摘要：Wearable bioelectronic devices have the capacity for real-time human health monitoring,the provision of tailored services,and natural interaction with smart ***,these wearable bioelectronic devices rely on conventional rigid batteries that are frequently charged or replaced and are incompatible with the skin,leading to a discontinuity in complex therapeutic tasks related to human health monitoring and human-machine *** triboelectric nanogenerator(TENG)is a high-efficiency energy harvesting technology that converts mechanical into electrical energy,effectively powering wearable bioelectronic *** study comprehensively overviews recent advances in stretchable TENG for use in wearable bioelectronic *** working mechanism of stretchable TENG is initially explained.A comprehensive discussion presents the approaches for fabricating stretchable TENG,including the design of stretchable structures and the selection of stretchable ***,applications of wearable bioelectronic devices based on stretchable TENG in human health monitoring(body movements,pulse,and respiration)and human-machine interaction(touch panels,machine control,and virtual reality)are ***,the challenges and developmental trends regarding wearable bioelectronic devices based on stretchable TENG are elaborated.

摘要：由于银硫簇的不稳定性和有限的刺激响应特性,构建新型的具有光开关性质的银-硫簇基金属有机框架(SCC-MOF)面临着重大挑战.基于此,本文设计并合成了一种新型光致变色的SCC-MOF(Ag_(12)-BMPTC),该材料利用二芳基乙烯配体和银硫簇前驱体通过溶剂缓慢挥发而得到.Ag_(12)-BMPTC在365和500 nm光照射下表现出优异的可逆光响应特性.此外,这种光开关性质为其在信息加密和手性开关方面提供了潜在应用.本研究不仅扩大了SCC-MOF的种类,而且为设计和合成新型光致变色材料提供了新的思路和潜在应用.

摘要：带隙可调的钙钛矿材料在室内光伏(IPVs)领域具有广阔的应用前景.然而,与室内光相匹配的宽带隙钙钛矿通常导电性较差,缺陷密度较高,往往不利于电荷提取和传输,限制了其光伏特性.在这里,我们通过调节Br/I比,探究了不同带隙三阳离子钙钛矿的IPVs特性.研究表明,宽带隙钙钛矿能充分利用室内光,在低照度下能获得较高的开路电压,但高Br/I比的钙钛矿具有较高的缺陷密度,不利于获得高短路电流密度和填充因子.通过进一步研究不同带隙钙钛矿的结晶动力学、缺陷密度和电荷传输特性,我们发现主流观念中高效IPVs着重考虑室内光伏材料的带隙是不全面的,我们证明了通过适当降低宽带隙晶体中的Br含量可以获得室内光伏特性更优异的器件.也就是说,室内光伏晶体材料的制备需要兼顾带隙和电荷传输特性.在此工作中,平衡带隙和电荷传输的器件(Br 0.23,1.62 eV)在1035 lux的LED灯照射下取得了40.71%的最佳效率.我们的研究为高效室内光伏的设计提供了新思路.

摘要：连翘作为传统中药,具有显著的抗病毒作用,尤其是在治疗新冠肺炎方面。然而,其抗病毒有效化合物及其靶点尚不清楚。本论文利用网络药理学技术筛选连翘中的抗病毒成分和靶标,并利用分子对接技术分析了它们之间的相互作用。最终,从连翘中筛选出11个活性化合物(1–11)和7个抗病毒靶标(AKT1、TP53、MYC、PTEN、CASP8、MMP9和VEGFA),并利用基因本体论分析预测了潜在靶标可能的生物信号通路。基于分子对接结果,我们讨论了活性化合物的构效关系。此外,对活性化合物的吸收、分布、代谢、排泄和毒性(ADMET)特性进行了预测和分析。本研究阐明了连翘多个靶点和途径在治疗病毒性疾病中的协同作用,以及活性化合物的可药用性。本研究为开发和设计新型抗病毒药物提供了依据。

摘要：Geographic Hypermedia(GH)is a rich and interactive map document with geo-tagged graphics,sound and video ele-ments.A Geographic Hypermedia System(GHS)is designed to manage,query,display and explore GH *** emerging geo-tagged videos and measurable images as valuable geographic data resources,this paper aims to design a web-based GHS using web mapping,geoprocessing,video streaming and XMLHTTP *** concept,data model,system design and implementation of this GHS are discussed in ***-tagged videos are modeled as temporal,spatial and metadata entities such as video clip,video path and frame-based ***,geo-tagged stereo video and derived data are modeled as interre-lated entities:original video,rectified video,stereo video,video path,frame-based description and measurable image(rectified and disparity image with baseline,interior and exterior parameters).The entity data are organized into video files,GIS layers with linear referencing and XML documents for web *** data can be integrated in HTML pages or used as Rich Internet Appli-cations(RIA)using standard web technologies such as the AJAX,*** and RIA *** SOA-based GHS is designed using four types of web services:ArcGIS Server 9.3 web mapping and geoprocessing services,Flash FMS 3.0 video streaming ser-vices and GeoRSS XMLHTTP *** applications in road facility management and campus hypermapping indicate that the GH data models and technical solutions introduced in this paper are useful and flexible enough for wider deployment as a GHS.

