摘要：In this paper,the MCI（multipath crossover interconnection）technique for octagon single and symmetrical spiral inductors has been presented to improve the quality *** metal wires of the single and symmetrical inductors formed by the top metal are divided into multiple segments according to the depth of the skin *** outermost path of the metal is crossover-interconnected to the innermost path by the underlayer metal and via The crossover technique makes the lengths of the total current paths between two ports approximately equal to each ***,the induced magnetic flux and resistance of each path can be balanced and the Q-factor of spiral inductors can be *** proposed MCI technique has been validated by the electromagnetic simulation with the 130-nm 1P6M SiGe BiCMOS *** the devices with occupying areas of 240 240 μm^2,results of electromagnetic simulation show that about 24%improvement in the Q-peak（3.3 GHz）of the MCI single inductor as compared to conventional single inductors（3.1 GHz）,and about 88.1%improvement in the Q-peak（3.2 GHz）of the MCI symmetrical inductor as compared to conventional symmetrical inductors（1.8 GHz）.

摘要：KTX（Keda Torus for eXperiment）is a new reversed field pinch *** KTX plasma control system（PCS）can provide real-time,stable,flexible plasma control which is designed by ASIPP（Institute of Plasma Physics,Chinese Academy of sciences）,based on the Linux cluster system and EPICS（Experimental Physics and Industrial Control System）framework,and developed from DIII-D（Doublet III-D）*** control of the equilibrium field in KTX uses a PID（Proportional-Integral-Derivative）feedback *** control of the gas injection is an open loop *** plasma control simulation system is one part of the plasma control system,which is used to test the plasma control algorithm if it is revised and *** KTX PCS has been successfully tested using HT-7（Hefei Torus 7）experiment data in simulation *** the next phase,an error field feedback control and KTX simulator will be added to the KTX PCS,and the KTX PCS will be applied in experiments in the future.

摘要：电子结构和电导率是析氧反应活性的重要描述符,它们可以通过掺杂来调节.鉴于金属掺杂通常会减少电催化剂的活性位点数量,本工作探究了阴离子掺杂对尖晶石钴酸锌(ZCO)电子结构及其析氧活性的影响.与三价钴为主的ZCO相比,用电负性较低的硫取代氧会提高低自旋态(t_(2g)-^(6)e_(g)^(1))二价钴的占比,其析氧活性要高于低自旋态的三价钴(t_(2g)-^(6)e_(g)^(0)).掺硫钴酸锌(ZCO-S)中钴离子和阴离子之间的电子密度的再分布导致了二价钴的增多,而且钴和硫离子间的强共价作用也会加速电荷迁移.ZCO-S在1.65伏(相对于可逆氢电极)下的比活性比原始ZCO高11倍.相反,掺入具有较高电负性和价态的氟(F)并不能有效地改善电子结构,最终导致材料析氧活性的降低.本工作建立了所掺阴离子的电负性与钴酸锌本征析氧活性之间的联系,并提供了一种通过掺杂不同电负性的阴离子来调控尖晶石氧化物的电子结构的简单有效的方法,这为合理设计高性能尖晶石电催化剂提供了新途径.

摘要：高活性MOF基催化剂的设计和合成为促进动力学不利的氧还原反应(ORR)过程开辟了新的途径.本研究通过在ZIF-8前驱体表面涂覆二茂铁甲酸,然后进行两步炭化工艺,设计和制备了一种具有新型结构的高效电催化剂,以提高ORR性能.两步炭化过程对于将热解Fe_(3)C纳米颗粒封装到碳纳米管(CNTs)中以及将Fe单原子隔离到N掺杂碳(NC)基体上至关重要.此外,Fe元素的相对含量对优化催化剂的ORR性能至关重要.所制得Fe_(3)C@CNTs/NC-M催化剂结构先进,在碱性溶液中表现出良好的长期稳定性和电催化ORR性能,其半波电位和极限电流分别达到0.941 V和6.31 mA cm^(-2).此外,该电催化剂在甲醇溶液中具有较强的耐受性和良好的稳定性.Fe_(3)C@CNTs/NC-M锌空气电池(ZAB)具有1.525 V的开路电位,420 mA cm^(-2)时的峰值功率密度为348 mW cm^(-2),10 mA cm^(-2)时的最大容量为843 mA h g_(Zn)^(-1).因此,这种合成策略为构建具有有效和稳定的ORR性能的MOF基电催化材料提供了一条有效途径.

摘要：Supports are commonly implemented in the industrial application of heterogeneous catalysts to improve the stability and recyclability of *** supported catalysts often show the enhanced activity and selectivity in various catalytic ***,the specific contributions of electronic and steric effects to a catalytic system often remain elusive due to the lack of well-defined model *** this work,two types of uniform Pd nanocrystals covered by{111}facets in tetrahedral and octahedral shapes,respectively,are synthesized with identical chemical environment and loaded on Ti O_2supports to form hybrid structures(Pd{111}-Ti O_2)towards the application of formic acid *** observation suggests that the polarization effect at the interface of Pd-Ti O_2enhances its activity in formic acid ***,the Pd tetrahedrons-Ti O_2hybrid structure whose Pd{111}-Ti O_2interface possesses a larger angle shows higher catalytic activity,owing to the reduced steric effect as compared to Pd octahedrons-Ti O_*** study reveals the nature of interface effects in formic acid decomposition,and provides a guidance for the related catalyst design.

