摘要：RuO_(x)是一种有潜力的析氢反应(HER)电催化剂,然而,其表面上*OH和*H中间体的竞争吸附以及过度H结合导致其析氢性能较差.FeOOH具有较强的亲氧性,有望与RuO_(x)耦合形成RuO_(x)/FeOOH复合材料来有效促进HER动力学.鉴于Ru^(3+)的强氧化性,构建温和的反应环境是设计结构均匀、Ru位点可及的RuO_(x)/FeOOH复合材料的关键.本文提出一种乙醇调控铁腐蚀策略,在泡沫铁上原位生长了RuO_(x)/FeOOH电催化剂.醇羟基与Ru^(3+)配位降低了Ru^(3+)的氧化性,并减缓了其扩散,避免了剧烈的氧化还原反应.优化的纳米结构以及RuO_(x)和FeOOH之间的强电子相互作用,使所制备的催化剂在50和100 mA cm^(-2)电流密度下驱动HER和全解水,分别仅需67 mV过电位和1.56 V电压.基于羟基调控策略,乙二醇、正丙醇、异丙醇和甲醇同样可替代乙醇来增强RuO_(x)/FeOOH的HER活性.本工作提出了一种调节铁腐蚀行为的配位调控方法,为制备新型钌基复合催化剂提供了理论依据.

摘要：电子束光刻是纳米级硅光波导制作过程的关键工艺,本文以顶层硅220 nm的SOI晶圆为衬底研究了电子束光刻的主要工艺参数—曝光剂量对显影后的PMMA(聚甲基丙烯酸甲酯)正性抗蚀剂结构轮廓的影响,根据测量结果分析曝光剂量与显影后结构图形宽度的关系,找到最佳曝光剂量220μC/cm^(2)以便通过后续工艺得出与掩膜尺寸一致的最终结构。同时,依据图像分割曲线跟踪技术对剂量测试结果图进行轮廓提取处理,分析掩膜设计值和曝光剂量与边界轮廓二维粗糙度之间的关系,为后续相同衬底材料的电子束光刻提供参考意义。

摘要：Since the complex impeller structure and the difficult remanufacturing process may easily cause advance remanufacturing or excessive use,an optimized design method of impeller and service mapping model was presented for its proactive remanufacturing with setting up to explore the best remanufacturing time point in this *** a certain model of long distance pipeline compressor impeller with the Basquin equation and the design method of impeller,the mathematical relationship between the changes of structure and life of the impeller was *** the service mapping model between the structure and life was set up and simulated by ANSYS ***,the service mapping model was applied to feedback the original design for proactive *** this work,the best proactive remanufacturing time point of impeller was analyzed with the service mapping model,and the structural parameter values could be optimized at this time ***,in the results of this simulation,it proves that the impeller under this optimization performance could satisfy the impeller operating ***,comparing with the traditional optimization design method,the remanufacturing optimized design based on the service mapping model is feasible in proactive remanufacturing for sustainable development.

摘要：电容去离子(CDI)是一种具有良好发展前景的脱盐技术,CDI脱盐性能很大程度上取决于电极材料的结构和性质。本文以金属有机框架材料ZIF-67作为前驱体,制备了三种不同形态结构的ZIF-67基纳米多孔衍生碳材料,包括碳纳米盒(ZCNB)、碳纳米管(ZCNT)以及碳纳米盒和碳纳米管混合物(ZCNH),并研究了三种衍生碳材料的孔隙结构、表面性质、电化学性质与CDI性能构效关系。结果表明,三种ZIF-67基纳米多孔衍生碳材料中,由于ZCNB具有高比表面积、良好的润湿性、高表面电荷和合适的孔径,因此ZCNB具有最高的CDI除盐能力。尽管ZCNH和ZCNT中的碳纳米管可以提高碳材料的导电性,但同时降低了碳材料的比表面积和表面润湿性,从而降低了CDI除盐性能。本文将为MOFs基衍生碳电极材料的设计提供理论和实验指导。

摘要：The construction of waste rock dumps on existing tailing ponds has been put into practice in china to save precious land resources. This work focuses on the safety assessment of the Daheishan molybdenum mine waste rock dump under construction on two adjoining tailings ponds. The consolidation of the tailings foundation and the filling quality of the waste rock are investigated by the transient electromagnetic method through detecting water-rich areas and loose packing areas, from which, the depth of phreatic line is also estimated. With such information and the material parameters, the numerical method based on shear strength reduction is applied to analyzing the overall stability of the waste rock dump and the tailings ponds over a number of typical cross sections under both current and designed conditions, where the complex geological profiles exposed by site investigation are considered. Through numerical experiments, the influence of soft lenses in the tailings and possible loose packing areas in the waste rock is examined. Although large displacements may develop due to the soft tailings foundation, the results show that the waste rock dump satisfies the safety requirements under both present and designed conditions.

