摘要：Exclusive responsiveness to ultraviolet light (~3.2 eV) and high photogenerated charge recombination rate are the two primary drawbacks of pure TiO_(2). We combined N-doped graphene quantum dots (N-GQDs), morphology regulation, and heterojunction construction strategies to synthesize N-GQD/N-doped TiO_(2)/P-doped porous hollow g-C_(3)N_(4) nanotube (PCN) composite photocatalysts (denoted as G-TPCN). The optimal sample (G-TPCN doped with 0.1wt% N-GQD, denoted as 0.1% G-TPCN) exhibits significantly enhanced photoabsorption, which is attributed to the change in bandgap caused by elemental doping (P and N), the improved light-harvesting resulting from the tube structure, and the upconversion effect of N-GQDs. In addition, the internal charge separation and transfer capability of0.1% G-TPCN are dramatically boosted, and its carrier concentration is 3.7, 2.3, and 1.9 times that of N-TiO_(2), PCN, and N-TiO_(2)/PCN(TPCN-1), respectively. This phenomenon is attributed to the formation of Z-scheme heterojunction between N-TiO_(2) and PCNs, the excellent electron conduction ability of N-GQDs, and the short transfer distance caused by the porous nanotube structure. Compared with those of N-TiO_(2), PCNs, and TPCN-1, the H2 production activity of 0.1%G-TPCN under visible light is enhanced by 12.4, 2.3, and 1.4times, respectively, and its ciprofloxacin (CIP) degradation rate is increased by 7.9, 5.7, and 2.9 times, respectively. The optimized performance benefits from excellent photoresponsiveness and improved carrier separation and migration efficiencies. Finally, the photocatalytic mechanism of 0.1% G-TPCN and five possible degradation pathways of CIP are proposed. This study clarifies the mechanism of multiple modification strategies to synergistically improve the photocatalytic performance of 0.1% G-TPCN and provides a potential strategy for rationally designing novel photocatalysts for environmental remediation and solar energy conversion.

摘要：空气稳定有机自由基的发现引起了人们对探究其在分子电子学和自旋电子学中应用的兴趣.这些自由基具有独特的开壳层电子结构,因而表现出特殊的电学特性.由于其较弱的旋轨耦合特性,也使得其成为自旋电子学的重要研究对象.此外,自由基还可以通过二聚、分子识别和机械互锁等分子间相互作用来构筑超分子器件.本文综述了空气稳定有机自由基在电子学及自旋电子学中的应用,通过详述其卓越的电磁性能来拓展启发分子设计的多样性.本综述还概述了超分子自由基的制备方法和相关性质的研究进展,拓宽了单分子研究的范围.此外,自由基介导的单分子反应是一个新兴的研究方向,本文也对该领域的未来发展方向进行了展望.通过阐明空气稳定有机自由基的应用潜力,本文将有望对分子电子学和自旋电子学的研究产生一定的指导意义.

摘要：近年来,超三代移动通信系统的QoS体系结构已成为计算机网络领域和通信领域的一个研究热点.调研了相关的主要研究项目,通过对重点项目和国外该领域相关论文成果进行分析和比较,总结出未来B3G(beyond 3rdgeneration)系统QoS体系结构应是一种全IP的、层次化的、端到端的QoS体系结构,它应具有集成性、可管理性、可扩展性、自适应性和动态资源管理等特点.最后提出了B3G系统QoS体系结构的基本设计原则,并对未来工作进行了展望.