摘要：基于双边市场理论模型和博弈分析方法,分析了垄断、竞争2种环境下广告定向契合度和消费者隐私信息保护对媒体平台价格策略、均衡利润和广告商广告策略的影响,以期为媒体平台和广告运营商做出正确的管理决策提供理论参考.研究结果表明,垄断环境下,媒体平台的均衡广告价格不依赖于广告定向契合度和消费者隐私信息保护程度.竞争环境下,当广告商单归属时,随着自身广告定向契合度和竞争对手广告定向契合度的增强,媒体平台的均衡广告价格和均衡利润将降低,消费者隐私信息保护程度对媒体平台均衡广告量的影响取决于媒体平台自身广告定向契合度与竞争对手广告定向契合度的对比;当广告商多归属时,媒体平台的均衡广告价格、均衡广告量、均衡利润与自身广告定向契合度呈正相关关系,与竞争对手的广告定向契合度呈负相关关系.媒体平台在参与市场竞争过程中,应综合考虑其广告定向契合度等因素,在其成长的不同时期,审慎制定价格策略.

摘要：A hierarchical microporous-mesoporous metal-organic framework of HKUST-l（Cu）-encapsulated phosphotungstic acid （HPW） material, referred to as HPWs@Meso-HKUST-1, is prepared by a one-pot synthesis method using cetyltrimethylammonium bromide as the supramolecular template. The addition of HPWs to the synthesis mixture of hierarchical porous HKUST-1 results in the direct encapsulation of HPWs inside the mesopores of the HKUST-1 structure, with a homogeneous distribution over the HKUST-1 crystals, which is confirmed by XRD, FT-IR, N2 adsorption, UV-Vis DRS, and TEM. FT-IR-CO adsorption experiments indicated that additional Lewis acid sites were present in the HPWs@Meso-HKUST-1 sample. The novel heterogeneous catalyst demonstrates excellent catalytic performance for the selective oxidation of cyclopentene （CPE） to glutaraldehyde CGA） using tert-butyl hydroperoxide and acetonitrile （MeCN） as the oxidant and solvent, respectively. The high activity of the catalyst is attributed to the mesostructure of the catalyst and the nature and appropriate abundance of the HPWs--being highly dispersed with the addition of Lewis sites. After a reaction for 36 h, the 30% wt% HPWs@Meso-HKUST-1 catalyst exhibits a CPE conversion of 92.5% and a high GA yield of 73%. Furthermore, the HPWs@Meso-HKUST-1 material is sufficiently stable to prevent the leaching of HPWs, and behaves as a true heterogeneous catalyst that can be repeatedly recycled without sustaining a loss of activity and selectivity in the selective oxidation of CPE.

摘要：High-temperature proton exchange membrane(HT-PEM)fuel cells offer more advantages than low-temperature PEM fuel *** ideal characteristics of HT-PEMs are high conductivities,low-humidity operation conditions,adequate mechanical properties,and competitive *** molecular moieties,such as benzimidazole,benzothiazole,imide,and ether ether ketone,have been introduced to polymer chain backbones to satisfy the application requirements for *** most common sulfonated polymers based on the main chain backbones have been employed to improve the *** group/chain engineering,including the introduction of SO_(3)^(-) on the side chain,grafting,branching,and crosslinking,has been widely applied to HTPEMs to further improve their proton conductivity,thermal stability,and mechanical ***,phosphoric acid-doped polybenzimidazole is the most successful polymer material for application in *** compositing/blending modification methods of polymers are effective in obtaining high PA-doping levels and superior mechanical *** this review,the current progress of various membrane materials used for HT-PEMs is *** synthesis and performance characteristics of polymers containing specific moieties in the chain backbones applied to HT-PEMs are discussed *** modification approaches and their deficiencies associated with HT-PEMs are analyzed and *** and future challenges are also presented.

摘要：The third-order nonlinear optical(NLO)materials with stimuli-responsive properties have received extraordinary attention due to their controllable photophysical *** this work,two attractive metal complexes third-order NLO switches,which are far superior to congeneric optical switches in terms of their performance conversion,versatility,and fast response,were successfully designed and *** test of their third-order NLO properties proves that the metal complexes exhibit reverse saturable absorption and self-defocusing *** light irradiation,the third-order NLO behavior turns quickly into self-focusing *** relation between the molecular structures and the third-order NLO properties was investigated via1H nuclear magnetic resonance and ultraviolet-visible *** results show that the metal ions have a significant influence on the NLO behavior and reveal the origin of third-order NLO properties via Z-scan determinations,pump-probe technology,and density functional theory *** metal complexes can be used as third-order NLO switches with excellent fatigue resistance and broaden the application range of third-order NLO materials with adjustable performances.

摘要：本研究设计了一种后功能化工艺方法修饰类石墨相氮化炭材料。通过此工艺成功得到了硼掺杂的介孔氮化炭材料,该材料比表面积高达125 m^(2)/g,这为提升光催化分解水性能奠定了基础。利用X射线衍射、X射线光电子能谱,荧光光谱和紫外-可见光谱对材料进行了全面的表征。基于X射线光电子能谱分析,发现通过后功能化处理硼原子成功掺杂进入氮化炭的晶格中;通过吸收光谱分析得知,硼掺杂的介孔氮化炭材料增强了在可见光区的光吸收;通过荧光光谱分析得知,相比原始氮化炭材料,硼掺杂后的介孔氮化炭材料有着更低的荧光强度,意味着光生电子和空穴的分离得到了提升。对材料进行光催化分解水测试,后功能化处理得到的硼掺杂介孔氮化炭材料的产氢速率是原始氮化炭材料的10.2倍。此结论对后续利用后功能化工艺修饰材料提升材料性能具有一定的借鉴意义。