摘要：*** is an important phenomenon in nature and is involvedin all areas of the chemical *** andheterogeneous catalysis are key techniques in chemical *** development of efficient,stable,and environmentallyfriendly catalytic methods is receiving much attentionbecause of the increasing global shortage of energy and seriousenvironmental damage.A number of efforts have been made inthe past for designing rationally catalysts to achieve desirablecatalytic activities,selectivities,and stabilities for specific reactions[1].The current energy crisis is affecting economies inevery region,particularly in fossil‐oil‐consuming countries,because of rapidly decreasing available stocks,therefore biomassconversion to fuels and chemicals using various approaches,including thermal,biological,and chemocatalyticprocesses,is attracting great attention worldwide[2].

摘要：一维二氧化锆纳米纤维(ZrO_(2)NFs)作为一种重要的无机材料,以其独特的结构特性、优异的化学/热稳定性,以及杰出的光学/电子性能而备受关注.生物模板法、相转化法、离心纺丝法和静电纺丝法是合成ZrO_(2)NFs的简便且高度通用的方法,在隔热、空气过滤、水净化、催化剂载体、染料敏化电池和锂离子电池等新兴应用领域具有巨大的潜力.本文对多孔、中空、层状、甚至三维自组装等多种结构的ZrO_(2)NFs的合成策略进行了详细的描述和分析.此外,本文还讨论了近年来打破陶瓷脆性、构建柔性ZrO_(2)NFs的革命性进展及其变形机制.接着介绍了ZrO_(2)NFs在隔热、环境修复、催化、电池等领域的应用成果.最后,我们提供了关于ZrO_(2)NFs的全面总结、关键挑战和未来展望.本文对未来新型ZrO_(2)NFs的研究具有一定的指导意义.

摘要：1. Introduction Hydrogenation is one of the most important reactions in the chemical and petroleum refining industries. Since Sabatier [1] first studied the hydrogenation of unsaturated organic compounds in the presence of nickel in 1897, different catalysts have been tested for the hydrogenation of a wide range of substances to produce useful chemicals or intermediates. Compared with homogeneous catalysts, heterogeneous catalysts have attracted greater attention due to their easier separation and better handling properties [2]. Among the various heterogeneous catalysts, metal-supported catalysts are widely used in various hydrogenation reactions. Particularly, metal oxides are generally used as supports in consecutive hydrogenation reactions due to their high mechanical strength, whereas carbon supports are often utilized to produce fine medicals owing to their large surface area and acid-alkali resistance.

摘要：Dynamically crosslinked materials generally lose their self-healing ability and mechanical robustness in aqueous,acidic,and basic environments due to disruption of their dynamic interactions and ***,a micelle-like structure with a hydrophobic outer layer is used to protect ionic *** structure ensures the self-healing and long-term stability of the ionically crosslinked elastomers in aqueous,acidic,and basic *** elastomer possesses a tensile strength of 6.7 MPa and a strain at break of 1400%,which is superior to the existing waterproof selfhealing *** strain sensors and dielectric actuators based on the elastomer are highly stable and self-healable,even in extremely harsh *** design strategy of hydrophobic protection for dynamic interactions is quite general,allowing it to be extended to other self-healing materials.

摘要：Pressing need goes ahead for accessing freshwater in insufficient supply countries and regions,which will become a restrictive factor for human development and *** recent years,solar-driven water evaporation(SDWE)systems have attracted increasing attention for their specialty in no consume conventional energy,pollution-free,and the high purity of fresh *** particular,carbon-based photothermal conversion materials are preferred light-absorbing material for SDWE systems because of their wide range of spectrum absorption and high photothermal conversion efficiency based on superconjugate *** now,many carbon-based SDWE systems have been reported,and various structures emerged and were designed to enhance light absorption,optimize heat management,and improve the efficient water transport *** this review,we attempt to give a comprehensive summary and discussions of structure progress of the carbon-based SDWE systems and their working mechanisms,including carbon nanoparticles systems,single-layer photothermal membrane systems,bi-layer structural photothermal systems,porous carbon-based materials systems,and three dimensional(3D)*** these systems,the latest 3D systems can expand the light path by allowing light to be reflected multiple times in the microcavity to increase the light absorption rate,and its large heat exchange area can prompt more water to evaporate,which makes them the promising application *** hope our review can spark the probing of underlying principles and inspiring design strategies of these carbonbased SDWE systems,and further guide device optimizations,eventually promoting in extensive practical applications in the future.

