摘要：硼氮多重共振(MR)发光材料在宽色域有机发光二极管(OLEDs)中具有重要应用前景,因此受到广泛关注.其中,间位双硼骨架凭借其高效率和极窄的发光光谱,在蓝光发光材料的构筑中已展现出独特优势,但如何基于间位双硼骨架构筑绿光窄光谱发光分子却鲜有报道.本论文基于萘环稠合策略设计并合成了绿光发光分子BN-NAP和BNANAP,其最大发射峰分别为511和518 nm,并保持了窄光谱发光性质,其发光半峰宽(FWHM)仅为26和20 nm.利用BN-ANAP作为发光材料制备得到纯绿光OLED器件,其CIE坐标为[026,067],最大外量子效率(EQEmax)为21.0%,同时具有较小的效率滚降.

摘要：Bioprinting has been widely investigated for tissue engineering and regenerative medicine ***,it is still difficult to reconstruct the complex native cell arrangement due to the limited printing resolution of conventional bioprinting techniques such as extrusion-and inkjet-based ***,an electrohydrodynamic(EHD)bioprinting strategy was reported for the precise deposition of well-organized cell-laden constructs with microscale filament size,whereas few studies have been devoted to developing bioinks that can be applied for EHD bioprinting and simultaneously support cell *** study describes functionalized alginate-based bioinks for microscale EHD bioprinting using peptide grafting and fibrin incorporation,which leads to high cell viability(>90%)and cell *** printed filaments can be further refined to as small as 30μm by incorporating polyoxyethylene and remained stable over one week when exposed to an aqueous *** utilizing the presented alginate-based bioinks,layer-specific cell alignment along the printing struts could be observed inside the EHD-printed microscale filaments,which allows fabricating living constructs with cell-scale filament resolution for guided cellular orientation.

摘要：In this article,three novel and simple molecular structure with donor-acceptor(D-A) type copolymers via only head-to-head alkoxy(OR) and/or alkylthio(SR) side chains onto the bithiophene(BT) as donor units and fluorinated benzotriazole(FBTA) as acceptor unit,namely,PBTOR-FBTA,PBTOSR-FBTA and PBTSRFBTA,were successfully designed and *** impacts of sulfur-oxygen(S…O) or sulfur-sulfur(S-S) noncovalent interactions on their physicochemical properties,molecular stacking,carrier mobility,morphologies of blend films,as well as their photovoltaic performance were deeply and systematically *** introduction of SR side-chains suddenly lowered the highest occupied molecular orbital(HOMO) energy levels,blue-shifted absorption,enhanced π-π stacking,as well as improved morphology of the photoactive layer blends in comparison with the re ference polymer without SR *** solar cells(PSCs) were fabricated to estimate their photovoltaic performance of the *** an optimized blend ratio of PBTSR-FBTA:PC71BM(1:0.8,w/w),the PBTSR-FBTAbased device exhibits a higher power conversion efficiency(PCE) of 6.25%,which is about 3.34 and 1.87 folds than that of the PBTOR-FBTA and PBTOSR-FBTA-based devices,*** research results demonstrate that the modification of the simple and low-cost SR side chains is an effective strategy to improve the photovoltaic performance of the polymers.

摘要：Due to their high capacity,the P2-type layered oxide cathodes containing oxygen redox reaction processes have attracted wide attention for sodium-ion ***,these materials usually exhibit poor electro-chemical properties,resulting from irreversible oxygen redox reactions and phase transition processes at high voltages,and thus hinder their large-scale *** work reveals the mechanism for the significantly improved cycle stability and rate performance of Co/Ni-free Na_(0.7)5Li_(0.25-2/3x)CuxMn_(0.75-1/3x)O_(2)via Cu ***-situ XPS demonstrates that Cu doping reduces the amount of Mn^(3+)that triggers the Jahn-Teller effect during the *** addition,the electron enrichment of oxygen around Cu can alleviate the irreversible oxidation of oxygen,and thus suppressing the phase transition originates from the rapid weakening of the electrostatic repulsion between ***,in-situ XRD results verify that the Na_(0.7)5Li_(0.19)Cu_(0.09)Mn_(0.7)2O_(2)maintains the P2 phase structure during charging and discharging,resulting in a near-zero strain characteristic of 1.9%.Therefore,the optimized cathode delivers a high reversible capacity of 194.9 mAh g−1 at 0.1 C and excellent capacity retention of 88.6%after 100 cycles at 5 *** full cell paired with commercial hard carbon anode delivers energy density of 240 Wh kg−*** research provides an idea for designing a new type of intercalated cathode for sodium-ion batteries with low cost and high energy density.