摘要：In this paper, we construct a composite Milstein method for nonlinear stochastic differential delay equations. Then we analyze the mean square stability for this method and obtain the step size condition under which the composite Milstein method is mean square stable. Moreover, we get the step size condition under which the composite Milstein method is global mean square stable. A nonlinear test stochastic differential delay equation is given for numerical tests. The results of numerical tests verify the theoretical results proposed.

摘要：Herein,we report a three-dimensional porous TiO_(2)/Fe_(2)TiO_(5)/Fe_(2)O_(3)(TFF)inverse opal through in situ thermal solid reactions for photoelectrochemical water *** Fe_(2)TiO_(5) interfacial layer within TFF acting as a bridge to tightly connect to TiO_(2) and Fe_(2)O_(3) reduces the interfacial charge transfer resistance,and suppresses the bulk carrier *** optimized TFF displays a remarkable photocurrent density of 0.54mAcm^(-2) at 1.23V *** hydrogen electrode(RHE),which is 25 times higher than that of TiO_(2)/Fe_(2)O_(3)(TF)inverse opal(0.02mAcm^(-2) at 1.23V ***).The charge transfer rate in TFF inverse opal is 2-8 times higher than that of TF in the potential range of 0.7-1.5V *** effects of the Fe_(2)TiO_(5) interfacial layer are further revealed by X-ray absorption spectroscopy and intensity-modulated photocurrent *** work offers an interfacial engineering protocol to improve charge separation and transfer for efficient solar water splitting.

摘要：In this study,diodo boron dipyrromethene(BODIPY)is employed a8 the energy donor and 3,4,9,10-perylene tetracarboxylic dianhydride(PDA)as the energy acceptor,enabling the synthesis of two new compounds:a BODIPY-perylene dyad named P1,and a triad named *** investigate the impact of the energy donor on the photophysical processes of the system,P1 comprises one diodo-BODIPY unit and one PDA unit,whereas P2 contains two diodo-BODIPY moieties and one PDA *** to the good spectral complementarity between diiodo-BODIPY and PDA,these two compounds exhibit excellent light-harvesting capabilities in the 400-620 nm ***-state fluorescence spectra demonstrate that when preferentially exciting the diodo-BODIPY moiety,it can effectively transfer energy to PDA;when selectively exciting the PDA moiety,quenching of PDA fluorescence is observed in both P1 and *** transient absorption results show that both compounds can efficiently generate triplet excited states,which are located on the PDA *** lifetimes of the triplet states for these two compounds are 103 and 89μs,respectively,significantly longer than that of *** results from the photooxidation experiments reveal that both P1 and P2 demonstrate good photostability and photooxidation capabilities,with P2 showing superior photooxidative *** photooxidation rate constant for P2 is 1.3 times that of P1,and its singlet oxygen quantum yield is 1.6 times that of *** results obtained here offer valuable insights for designing new photosensitizers.

摘要：A novel polysaccharide-bonded abrasive tool is proposed for the green machining of single-crystal *** prescription and manufacturing process of the proposed tool is designed,and the gelation property of polysaccharide by microwave treatment is *** tool samples are fabricated,and a machining experiment on a single-crystal sapphire is *** is found that the crystallinity of polysaccharide gel decreases as the proportion of cross-linked polysaccharide *** tool samples with cross-linked polysaccharide present higher surface *** the new abrasive tool,the surface quality of sapphire wafer can be significantly *** new tool with an abrasive to binder ratio of 2∶1 attains a material removal rate of 0.68μm/*** is found that increasing the abrasive to binder ratio leads to better self-dressing performance but worse material removal ability and greater loss of abrasive tool *** validity of polysaccharide as an abrasive tool binder is preliminarily verified.

摘要：Rational designs of electrocatalytic active sites and architectures are of great importance to develop cost-efficient non-noble metal electrocatalysts towards efficient oxygen reduction reaction(ORR)for high-performance energy conversion and storage *** this work,active amorphous Fe-based nanoclusters(Fe NC)are elaborately embedded at the inner surface of balloonlike N-doped hollow carbon(Fe NC/Csphere)as an efficient ORR electrocatalyst with an ultrathin wall of about 10 *** evaluated for electrochemical performance,Fe NC/Csphere exhibits decent ORR activity with a diffusionlimited current density of~5.0 mA/cm^(2)and a half-wave potential of~0.81 V in alkaline solution,which is comparable with commercial Pt/C and superior to Fe nanoparticles supported on carbon sheet(Fe NP/C sheet)*** electrochemical analyses combined with electronic structure characterizations reveal that robust Fe-N interactions in amorphous Fe nanoclusters are helpful for the adsorption of surface oxygen-relative species,and the strong support effect of N-doped hollow carbon is benefitial for accelerating the interfacial electron transfer,which jointly contributes to improve ORR kinetics for Fe NC/Csphere.