摘要：Much attention has been paid for the synthesis of dimethyl carbonate(DMC) by urea indirect alcoholysis method, which had not been actually industrialized by now. The rigorous full process model was then necessary to optimize the process with heat integration. In this paper, a full process was designed and optimized for the DMC synthesis by urea indirect alcoholysis method based on Aspen Plus *** technological analysis was developed to find how the process was influenced by the three main recycled materials of methanol, 1,2-propylene glycol(PG) and mixture of DMC–methanol. Simultaneously,the thermal optimization was taken into account for energy saving and the optimized process was proposed with heat integration. Moreover, the economic evaluation was implemented for the optimized process with total annualized cost(TAC) and cost of product(COP) according to the plant investment and operations. It was found that the 11.6% decrease in TAC was obtained for the optimized process compared to the original designed process. The COP analysis showed that the process was economically efficient for the production of DMC from urea and methanol.

摘要：Mg-8Sn-1Al-1Zn-xNi(x=0.5%, 1.0%, 1.5%, 2.0%, mass fraction) alloys were designed and prepared. The microstructures and the mechanical properties were studied by using optical microscope, scanning electronic microscope, energy dispersive X-ray spectroscope, X-ray diffraction and a standard universal testing machine. The results show that the microstructure of Ni-containing alloys consist of α-Mg, Mg2 Sn, β-Mg-Ni-Al and γ-AlNi phases. No β-Mg-Ni-Al phase was observed in TAZ811-2.0Ni alloy due to its 1:1 atomic ratio of Ni/Al. The addition of Ni refines the α-Mg dendrites and suppresses the formation of coarse Mg2 Sn phase. The tensile properties results show that the TAZ811-0.5Ni alloy presented the best mechanical properties, which is due to the rod-like β-Mg-Ni-Al phase, refined α-Mg dendrites and Mg2 Sn phase, as well as γ-AlNi phase. The tensile fracture mechanism transits from cleavage to quasi-cleavage fracture with the increasing Ni addition.

摘要：A rational integration of multiple reactive centers into a combined unit to facilitate their cooperative effects is a smart approach for accelerating the catalytic ***,to achieve this goal,linear imidazolium-based ionic polymers were confined into the nanopores of mesoporous silica nanospheres anchored with homogeneously distributed zinc *** to the flexible character and the reinforced cooperative effects of the ionic liquid(nucleophile)and zinc species(Lewis acid)in the confined mesoporous structure,the resultant composite exhibited dramatically improved catalytic performance in the cycloaddition of CO2 with epoxides to form cyclic *** was in contrast to that observed for the individual catalytic ***,such a solid catalyst could be easily recovered and reused four times without a significant loss of activity.

摘要：弹光调制干涉信号范围为百赫兹到数十吉赫兹之间,而由于探测器阵列无法对该等级频率实现有效响应,因此,该情况使弹光调制器在光谱成像工作中受到限制。为了解决该问题,发展了一种使用两块具有相近谐振频率的PEM,并基于该频率差进行光信号调制的方法。该方法将两个弹光调制器分别工作在数值略有差异的频率f_1和f_2上,被测光通过双弹光调制器实现差频调制,因此干涉信号中产生载有被测光的低频调制分量,低频调制频率是以δ_i(σ,t)=δ_(0i)(σ)sin(ωit)为基频的一系列倍频信号,该低频调制信号使用普通探测器即可实现探测,再将直流和高频信号滤波后,仅对调制信号后的低频成分进行对应的运算即可得到被测光谱。由于该频率差比所使用PEM的谐振频率低2至3个数量级,因此,该方法可使探测器获得更多的响应时间,而且由于该方法并不需要所使用的两块PEM具有严格一致的谐振频率和相同的光程差,降低了系统本身的设计难度。

摘要：A multi-parameter nonlinear elasto-plastic constitutive model which can fully capture the three typical features of stress-strain response, linearity, plasticity-like stress plateau and densification phases was developed. The functional expression of each parameter was determined using uniaxial compression tests for aluminum alloy foams. The parameters of the model can be systematically varied to describe the effect of relative density which may be responsible for the changes in yield stress and hardening-like or softening-like behavior at various strain rates. A comparison between model predictions and experimental results of the aluminum alloy foams was provided to validate the model. It was proved to be useful in the selection of the optimal-density and energy absorption foam for a specific application at impact events.