摘要：本文设计合成了两种具有不同连接方式(亚胺键和sp^(2)-C-CN键)的三嗪基共价有机框架(COFs)材料.连接单元的微小变化导致可见光驱动制氢性能的巨大差异.具有sp^(2)碳连接方式的全π共轭二维COFs在450 nm波长处表现出13.48%的外量子效率,优于已报道的COFs光催化剂.而亚胺键的二维COFs几乎没有光活性.借助光电化学研究和量子化学计算进一步研究了二维COFs的催化机理,为太阳能转化高性能有机光催化剂的制备提供了新的见解.

摘要：动态调控是现代光学器件中必不可少的特性,在激光雷达系统、显示器件以及数码相机等设备中具有重要意义.与传统的体光学器件相比,动态超表面为实现小型化和集成化智能光学系统提供了一个极具吸引力的解决方案.相变材料具有高的折射率对比度和易于操控的特性,是设计动态超表面的理想材料.本文通过操控氧化钒的相变,在近红外区域设计实现了可调谐的超构透镜和可切换图像编码的超表面器件.通过控制氧化钒的相变,能够改变超透镜的聚焦强度,实现强度对比约为12倍的开关聚焦效果.此外,利用氧化钒的相变还设计实现了任意两个不同数字图案的可切换成像.本工作为实现动态成像和光学加密系统的可调谐超表面奠定了基础.

摘要：Electrochemical oxidation of 5-hydroxymethylfurfural(HMF)has shown promising prospects in producing highly valuable ***,we report the synthesis of ultrasmall Ag nanoclusters anchored on NiColayered double hydroxide(NiCo-LDH)nanosheet arrays(Agn@NiCo-LDH)via a facile electrodeposition *** prepared Agn@NiCo-LDH nanosheet arrays exhibit excellent electrocatalytic HMF oxidation performance with a current density of 10 mA cm^(−2) at 1.29 VRHE and the Faraday efficiency of nearly 100%for 2,5-furandicarboxylic acid *** study offers an effective approach to rationally design nanoclusters to achieve high catalytic activity for sustainable energy conversion and production.

摘要：The kinetic competition between electron-hole recombination and water oxidation is a key limitation for the development of efficient solar water splitting materials. In this study, we present a solution for solving this challenge by constructing a quantum dot-intercalated nanostructure. For the first time, we show the interlayer charge of the intercalated nanostructure can significantly inhibit the electron-hole recombination in photocatalysis. For Bi2WO6 quantum dots （QDs） intercalated in a montmorillonite （MMT） nanostructure as an example, the average lifetime of the photogenerated charge carriers was increased from 3.06 μs to 18.8 Ds by constructing the intercalated nanostructure. The increased lifetime markedly improved the photocatalytic performance of Bi2WO6 both in solar water oxidation and environmental purification. This work not oMy provides a method to produce QD-intercalated ultrathin nanostructures but also a general route to design efficient semiconductor-based photoconversion materials for solar fuel generation and environmental purification.

摘要：在柔性设备和静态储能电网应用中,可充电水性锌离子电池展现出巨大的潜力.但其发展受到界面不稳定性引起的副反应及枝晶生长的阻碍.本研究中,我们采用了一种新颖的电解液设计,通过含大量孤电子对的亲锌葫芦[7]超分子来应对这一挑战.这些超分子因其独特的分子结构,能够在电化学循环中有效地吸纳和固定Zn离子,从而有效避免了Zn离子的无序迁移和枝晶的形成.超分子中丰富的孤对电子提供的Lewis碱性位点(如叔胺和羰基氧)作为Zn离子的供电子成核位点,促进了紧密成核.这些超分子与Zn离子之间的强烈相互作用,不仅提高了系统的稳定性,还显著抑制了不良副反应.因此,我们组装的对称电池和Zn//V_(2)O_(5)全电池均展示了长效的循环稳定性和卓越的库仑效率.

摘要：Short-range ordering(SRO)is one of the most important structural features of high entropy alloys(HEAs).However,the chemical and structural analyses of SROs are very difficult due to their small size,complexed compositions,and varied *** electron microscopy(TEM)as well as its aberration correction techniques are powerful for characterizing SROs in these compositionally complex *** this short communication,we summarized recent progresses regarding characterization of SROs using TEM in the field of *** using advanced TEM techniques,not only the existence of SROs was confirmed,but also the effect of SROs on the deformation mechanism was ***,the perspective related to application of TEM techniques in HEAs are also discussed.