摘要：简要介绍高熵合金的发展和其相形成判据。针对高熵合金的大数据体系提出一种新的合金设计形式,涉及并研究了一种新型的高熵合金。结果表明:A_xB_yC_((100-a-b-x-y))D_aE_b的涉及形式比起以往的伪二元系合金形式,如A_xBDE,更加符合大数据体系的要求。提出的设计方法能够直观快捷的从高熵合金大数据体系中筛选出预期的合金成分。本研究设计的高熵合金AlCoCrFeMo_(0.05)Ni_2与目标合金相符,且在700℃下有很好的应用前景。

摘要：The double drum coal shearer is widely applied for the underground coal exploration in the mining *** vibration and noise control are significant factors for the stability design of the double drum coal *** this paper,the vibration properties of a double drum coal shearer are firstly *** horizontal,transverse and torsional vibrations of the motor body and the angle displacements of the rockers are taken into *** walking units and the hydraulic units are modeled by the stiffness-damping *** nonlinear equation of motion of the double drum coal shearer is established by applying the Lagrange’s *** nonlinear vibration response of the system is calculated by using the Runge Kutta numerical *** effects of the shearing loads,the equivalent damping and stiffness of the walking units,the inclination angels of the rockers and the equivalent damping and stiffness of the hydraulic units on the vibration properties of the system are discussed.

摘要：The self-assembled phospholipid-or cytosolassociated multienzyme complexes constitute necessary components of the foundation of *** a proof of concept,metalcoordinated supramolecular nanogels (MCSGs) have been designed,with the self-assembly of di-lysine coordinated iron(Fe(Lys)_(2))-functionalized peptide gelators on the interface by an in situ amidation-induced protonation *** monoatomic and highly dispersed active centers of Fe(Lys)_(2) offered the nanogel mimics with excellent reaction rates due to the high density and nano compartmental structure similar to the natural matrix-associated multienzyme ***_(2)@MCSGs show both superoxide dismutase (SOD) activity and peroxidase (POD) activity,and the higher activities compared with the activity of free Fe(Lys);molecules can be *** loading the substrate 2,2'-azinobis-(3-ethylbenzthiazoline-6-sulphonate)(ABTS),SiO_(2)@MCSGs;can responsively convert O^(-)_(2) in the tumor microenvironment into H_(2)O_(2) intermediates and then tandem catalyze the oxidization of ABTS for contrast photoacoustic (PA) imaging of tumor by the SOD-POD mimic activity,showing their great potential as the efficient enzymatic agents for pathological theranostics.

摘要：Backgrou nd Dense titanium(Ti)fusion cages have been commonly used in transforaminal lumbar interbody ***,the stiffness mismatch between cages and adjacent bone endplates increases the risk of stress shielding and cage *** The current study presents a multiscale optimization approach for porous Ti fusion cage development,including microscale topology optimization based on homogenization theory that obtains a unit cell with prescribed mechanical properties,and macroscale topology optimization that determines the layout of framework structure over the porous cage while maintaining the desired *** biomechanical performance of the designed porous cage is assessed using numerical simulations of fusion *** laser melting is employed to assists with fabricating the designed porous structure and porous *** The simulations demonstrate that the designed porous cage increases the strain energy density of bone grafts and decreases the peak stress on bone *** mechanical and morphological discrepancies between the as-designed and fabricated porous structures are also *** From the perspective of biomechanics,it is demonstrated that the designed porous cage contributes to reducing the risk of stress shielding and cage *** optimization of processing parameters and post-treatments are required to fabricate the designed porous *** present multiscale optimization approach can be extended to the development of cages with other shapes or materials and further types of orthopedic implants.

摘要：ZnO is a typical direct wide-bandgap semiconductor material, which has various morphologies and unique physical and chemical properties, and is widely used in the fields of energy, information technology, biomedicine, and others. The precise design and controllable fabrication of nanostructures have gradually become important avenues to further enhancing the performance of Zn O-based functional nanodevices. This paper introduces the continuous development of patterning technologies, provides a comprehensive review of the optical lithography and laser interference lithography techniques for the controllable fabrication of Zn O nanostructures, and elaborates on the potential applications of such patterned Zn O nanostructures in solar energy, water splitting, light emission devices, and nanogenerators. Patterned Zn O nanostructures with highly controllable morphology and structure possess discrete three-dimensional space structure, enlarged surface area, and improved light capture ability, which realize the efficient carrier regulation,achieve highly efficient energy conversion, and meet the diverse requirements of functional nanodevices. The patterning techniques proposed for the precise design of Zn O nanostructures not only have important guiding significance for the controllable fabrication of complex nanostructures of other materials, but also open up a new route for the further development of functional nanostructures.

