摘要：The ground-based experimental tests are crucial to verify the related technologies of the drag-free *** work presents a design method of the ground simulator testbed for emulating the planar dynamics of the space drag-free *** this paper,the planar dynamic characteristics of the drag-free satellite with double test masses are analyzed and nondimensionalized.A simulator vehicle composed of an air bearing testbed and two inverted pendulums is devised on the basic of equivalent mass and equivalent stiffness proposed firstly in this *** the dynamic model of the simulator equivalent to the sensitive axis motion of the test mass and the planar motion of the satellite is derived from the Euler-Lagrange ***,the dynamic equivalence conditions between the space prototype system and the ground model system are derived from Pi *** satisfy these conditions,the scaling laws of two systems and requirements for the inverted pendulum are put ***,the corresponding control scaling laws and a closed-loop control strategy are deduced and applied to establishing the numerical simulation experiments of underactuated ***,the comparative simulation results demonstrate the similarity of dynamical behavior between the scaled-down ground model and the space *** a result,the rationality and effectiveness of the design method are proved,facilitating the ground simulation of future gravitational wave detection satellites.

摘要：Fast electron-hole recombination issues during titanium dioxide(TiO_(2))photocatalysis limit its application in preventing bacterial infection during bone defect *** this study,TiO_(2)@reduced graphene oxide(rGO)composites were synthesized using a hydrothermal method in which rGO,which possesses very high electrical conductivity,promotes the separation of photoelectron-hole pairs of TiO_(2),thus improving the efficiency of photocatalytic production of reactive oxygen species(ROS).Subsequently,TiO_(2)@rGO composites were introduced into poly-L-lactic acid(PLLA)to prepare bone scaffolds with photocatalytic antibacterial function via selective laser *** results showed that TiO_(2)grew on the surface of rGO and formed a covalent bond connection(Ti-O-C)with rGO.A decreased electrochemical impedance of TiO_(2)@rGO composites was observed,and the transient photocurrent intensity increased from 0.05 to 0.5μA/cm^(2).Analysis of electron spin resonance found that the photocatalytic products of TiO_(2)were·OH and·O^(2-),two kinds of ROS capable of killing bacteria via disrupting the structure of the bacterial membrane in *** experiments showed that the PLLA/TiO_(2)@rGO scaffolds had good antibacterial properties against Escherichia coli and Staphylococcus ***,we report that these scaffolds exhibited both enhanced mechanical properties due to the addition of TiO_(2)@rGO as a reinforcement material and good biocompatibility during cell proliferation.

摘要：Homogeneous redox mediation is efficient in alleviating the shuttling effect and slow redox kinetics of lithium polysulfides in lithium-sulfur ***,their perfect performance is not fulfilled owning to the fact that the multi-step transformation of lithium polysulfides requests the multifunctional active positions for the tandem *** on the redox comediation principles,a promoter of mixing organodiselenide and organoditelluride(mixed-Se/Te)was raised to induce tandem catalysis and boost the effective electrochemical conversion of lithium *** specifically,diphenyl diselenide facilitated the liquid-liquid and solid-liquid transformation between lithium polysulfides and sulfur,while diphenyl ditelluride improved the solid-liquid transformation concerning lithium sulfide ***,even under high sulfur loading of 6.5 mg cm^(−2) and low electrolyte/sulfur ratio of 5.88μL mg^(−1),the 10 mM low concentration mixed-Se/Te promoter offered a high discharge capacity of 6.6 mAh cm^(−2) and high rate performance of 4.1 mAh cm^(−2) at 0.5 ***,the assembled 1.5 Ah-level lithium-sulfur pouch cells provide an energy density of 332 Wh kg^(−1) at 0.05 C and good cycling *** research demonstrates the applicability of propelling continuous sulfur conversion reactions with detached active positions and is anticipated to stimulate deep molecular design of kinetic promoter to targeted energy-associated redox reactions.

