摘要：Fast electron-hole recombination issues during titanium dioxide(TiO_(2))photocatalysis limit its application in preventing bacterial infection during bone defect *** this study,TiO_(2)@reduced graphene oxide(rGO)composites were synthesized using a hydrothermal method in which rGO,which possesses very high electrical conductivity,promotes the separation of photoelectron-hole pairs of TiO_(2),thus improving the efficiency of photocatalytic production of reactive oxygen species(ROS).Subsequently,TiO_(2)@rGO composites were introduced into poly-L-lactic acid(PLLA)to prepare bone scaffolds with photocatalytic antibacterial function via selective laser *** results showed that TiO_(2)grew on the surface of rGO and formed a covalent bond connection(Ti-O-C)with rGO.A decreased electrochemical impedance of TiO_(2)@rGO composites was observed,and the transient photocurrent intensity increased from 0.05 to 0.5μA/cm^(2).Analysis of electron spin resonance found that the photocatalytic products of TiO_(2)were·OH and·O^(2-),two kinds of ROS capable of killing bacteria via disrupting the structure of the bacterial membrane in *** experiments showed that the PLLA/TiO_(2)@rGO scaffolds had good antibacterial properties against Escherichia coli and Staphylococcus ***,we report that these scaffolds exhibited both enhanced mechanical properties due to the addition of TiO_(2)@rGO as a reinforcement material and good biocompatibility during cell proliferation.

摘要：Homogeneous redox mediation is efficient in alleviating the shuttling effect and slow redox kinetics of lithium polysulfides in lithium-sulfur ***,their perfect performance is not fulfilled owning to the fact that the multi-step transformation of lithium polysulfides requests the multifunctional active positions for the tandem *** on the redox comediation principles,a promoter of mixing organodiselenide and organoditelluride(mixed-Se/Te)was raised to induce tandem catalysis and boost the effective electrochemical conversion of lithium *** specifically,diphenyl diselenide facilitated the liquid-liquid and solid-liquid transformation between lithium polysulfides and sulfur,while diphenyl ditelluride improved the solid-liquid transformation concerning lithium sulfide ***,even under high sulfur loading of 6.5 mg cm^(−2) and low electrolyte/sulfur ratio of 5.88μL mg^(−1),the 10 mM low concentration mixed-Se/Te promoter offered a high discharge capacity of 6.6 mAh cm^(−2) and high rate performance of 4.1 mAh cm^(−2) at 0.5 ***,the assembled 1.5 Ah-level lithium-sulfur pouch cells provide an energy density of 332 Wh kg^(−1) at 0.05 C and good cycling *** research demonstrates the applicability of propelling continuous sulfur conversion reactions with detached active positions and is anticipated to stimulate deep molecular design of kinetic promoter to targeted energy-associated redox reactions.

摘要：Evapotranspiration(ET)is of great significance for the ecological environment and water resource utilization in arid and semi-arid *** Mongolian Plateau,owing to drought,low rainfall,and extremely uneven distribution of water resources,has a typical temperate continental climate.A refined understanding of the spatiotemporal distribution of ET in this region will help in establishing regulatory strategies for climate change responses,regional livestock regulation,and grassland degradation *** this study,meteorological station data,precipitation data,and the Penman-Monteith model were used to study the temporal and spatial distribution characteristics of actual ET over the Mongolian Plateau from 2011 to *** found that:(1)The spatial distribution of ET in the Mongolian Plateau showed a high trend in the north and east and a low trend in the middle and *** was a significant difference in the regional annual ET,with the highest ET reaching over 500 mm and the lowest being only approximately 70 mm.(2)The annual ET values in 2013,2018,and 2019 were relatively large,varying between 80 and 500 mm,and the overall ET of the Mongolian Plateau first decreased,then increased,and then decreased.(3)The temporal distribution exhibits a unimodal trend of increasing and then decreasing,with July being the turning ***-September was a period of high ET,with the highest ET exceeding 100 *** vegetation coverage was high,precipitation was abundant,and the vegetation ET effect was *** was a period of low ET,with a maximum ET of approximately 10 mm in January and December;the ET for the month with the lowest value was approximately *** quantitative inversion method proposed in this study can provide method and data support for north and central Asia,and other large arid and semi-arid areas.