摘要：High-temperature proton exchange membrane(HT-PEM)fuel cells offer more advantages than low-temperature PEM fuel *** ideal characteristics of HT-PEMs are high conductivities,low-humidity operation conditions,adequate mechanical properties,and competitive *** molecular moieties,such as benzimidazole,benzothiazole,imide,and ether ether ketone,have been introduced to polymer chain backbones to satisfy the application requirements for *** most common sulfonated polymers based on the main chain backbones have been employed to improve the *** group/chain engineering,including the introduction of SO_(3)^(-) on the side chain,grafting,branching,and crosslinking,has been widely applied to HTPEMs to further improve their proton conductivity,thermal stability,and mechanical ***,phosphoric acid-doped polybenzimidazole is the most successful polymer material for application in *** compositing/blending modification methods of polymers are effective in obtaining high PA-doping levels and superior mechanical *** this review,the current progress of various membrane materials used for HT-PEMs is *** synthesis and performance characteristics of polymers containing specific moieties in the chain backbones applied to HT-PEMs are discussed *** modification approaches and their deficiencies associated with HT-PEMs are analyzed and *** and future challenges are also presented.

摘要：Glass-forming ability is a long-standing concern in the field of metallic glasses(MGs),which greatly limits their maximum casting size and extensive *** this work,we report an ultrasonic-assisted rapid cold welding of bulk MGs without using any *** with various compositions are welded together under a 20,000-Hz highfrequency ultrasonic vibration without losing their amorphous *** ultrasonic technology offers the advantages of rapid bonding(<1 s)at low temperature(near room temperature)and low stress(<1 MPa).According to the phenomenon observed in the experiment,the activated fresh atoms diffuse through the broken channel port under continuous rupture of the oxide layer,and the ultrasonic vibration accelerates the atomic-diffusion ***,stable bonding of the MG interface is *** universal ultrasonic-assisted welding process can realize the composition design of dissimilar MGs as well as tuning of new materials with new performance.

摘要：A novel metal/semiconductor photocatalyst,Cu nanoparticles(NPs)modified TiO2 hollow spheres(Cu/TiO2),was designed for efficient photocatalytic overall water splitting(POWS)under both ultraviolet(UV)and visible(Vis)*** Cu/TiO2 photocatalyst possesses excellent POWS performance under Vis light at the highest level among the reported TiO2-based ***,the metal/semiconductor junction formed between Cu and TiO2 enables controlled water-oxidation product selectivity(H2O2 or O2)via different reaction pathways regulated by irradiation *** UV light,the electrons excited in TiO2 are captured by Cu NPs through the Cu/TiO2 Schottky interface for H2 production,with the photoholes in TiO2 producing H2O2 through a two-electron process;whilst under Vis light,Cu NPs act as plasmon to inject hot electrons to TiO2 for H2 production,while O2 is produced by hot holes on Cu NPs via a four-electron *** rational design of function-switchable metal/semiconductor junction may be helpful to understand the mechanisms for POWS with desired gas/liquid water-oxidation products.

摘要：Extremely small-sized iron oxide nanoparticles(ESIONPs)with sizes less than 5 nm have shown great promise as T_(1)contrast agents for magnetic resonance imaging(MRI).However,their facile and scalable production with simultaneously endowed biocompatible surface chemistry remains difficult to be *** this study,by using the coprecipitation method implemented in a specially designed gas/liquid mixed phase fluidic reactor,polyglucose sorbitol carboxymethyether(PSC)coated ESIONPs were continuously synthesized with controllable particle sizes ranging from 1.8 to 4 *** the differently sized ESIONPs,the 3.7-nm ESIONPs exhibit the best performance as T_(1)MRI contrast agent,featuring a high r_(1) value of 4.11(mmol L^(−1))^(−1)s^(−1)and low r_(2)/r_(1) ratio of 7.90 under a clinical 3 T MR scanning,as well as the excellent T_(1)MRI contrast effect in not only water but also the cellular environment and blood ***,the ESIONPs possess long-term stability and good dispersity in aqueous dispersions,making them ideal candidates as safe and effective T_(1)-weighted MRI contrast agent for real clinical use.

摘要：An optimized compound 9-(9,9-dimethylacridin-10(9 H)-yl)-6 H-benzo[c]ch-romen-6-one(MAB) was designed and synthesized based on our previously reported TADF emitter 6-(9,9-dimethylacridin-10(9 H)-yl)-3-methyl-1 H-isochromen-1-one(MAC) to further improve the performance of thermally activated delayed fluorescence(TADF)emitters. With the additional phenyl in coumarin-contained plane, MAB possesses an extended distribution of the lowest unoccupied molecular orbitals(LUMO), and thus realizes reduced electron exchange between the frontier molecular orbitals and a stretched molecular dipole moment compared with MAC. MAB based organic light-emitting diode(OLED)exhibits a remarkable maximum external quantum efficiency(EQE) of 21.7%, which is much better than the maximum EQE of MAC-based OLED with a value of 12.8%. Our work proves that extending the distribution of LUMO is a simple but effective method to improve the efficiency of TADF emitter.