摘要：Covalent organic frameworks(COFs)are garnering significant interest in photocatalytic CO_(2) ***,their limited efficiency in separating photogenerated carriers and the scarcity of catalytic sites lead to suboptimal photocatalytic *** we develop a molecular engineering approach to design a pyrene-based COF(PyTa-H COF)confined cobalt single atoms photocatalyst(Co SACs)for CO_(2) *** moiety is introduced to enhance visible-light harvesting capability and improve charge separation in the ***,Co SACs enhance the photocatalytic activity by accelerating the migration of photo-induced carriers and reducing the reaction energy of the rate-determining ***,PyTa-H@Co achieves a CO production rate of 18.36 mmol g^(−1) h^(−1) and a selectivity of 94%in 4 h under visible light irradiation,which is comparable to the reported best-performing *** functional theory calculations reveal that the Co SACs greatly stabilize*COOH and significantly reduce the energy of the decisive step,leading to outstanding photocatalytic *** work,through molecular engineering design,highlights the critical relationship between catalyst structure and function in enhancing photocatalytic efficiency.

摘要：The global demand for effective skin injury treatments has prompted the exploration of tissue engineering *** three-dimensional(3D)bioprinting has shown promise,challenges persist with respect to achieving timely and compatible solutions to treat diverse skin *** situ bioprinting has emerged as a key new technology,since it reduces risks during the implantation of printed scaffolds and demonstrates superior therapeutic ***,maintaining printing fidelity during in situ bioprinting remains a critical challenge,particularly with respect to model layering and path *** study proposes a novel optimization-based conformal path planning strategy for in situ bioprinting-based repair of complex skin *** strategy employs constrained optimization to identify optimal waypoints on a point cloud-approximated curved surface,thereby ensuring a high degree of similarity between predesigned planar and surface-mapped 3D ***,this method is applicable for skin wound treatments,since it generates 3D-equidistant zigzag curves along surface tangents and enables multi-layer conformal path planning to facilitate the treatment of volumetric ***,the proposed algorithm was found to be a feasible and effective treatment in a murine back injury model as well as in other complex models,thereby showcasing its potential to guide in situ bioprinting,enhance bioprinting fidelity,and facilitate improvement of clinical outcomes.

摘要：Machine learning (ML) has been widely used todesign and develop new materials owing to its low computational cost and powerful predictive capabilities. In recentyears, the shortcomings of ML in materials science have gradually emerged, with a primary concern being the scarcity ofdata. It is challenging to build reliable and accurate ML modelsusing limited data. Moreover, the small sample size problemwill remain long-standing in materials science because of theslow accumulation of material data. Therefore, it is importantto review and categorize strategies for small-sample learningfor the development of ML in materials science. This reviewsystematically sorts the research progress of small-samplelearning strategies in materials science, including ensemblelearning, unsupervised learning, active learning, and transferlearning. The directions for future research are proposed, including few-shot learning, and virtual sample *** importantly, we emphasize the significance of embedding material domain knowledge into ML and elaborate on thebasic idea for implementing this strategy.

摘要：Lithium metal batteries (LMBs) using gelpolymer electrolytes with satisfactory theoretical capacity andlow cost hold great promise for high energy density storagesystems. However, the inherently unwanted polarizations anduncontrolled lithium dendrites resulting from inferior Li-iontransporting efficiency hinder the practical application ofconventional gel electrolytes. Herein, a highly conductivecomposite gel polymer electrolyte with effective Li-ion conducting channels is designed via swelling nanofibrous membrane, where the single-ion conducting polymer of lithiumsulfonate-based polyether (DEBS-Li) used as the Li-ion accelerator is combined with poly(vinylidene fluoride-hexafluoropropylene)P(VDF-HFP) matrix by the electrospinningtechnology. The DEBS-Li having rich sulfonic groups canpromote lithium salts dissociation via electrostatic interaction,thus expediting the ionic migration and enabling the as-developed gel electrolyte with high ionic conductivity (~1.58×10^(−3) S cm^(−1)) and lithium transference number (0.62) at 25℃.Such optimization of ionic transfer kinetics can highly delaythe nucleation time of lithium dendrite and significantly inhibit dendritic formation, which leads to a stable Li plating/stripping in the symmetrical battery over 250 h at1.5 mA cm^(−2). Benefiting from these advantages, the Li||LiFePO_(4)cell using the electrolyte realizes ultralong stable cyclingover 500 cycles at a high rate of 10 C with ~90% capacityretention. We believe this novel lithium sulfonate-basedpolyether gel polymer electrolyte has profound potential forpractical applications in high-performance LMBs.

