摘要：Selective hydrogenolysis of glycerol to 1,3‐propanediol（1,3‐PD） is an important yet challenging method for the transformation of biomass into value‐added chemicals due to steric hindrance and unfavorable thermodynamics. In previous studies, chemoselective performances were found de‐manding and sensitive to H2 pressure. In this regard, we manipulate the chemical/physical charac‐teristics of the catalyst supports via doping Nb into WOx and prepared 1D needle‐, 2D flake‐, and 3D sphere‐stack mesoporous structured Nb‐WOx with increased surface acid sites. Moreover, Nb dop‐ing can successfully inhibit the over‐reduction of active W species during glycerol hydrogenolysis and substantially broaden the optimal H2 pressure from 1 to 5 MPa. When Nb doping is 2%, sup‐ported Pt catalysts showed promising performance for the selective hydrogenolysis of glycerol to 1,3‐PD over an unprecedentedly wide H2 pressure range, which will guarantee better catalyst sta‐bility in the long run, as well as expand their applications to other hydrogen‐related reactions.

摘要：Future climate change is usually projected by coupled earth system models under specific emission sce- narios designed by integrated assessment models （IAMs）, and this offline approach means there is no interaction between the coupled earth system models and the IAMs. This paper introduces a new method to design possible future emission scenarios and corresponding climate change, in which a simple economic and climate damage component is added to the coupled earth system model of Beijing Normal University （BNU-ESM）. With the growth of population and technological expertise and the declining emission-to-output ratio described in the Dynamic Inte- grated Climate-Economy model, the projected carbon emission is 13.7 Gt C, resulting in a 2.4℃ warming by the end of the twenty-first century （2080-2099） compared with 1980-1999. This paper also suggests the importance of the land and ocean carbon cycle in determining the CO2 con- centration in the atmosphere. It is hoped that in the near future the next generation of coupled earth system models that include both the natural system and the social dimension will be developed.

摘要：Photocatalytic hydrogen production represents a promising strategy for clean, sustainable, and environmentfriendly energy supply. Up to now, great efforts have been devoted to designing the photocatalysts with noble metal as co-catalyst for visible-light-driven hydrogen evolution, while more efficient photocatalytic systems are still a major challenge. Herein, we report a facile strategy for synthesizing faceto-face ultrathin Pd nanosheets-amorphous carbon nitride(Pd NSs-ACN) structure with large contacting interface and short electronic transmission pathway, which can work as an efficient photocatalyst for hydrogen production. The synthesis starts with the growth of ultrathin Pd NSs, followed by assembly with the visible-light-response ACN through a simple stirring and annealing procedure. The resultant two dimensional face-to-face structures deliver an average hydrogen generation rate of 1.45 mmol h-1g-1 at a temperature of 25℃,almost 2.6 times higher than that of Pd Nps-ACN with particle-to-face structural feature. The efficient photocatalytic activity is ascribed to the formation of high-density of active sites between ultrafine face-to-face contacted Pd NSs and the ACN, which cooperate more synergistically towards photocatalytic hydrogen production. The face-to-face engineered Pd NSs-ACN hybrids also offer a good stability revealed by photocatalytic hydrogen production measurements. The extraordinary performance highlights a powerful engineering model for designing other face-to-face contacting co-catalyst/photocatalysts, which will be a great impetus to optimize new catalytic transformations.

摘要：Cadaverine. a natural polyamine with multiple bioactivities that is widely distributed in prokaryotes and eukaryotes, is becoming an important industrial chemical. Cadaverine exhibits broad prospects for various applications, especially as an important monomer for bio-based polyamides. Cadaverine-based polyamide PA 5X has broad application prospects owing to its environmentally friendly characteristics and exceptional performance in water absorption and dimensional stability. In this review, we summarize recent findings on the biosynthesis, metabolism, and physiological function of cadaverine in bacteria, with a focus on the regu- latory mechanism of cadaverine synthesis in Escherichia coil （E. coli）. We also describe recent developments in bacterial production of cadaverine by direct fermentation and whole-cell bioconversion, and recent approaches for the separation and purification of cadaverine. In addition, we present an overview of the ap- plication of cadaverine in the synthesis of completely bio-based polyamides. Finally. we provide an outlook and suggest future developments to advance the production of cadaverine from renewable resources.

摘要：Intellectualization has become a new trend for telecom industry, driven by intelligent technology including cloud computing, big data, and Internet of things. In order to satisfy the service demand of intelligent logistics, this paper designed an intelligent logistics platform containing the main applications such as e-commerce, self-service transceiver, big data analysis, path location and distribution optimization. The intelligent logistics service platform has been built based on cloud computing to collect, store and handling multi-source heterogeneous mass data from sensors, RFID electronic tag, vehicle terminals and APP, so that the open-access cloud services including distribution, positioning, navigation, scheduling and other data services can be provided for the logistics distribution applications. And then the architecture of intelligent logistics cloud platform containing software layer(SaaS), platform layer(PaaS) and infrastructure(IaaS) has been constructed accordance with the core technology relative high concurrent processing technique, heterogeneous terminal data access, encapsulation and data mining. Therefore, intelligent logistics cloud platform can be carried out by the service mode for implementation to accelerate the construction of the symbiotic win-winlogistics ecological system and the benign development of the ICT industry in the trend of intellectualization in china.