摘要：侧风作用是影响高速磁浮系统动力设计的重要因素之一。为获得侧风作用下高速磁浮列车-轨道梁耦合振动响应,首先,建立了风-静悬磁浮列车-轨道梁(WSMG)和风-移动磁浮列车-轨道梁(WMMG)空间耦合分析模型。然后,通过风洞试验对磁浮车辆的气动特性进行测试。磁浮列车的控制系统采用比例-积分-微分(PID)控制器和加速度反馈相结合的比例-积分-微分-加速度(PIDA)控制算法进行调控。最后,分析了平均风、脉动风、风速和车速对磁浮系统动力响应的影响。结果表明:PIDA控制算法可以消除侧风引起的磁浮间隙稳态误差,并减小大约40%的车体横向位移;均匀风只改变列车的平衡位置,脉动风和轨道不平整是引起磁浮列车-轨道系统振动的主要原因;风速对车辆的横向振动的影响更为敏感,当风速超过30 m/s时,高速磁浮列车应停止运行。

摘要：同步条件二种小世界(SW ) 网络一再学习。小世界拓扑学罐头大部分在横梁运输网络( BTN )的动态行为上影响，如果 BTN 与 SW 拓扑学被构造，全球线性联合和特殊线性反馈能也认识到横梁光圈混乱的同步控制 asper 在有 SW 拓扑学的 BTN 的碘的状态分别地。这重要结果能提供一个有效方法因为试验性的学习和在驱使放射性的 high-currentaccelerator 的 BTN 的设计设计清洗原子力量系统，并且可以为光圈混乱在未来的应用有潜在的使用安全通讯。

摘要：A novel kind of SC（superconducting） solenoid coil is designed to satisfy the homogencity requirement of the magnetic *** this paper,we first calculate the current density distribution of the solenoid coil section through the linear programming *** a traditional solenoid and a nonrectangular section solenoid are designed to produce a central field up to 7 T with a homogencity to the greatest *** comparision of the two solenoid coils designed in magnet field quality,fabrication cost and other aspects,the new design of the nonrectangular section of a solenoid coil can be realized through improving the techniques of framework fabrication and ***,the outlook and error analysis of this kind of SC magnet coil are also discussed briefly.

摘要：Failure data from oilfield showed that casings which were designed according to API standards were deformed and collapsed in salt formations. The main reason for decrease in strength may be caused by non-uniform loading(NUL) that was not considered in traditional casing collapsing strength design or that the designing method should be improved and developed. Obviously, the calculation of casing collapse strength is one of the key factors in casing design. However, the effect of NUL on casing collapse strength was generally neglected in the present computational methods. Therefore, a mechanical model which can calculate casing collapse strength under NUL was established based on the curved beam theory of the elasticity and was solved using displacement method. Simultaneously, three anti-collapse experiments were performed on C110 casing under NUL, and the strain and deformation laws of three casings in the process of collapse were obtained by the electrical method. Yield limit of every casing was obtained by analyzing those data. Experimental results are consistent with the results of calculation of new model. It indicates that the model can be used to calculate yield limit loading of casings under NUL.

摘要：在深部开挖工程中,深部岩石往往经历“三轴高应力+开挖卸荷+动力扰动”的全应力过程。为了研究围压卸荷对深部预应力岩石的动态破坏特征的影响,采用改进的分离式霍普金森压杆对红砂岩进行了一系列三轴卸荷动态压缩试验,还进行了单轴预应力冲击压缩试验(不考虑围压卸荷效应)。结果表明,红砂岩的动态抗压强度表现出明显的应变率效应。在应变率近似相等的情况下,三轴卸荷动态压缩试验中岩石的动态强度小于单轴预应力冲击压缩试验中岩石的动态强度。围压卸荷造成明显的强度弱化效应,并采用动态强度弱化因子(DSWF)量化强度弱化程度。在同一个应力路径下,岩石的应变率和入射能呈对数关系;而在入射能相同时,卸荷会导致预应力岩石有着更高的应变率。分析了试样的破坏模式,发现卸荷对试样破坏模式的影响并不显著。此外,讨论了围压卸荷对剪切强度参数(内聚力和摩擦角)的影响。在入射能相同时,发生卸荷后的预应力岩石更容易发生破坏。因此,在深部岩石工程开挖设计中应考虑卸荷对岩石力学特性的影响。