摘要：The multi-pass scheduling method is a key issue in die-less spinning for determining the quality of the final products, including their shape deviations and wall thicknesses, and has drawn increasing interest in recent studies devoted to trying to improve the accuracy of the formed parts. In this paper, two main parameters, roller path profiles and deformation allocations in each pass, are considered in newly proposed multi-pass scheduling and optimizing methods in die-less spinning. Four processing methods with different roller path profiles and with three deformation allocation methods are proposed for investigating the influence of scheduling parameters on product qualities. The ＇similar geometry principle for restraining shape deviation＇ and the ＇small curvature principle for maintaining wall thickness＇ are presented for optimal design of roller path profiles; in addition, the ＇uniform allocation principle for maintaining wall thickness＇ and the ＇large deformation principle for restraining shape deviation＇ are brought forward as suggestions for deformation allocations. Based on these principles, a scheduling method denoted by RF＋（FP ＆ EHS） is presented to improve the comprehensive quality of a product of die-less spinning.

摘要：Reactive distillation and dividing wall column distillation are two kinds of effective separation technologies,and their integrated configuration,reactive dividing wall column(RDWC),presents attractive *** this study,the rigorous simulation of RDWC for methyl acetate hydrolysis is performed,and sensitivity analysis is conducted to obtain the minimum reboiler *** a comparison is made between the conventional process and RDWC process,and it shows that 20.1% energy savings can be achieved by RDWC *** addition,the dynamic characteristic of RDWC is studied and an effective control strategy is *** simple PI control scheme with three temperature loops can obtain reasonable control performance and maintain products at desired *** is proved that this RDWC process is an energy efficiency alternative with good controllability.

摘要：The one-pot assembly reaction of a trilacunary,lone-pair-containing[B-α-SbW9O33]*** with Co2+ions in an aqueous medium led to the isolation of a novel{SbO3(H2O)3}bridging,dicobalt-substituted,sandwich-type tungstoantimonate{Co2Sb2(H2O)10[B-β-SbW9O33]2}^4–(1a).This compound was structurally characterized in the solid state by single-crystal X-ray diffraction,elemental analyses,thermogravimetric analysis,and IR *** most remarkable feature was that 1a comprises two trilacunary[B-β-SbW9O33]9^-fragments trapping a novel,centrally symmetric,rhomb-like{Co2Sb2}belt with 10 terminal water *** combined with the photosensitizer[Ru(bpy)3]^2+and the sacrificial electron acceptor S2O82.,1a exhibited efficient catalytic activity for water oxidation with a remarkable turnover number(TON)of 193,initial turnover frequency(TOFinitial)of 5.3 s^-1,O2 yield of 30.8%,and quantum yield(ФQY)of 36.2%under light-driven conditions.

摘要：This paper investigates the problem of global disturbance rejection for a class of switched nonlinear systems where the solvability of the disturbance rejection problem for subsystems is not assumed. The disturbances are assumed to be sinusoidal with completely unknown frequencies, phases and amplitudes. First, as an extension of the classic concept of internal model for non-switched systems, a switched internal model is proposed. Second, in order to solve the problem under study, an adaptive control method is established on the basis of the multiple Lyapunov functions method. Also,adaptive state-feedback controllers of subsystems are designed and incorporated with a switching law to asymptotically reject the unknown disturbances. Finally, an example is provided to demonstrate the effectiveness of the proposed design method.

摘要：A facile strategy was designed for the fabrication of Fe3O4-nanoparticle- decorated TiO2 nanofiber hierarchical heterostructures （FTHs） by combining the versatility of the electrospinning technique and the hydrothermal growth method. The hierarchical architecture of Fe3O4 nanoparticles decorated on TiO2 nanofibers enables the successful integration of the binary composite into batteries to address structural stability and low capacity. In the resulting unique architecture of FTHs, the 1D heterostructures relieve the strain caused by severe volume changes of Fe3O4 during numerous charge-discharge cycles, and thus suppress the degradation of the electrode material. As a result, FTHs show excellent performance including higher reversible capacity, excellent cycle life, and good rate performance over a wide temperature range owing to the synergistic effect of the binary composition of TiO2 and Fe304 and the unique features of the hierarchical nanofibers.