摘要：Considering the dependent relationship among wave height,wind speed,and current velocity,we construct novel trivariate joint probability distributions via Archimedean copula *** 30-year data of wave height,wind speed,and current velocity in the Bohai Sea are hindcast and sampled for case *** kinds of distributions,namely,Gumbel distribution,lognormal distribution,Weibull distribution,and Pearson Type III distribution,are candidate models for marginal distributions of wave height,wind speed,and current *** Pearson Type III distribution is selected as the optimal *** and trivariate probability distributions of these environmental conditions are established based on four bivariate and trivariate Archimedean copulas,namely,Clayton,Frank,Gumbel-Hougaard,and Ali-Mikhail-Haq *** joint probability models can maximize marginal information and the dependence among the three *** design return values of these three variables can be obtained by three methods:univariate probability,conditional probability,and joint *** joint return periods of different load combinations are estimated by the proposed *** responses(including base shear,overturning moment,and deck displacement) are further *** the same return period,the design values of wave height,wind speed,and current velocity obtained by the conditional and joint probability models are much smaller than those by univariate *** the dependence among variables,the multivariate probability distributions provide close design parameters to actual sea state for ocean platform design.

摘要：Sodium metal anode holds great promise in pursuing high-energy and sustainable rechargeable batteries,but severely suffers from fatal dendrite growth accompanied with huge volume ***,a robust mixed conducting sodium metal anode is designed through incorporating Na SICON-type solid Na-ion conductor into bulk Na.A fast and continuous pathway for simultaneous transportation of electrons and Na+is established throughout the composite *** intimate contact between Na-ion conducting phase and Na metallic phase constructs abundant two-phase boundaries for fast redox ***,the compact configuration of the composite anode substantially protects Na metal from being corroded by liquid organic electrolyte for the minimization of side *** from the unique configuration,the composite anode shows highly reversible and durable Na plating/stripping *** symmetric cells exhibit ultralong lifespan for over 700 h at 1 mA cm^(-2)with a high capacity of 5 m Ah cm^(-2)and outstanding rate capability up to 8 m A cm^(-2)in the carbonate *** cells with Na_(3)V_(2)(PO_(4))_(3)/C cathode demonstrate impressive cycling stability(capacity decay of 0.012%per cycle)and low charge/discharge polarization as *** work provides new insights into rational design and development of robust sodium metal anode through an architecture engineering strategy for advanced rechargeable sodium batteries.

摘要：A series of shape-persistent polyphenylene dendritic C_(60)derivatives as the electron transport materials were designed and synthesized via a catalyst-free Diels-Alder[4+2]cycloaddition *** increasing hyperbranched scaffolds could effectively enhance the solubility;notably,both first and second generation dendrimers,C_(60)-G1 and C_(60)-G2,demonstrated more than 5 times higher solubilities than pristine C_(60).Furthermore,both simulated and experimental data proved their promising solution-processabilities as electron-transporting layers(ETLs)for perovskite solar *** a result,the planar p-i-n structural perovskite solar cell could achieve a maximum power conversion efficiency of 14.7%with C_(60)-G2.

摘要：In order to provide a provincial spatial database, this paper presents a scheme for spatial database construction to meet the needs of china. The objective and overall technical route of spatial database construction are described. The logical and physical database models are designed. key issues are addressed, such as integration of multi-scale heterogeneous spatial databases, spatial data version management based on metadata and integrative management of map cartography and spatial database.

摘要：Hollow metal-organic frameworks(MOFs)and their derivatives have attracted more and more attention due to their high specific surface area and perfect morphological structure,which determine their large potential application in energy storage and catalysis ***,few researchers have carried out further modification on the outer shell of hollow MOFs,such as the perforation modification,which will endow hollow nanomaterials derived from MOFs with *** this paper,hollow MOFs of MIL-53(Fe)with perforated outer surface are successfully synthesized by using SiO2 nanospheres as the template via a self-assembly process induced by the coordination *** tightly packed mesopore structure makes the carbon outer shell of MOFs thinner,thus realizing the in-situ transformation from MOFs to hollow Fe3 O4/carbon,which exhibits perfect capacity approaching 1270 mA h g-1 even after 200 cycles at 0.1 A g-1,as an anode material in lithium ion batteries(LIBs)*** research provides a new strategy for the design and preparation of MOFs and their derivatives with multifunctionality for the energy applications.