摘要：Accurate detection of multiple small end-metabolic biomarkers is more sensitive than large biomoleculesto provide real-time feedbacks of physiological/pathologicalstate, but is more challenging due to lack of specific identifyinggroups. Current optical platforms suffer from unsatisfactoryresolutions to differentiate each target because they producesimilar output to different targets using a single excitation,and inevitably involve non-functional components that increase chances of interacting with non-target ***, by taking full advantage of each building unit’sfunctionality to integrate multivariate recognition elements inone interface, a dual-excitation-driven full-component-responsive metal-organic framework (MOF)-based luminescentprobe, namely CeTMA-TMA-Eu, is successfully custom-tailored for detecting both pseudouridine (Ψ) and N-acetylaspartate (NAA), the diagnostic hallmarks of cancer andneurodegenerative disorder. Remarkably, Ψ interacts withMOF’s organic building unit (trimesic acid, TMA) and filtersout its absorptions of 262 nm-light to reduce its energytransferred to Eu^(3+), while NAA induces the valence transitionof Ce^(4+)/Ce^(3+) nodes to improve the cooperative energy transferefficacy from TMA and Ce^(3+) to Eu^(3+). As a result, this platformexhibits completely reverse photoresponses towards Ψ(“switch-off” at 262 nm excitation) and NAA (“switch-on”upon 296 nm excitation), and demonstrates excellent selectivity and sensitivity in complex biofluids, with low detection limits of 0.16 and 0.15 μM, and wide linear ranges of0–180 and 0–100 μM, respectively. Such full-componentresponsive probe with dual-excitation-mediated reverse responses for multi-small targets intrinsically minimizes its interaction with non-target molecules and amplifies resolutionto discriminate each target, providing a new strategy for improving assay accuracy of multi-small biomarkers in diagnostics.

摘要：The low temperature,high salt content,and bacterial composition of a seawater environment can induce severe infections in open wounds,thus impeding wound *** date,numerous wound dressings have been developed for injuries and various antibacterial ***,ordinary antibacterial strategies could not provide long-term resistance to infections and could not promote wound ***,we proposed a strategy for enhancing resistance to seawater immersion wound infection by killing bacteria and delivering bacterial antigens in ***,MXene-embedded tannin-Eu^(3+)(M@TA-Eu)particles were constructed to effectively alleviate injuries infected through seawater immersion and persistently fight infection by forming in situ bacterial vaccines and immune *** the particle,the platform composed of TA and Eu3+exhibited provascularization and antigen presentation *** with near-infrared photothermal effect were introduced to kill the bacteria,promote the recruitment of antigen presentation cells,and ultimately enhance vaccination *** results showed that the particles not only effectively accelerated the healing of injuries by relieving wound inflammation and inhibiting bacteria but also produced a potent vaccination by forming in situ bacterial ***,the M@TA-Eu particles are novel materials for high-grade anti-infection dressing.

摘要：The A–D–A′–D–A-type non-fused ring electron acceptors(NFREAs),consisting of electron-donating unit(D)as the bridge to link electron-accepting units(A and A′),have emerged as promising electron acceptors for organic solar cells(OSCs)and organic photodetectors(OPDs).As the units are linked by the carbon–carbon single bonds,these electron acceptors generally possess feasible synthesis and tunable optoelectronic ***,the recent progress of A–D–A′–D–A-type NFREAs is reviewed,including molecular design,device performance,structure–property relationships,and their applications in OSCs and ***,we discuss the challenges and propose the perspectives for the further development of A–D–A′–D–A-type NFREAs.