fullerene acceptors based on thieno[3,2-b]thiophene fused core with different ending groups, named TTIC-M, TTIC, TTIC-F were designed and synthesized. Using a wide bandgap polymer PBDB-T as donor to form a complementary absorption in the range of 300–900 nm, high efficencies of 9.97%, 10.87% and 9.51% were achieved for TTIC-M, TTIC and TTFC-F based photovoltaic devices with impressively high short circuit current over21 mA cm^-2.

摘要：In order to develop efficient photocatalysts,great efforts have been made to reduce hexavalent chromium to trivalent *** photocatalytic efficiency of this reduction depends largely on the adsorption and diffusion of hexavalent chromium ions on the surface of the *** this paper,polyanilineTiO2 composite can effectively improve the photocatalytic reduction performance and stability of hexavalent chromium *** effect of polyaniline(PANI) thickness on Cr(VI) activity and stability of photocatalytic reduction was studied by adjusting the content of PANI on Mesoporous TiO2(MT) *** the irradiation conditions,the reaction results showed that the reduction rate was 100%,and the maximum reaction rate reached 0.62 min-1 when the PANI modification was 3.0%.Moreover,the results showed that the reduction performance remained 100% after ten *** main reason is that the PANI modified on the surface of TiO2 is rich in positively charged amino group,which can efficiently adsorb the reactant Cr(VI),and make the product Cr(III) leave the reaction interface quickly,thus ensuring the performance of photocatalyst.

摘要：The super-high speed high temperature superconductor （HTS） maglev evacuated tube transport （ETT） is a promising transport mode for the future. As a key component of the HTS maglev vehicle, the permanent magnet guide- ways （PMGs） with different geometrical configurations and iron yoke widths are analyzed by finite element method （FEM）. The levitation force of a single onboard HTS maglev device over the designed PMG at different field cooling heights （FCH） is measured by magnetic levitation measurement system. Based on the designed PMG and experimental results, a preliminary scheme of subterranean super-high speed HTS maglev ETT is described in this paper. The HTS maglev ETT is mainly composed of an evacuated tube, HTS maglev vehicle, PMG, propulsion system, station, emergency rescue system, etc. In addition, a subterranean tube that consists of foundation tube and vacuum airproof layer is introduced. In order to convert the stress caused by the air pressure difference between inside and outside of the vehicle, a multi-circular vehicle body is designed. The vehicle is driven by a linear motor propulsion system under the control of a ground controlling system. The scheme of long-distance super-high speed passenger transportation is accomplished by the connection of different vehicles.

摘要：霍尔效应仿真实验采用面向对象技术,以模块化、局部化、可重复性和拓展性为设计原则,实现了LabVIEW环境下实验仪器的数值建模和图像建模,以事件驱动方式实现实验场景和仪器界面及操作的仿真.结果表明该类仿真实验在仿真性、交互性、设计性、结果的处理和报告的提交上都达到了很好的仿真和实现,能实现良好的教学效果,有效缓解实验室压力.

摘要：Au Pd nanoalloys with tunable Pd concentrations have been synthesized and used as model catalysts. They have been directly imaged by high-angle annular dark-field scanning transmission electron microscopy and investigated by thorough analyses of their extended X-ray absorption fine structure, X-ray absorption near-edge structure, X-ray diffraction and X-ray photoelectron spectroscopy measurements. The bimetallic nanoparticles are embedded in a carbonaceous matrix and have almost an identical structure at the atomic level and the same electronic properties as Au Pd bulk alloys with the same compositions. The d-electron increase at surface Pd sites is determined by the Pd concentration of the alloy. Similarly, their activation entropy and catalytic activity for the hydrogenation of quinoline is related to the Pd concentration, with Au50 Pd50 the most active of the alloys investigated. An almost 11 times higher activity was achieved compared to a pure Pd catalyst. The experimentally measurable surface d charge at the Pd sites in the Au Pd was found to linearly correlate with the activation entropy and catalytic activity for the hydrogenation of quinoline. The alloy structure is stable, showing negligible metal segregation, dissolution-redeposition and aggregation during the hydrogenation process which involves strong adsorption.

摘要：TiO2 mesocrystals can considerably enhance charge separation owing to their oriented superstructures,with fewer internal defects and porous properties providing more active *** this work,we prepared TiO2 mesocrystal films by a direct annealing *** morphology and crystal phase of the film were controlled by adjusting the ratio of NH4F and the calcination ***,we found that Au nanoparticles loaded on a TiO2 mesocrystal film enabled highly efficient visible light photocatalytic *** photocatalytic activities were studied by hydrogen generation and photoreduction of Cr(VI).This work represents a considerable advance in the development and application of the TiO2 mesocrystals.

摘要：生命活动中用于维持生物体内超氧阴离子自由基动态平衡的超氧化物歧化酶(superoxidedismutase,SOD)是一类金属酶,属于典型的生物大分子金属络合物,因其在生命活动中所起的重要作用而备受关注。目前,有关SOD的模拟已从小分子化合物的模拟,走向大分子环境与活性中心相结合的系统模拟。本文从高分子化合物角度对模拟SOD的研究进展作一综述,以期为设计并开发具有生物相容且高活性的新型高分子抗氧化剂提供新思路。天然大分子有蛋白质与多肽、多糖、分子聚集体,目前所采用的蛋白质(多肽)是性能稳定的天然蛋白质或通过基因重组技术生物合成的蛋白质或多肽,所采用的多糖类物质主要有右旋糖酐、羧甲基纤维素、壳聚糖等。小分子活性化合物(如金属卟啉、新型肟类为配体的同核与异核复合物、salen型金属配合物等)通过与这些天然大分子结合,在提高活性的同时也改善了其稳定性。将活性小分子物质与分子聚集体(如胶束、脂质体)结合制得的SOD模拟物可以模拟天然SOD在体内的环境,提高抗氧化活性和体内循环时间。合成高分子模拟SOD的工作主要集中于高分子接枝金属配合物的研究,其中典型的合成高分子有聚乙二醇(polyethylene glycol,PEG)、聚L-赖氨酸、聚(苯乙烯-马来酸酐)、聚(环己烷-1,4-丙酮二亚甲基缩酮)、氯化聚苯乙烯树脂、聚乳酸和一些嵌段共聚物,其抗氧化活性与金属配体有关,是一类潜在的抗癌药物。