摘要：由可见光驱动的将CO_(2)转化为高附加值燃料是一种清洁可再生的技术,有助于控制全球变暖和应对能源短缺.近年来,二维的金属偶氮盐框架(2D MAFs)因其特定的电子传输路径、高度暴露的表面活性位点及可调节的吸光能力,在CO_(2)光还原研究中备受关注.然而,对其在该领域的研究仍处于初级阶段.本文设计了一种新型二维MAFs(compound 1),通过四-(4-四唑基苯基)乙烯(H;4;TTPE)与钴的自组装实现了对CO_(2)的光还原.作为对比,通过类似的合成过程构建了具有三维结构的compound 2.非均相光催化实验结果显示,2D compound 1的光还原性能明显优于3D compound 2,在相同条件下,其CO产率高达11.56 mmol g^(-1)h^(-1),是compound 2(1.94 mmol g^(-1)h^(-1))的6倍.这一性能优势源于compound 1独特的二维结构,其不仅具有有利于CO_(2)还原的能级,还能在整个CO_(2)光还原过程中促进电子-空穴高效分离.本工作为设计适用于高效CO_(2)光还原的2D MAFs光催化剂指引了方向.

摘要：Beam focusing is one of the unique characteristics of ultrasonic phased array compared with conventional *** the basis of two-dimensional radiated sound field of phased array,the three-dimensional radiated sound field was simulated in the paper,and then the effect of different frequencies,different number of array elements and different element spacings on focal spot,the depth of focus and the effect on horizontal and vertical resolution were *** optimal results of transducer parameters have certain reference value for the design of phased array probe.

摘要：Research of the acoustic local effect of metamaterial is widely used in the fields of environmental science,military industry and *** this paper,the metamaterial is designed by annular columnar *** acoustic local effect in slender columnar structure with two layers of rings in air is *** prove that when the plane acoustic wave is incident into the model,complex interference and diffraction *** at different frequencies,multipolar acoustic local effect existes and cycle distribution phenomenon is *** is noteworthy that this phenomenon has very weak relatedness with the materials and acoustic parameters of the *** research of this metamaterial design in this paper has definite reference significance in the acoustic communication and amplification of the acoustic signal detection.

摘要：The acoustic focusing effect of metamaterial has a wide range of applications in medicine,acoustic imaging,signal detection,*** paper presents an acoustic metamaterial applied to the acoustic focusing *** formation of acousticmetamaterial is designed into a cylindrical structure with three layers of ludox,cork and fluid rubber,which can produce a focusingphenomenon when acoustic waves propagate in *** these strange phenomena,a scientific description is given *** can also be concluded that when the frequency of the incident acoustic wave increases?the number of peripheral bandsoutside the focusing poles will increase ***,there are numerous groups of multipolar focusing phenomena inhigh *** design of this acoustic metamaterial is successful through theorietical and experimental verification,therefore,it can be applied to acoustic communication and test.

摘要：The optical fiber based on silicon materials has a smaller thermal expansion coefficient, therefore it can be used for the preparation of sensor devices which are insensitive to temperature but sensitive to refractive index, strain, stress, etc. For example, we can use optical fiber Fabry-Perot （F-P） sensor to achieve high sensitivity stress sensing. In this paper, we design an optical fiber F-P sensor with low cost and high sensitivity based on chemical etching method and analyze the stress sensing properties. Hydrofluoric acid is used to prepare the end face concave hole of the optical fiber first, and then the hollow struc-ture of the fiber F-P sensor is obtained by melting and discharge. This preparation method contributes greatly to enhancing the stress sensing properties and temperature insensitivity of the optical fiber device. The experimental results show that interference spectrum peak change is proportional to the stress change of optical fiber F-P sensor, stress sensitivity can reach 5. 2, and the cost is relatively low. Based on this,it has a certain application value in the stress sensing field.