摘要：本文介绍了一种基于横向可移动栅极场效应晶体管(LMGFET)的新型微型力传感器的开发。提出了一种精确的电气模型,用于小型LMGFET器件的性能评估,与以前的模型相比,其精度有所提高。采用了一种新型三明治结构,该结构由一个金交叉解耦栅阵列层和两个软光阻层SU-8组成。通过所提出的双差分传感结构,LMGFET横向工作在垂直干扰下的输出电流被大大消除,所提出传感器的相对输出误差从4.53%(传统差分结构)降低到0.01%。提出了一种实用的传感器制造工艺,并对其进行了模拟。基于LMGFET的力传感器的灵敏度为4.65μA·nN^(-1),可与垂直可移动栅极场效应晶体管(VMGFET)器件相媲美,但非线性度提高了0.78%,测量范围扩大了±5.10μN。这些分析为LMGFET器件的电气和结构参数提供了全面的设计优化,并证明了所提出的传感器在生物医学显微操作应用中具有良好的力传感潜力。

摘要：为提高骨缺损修复的治疗效果,设计孔隙率为78.8%、70.8%、62.6%和54.4%的梯度多孔钛支架(分别表示为P1,P2,P3和P4),并通过选择性激光熔化技术进行制备。通过模拟和实验方法研究支架的成形性、显微组织、力学性能和渗透性能。模拟结果表明,4种梯度结构的最大等效应力和渗透性分别在569.1~1469.0MPa和(21.7~54.6)×10^(−9)m^(2)范围内,并且P3和P4具有更小的最大等效应力,表明P3和P4具有更高的强度。P3和P4结构支架的显微组织为α'马氏体,屈服强度和弹性模量分别为185.3~250.8MPa和6.1~9.7GPa。相比于P3结构支架,P4结构支架展现出更高的强度和与皮质骨更加匹配的弹性模量,并且其渗透性(18.6×10^(−9)m^(2))在人体骨组织渗透性范围内。因此,具有P4结构支架有望被应用于骨科植入领域。

摘要：The past decade has witnessed a surge of interest in exploring emergent particles in condensed matter *** particles,emerged as excitations around exotic band degeneracy points,continue to be reported in real materials and artificially engineered systems,but so far,we do not have a complete picture on all possible types of particles that can be ***,via systematic symmetry analysis and modeling,we accomplish a complete list of all possible particles in time-reversal-invariant *** includes both spinful particles such as electron quasiparticles in solids,and spinless particles such as phonons or even excitations in electric-circuit and mechanical *** establish detailed correspondence between the particle,the symmetry condition,the effective model,and the topological *** obtained encyclopedia concludes the search for novel emergent particles and provides concrete guidance to achieve them in physical systems.

摘要：基于弹塑性断裂力学的裂纹扩展机理,用弹塑性有限元分析压载荷对LY12M铝合金疲劳裂尖应力场的影响。介绍了可用于负应力比试验数据描述的两种实际应用的工程模型和一种已发表的称作"张模型"的双参数裂纹扩展模型,通过在相应坐标系下描述试验数据,并比较各自拟合线的线性相关度R2。结果验证"张模型"的拟合效果较好,是一种负应力比下预测铝合金疲劳裂纹扩展寿命的较好的工程方法,同时,由于部分参数可用弹塑性有限元计算获得,所以可节省大量新材料研究的经费。

摘要：开发非贵金属催化剂,特别是用于碳上铁氮(FeNC)材料的催化剂,对于质子交换膜燃料电池(PEMFC)的广泛应用是一个迫切需求。然而,传统铁氮位点在酸性条件下的氧还原反应(ORR)活性较差,严重阻碍了其电池性能的进一步提高。本文通过限域的小分子合成策略,大规模合成了具有一氧化氮(NO)基团轴向修饰的FeN_(4)(表示为NO-FeN_(4))。得益于NO基团的强吸电子效应,与传统的FeN_(4)样品相比,富含电子中心FeN_(4)位点表现出超高的ORR活性,具有三倍高的质量活性(0.85 V时为1.1 A·g^(−1)),以及全四电子反应选择性。此外,用所制备的电催化剂组装的质子交换膜燃料电池也表现出显著增强的峰值功率密度(>725 mW·cm^(−2))。这项工作为合理设计用于氧还原的先进M-Nx非贵金属电催化剂提供了一种新的方法。