摘要：Accurate detection of multiple small end-metabolic biomarkers is more sensitive than large biomoleculesto provide real-time feedbacks of physiological/pathologicalstate, but is more challenging due to lack of specific identifyinggroups. Current optical platforms suffer from unsatisfactoryresolutions to differentiate each target because they producesimilar output to different targets using a single excitation,and inevitably involve non-functional components that increase chances of interacting with non-target ***, by taking full advantage of each building unit’sfunctionality to integrate multivariate recognition elements inone interface, a dual-excitation-driven full-component-responsive metal-organic framework (MOF)-based luminescentprobe, namely CeTMA-TMA-Eu, is successfully custom-tailored for detecting both pseudouridine (Ψ) and N-acetylaspartate (NAA), the diagnostic hallmarks of cancer andneurodegenerative disorder. Remarkably, Ψ interacts withMOF’s organic building unit (trimesic acid, TMA) and filtersout its absorptions of 262 nm-light to reduce its energytransferred to Eu^(3+), while NAA induces the valence transitionof Ce^(4+)/Ce^(3+) nodes to improve the cooperative energy transferefficacy from TMA and Ce^(3+) to Eu^(3+). As a result, this platformexhibits completely reverse photoresponses towards Ψ(“switch-off” at 262 nm excitation) and NAA (“switch-on”upon 296 nm excitation), and demonstrates excellent selectivity and sensitivity in complex biofluids, with low detection limits of 0.16 and 0.15 μM, and wide linear ranges of0–180 and 0–100 μM, respectively. Such full-componentresponsive probe with dual-excitation-mediated reverse responses for multi-small targets intrinsically minimizes its interaction with non-target molecules and amplifies resolutionto discriminate each target, providing a new strategy for improving assay accuracy of multi-small biomarkers in diagnostics.

摘要：Dermal substitutes have provided a template for the regeneration and reconstruction of the ***,the healed skin tissue often exhibits abnormal morphology and functionality,including scarring and *** this study,a composite bioink composed of methacrylated gelatin(GelMA)and chitosan oligosaccharide(COS)was proposed for printing a dermal scaffold using digital light processing(DLP)*** GelMA/COS bioink exhibited suitable porosity,swelling,degradation rate,and mechanical *** inclusion of COS demonstrated antibacterial effects against both Gram positive and Gram-negative bacteria,while simultaneously fostering the proliferation of human dermal fibroblasts(HDFs).Additionally,the application of COS could effectively reduce the expression levels of fibrosis-related genes,such as collagen I,collagen III,and fibronectin *** three-dimensionally printed cell-laden dermal scaffold exhibited excellent shape fidelity and high cellular viability,facilitating the extension of HDFs along the scaffold and the simultaneous secretion of extracellular matrix ***,the HDF-laden dermal scaffold transplanted into full-thickness skin defect sites in nude mice was shown to accelerate wound closure,reduce inflammation,and improve wound ***,the DLP-printed dermal scaffold provides an appealing approach for effectively treating full-thickness skin defects in clinical settings.

摘要：The low temperature,high salt content,and bacterial composition of a seawater environment can induce severe infections in open wounds,thus impeding wound *** date,numerous wound dressings have been developed for injuries and various antibacterial ***,ordinary antibacterial strategies could not provide long-term resistance to infections and could not promote wound ***,we proposed a strategy for enhancing resistance to seawater immersion wound infection by killing bacteria and delivering bacterial antigens in ***,MXene-embedded tannin-Eu^(3+)(M@TA-Eu)particles were constructed to effectively alleviate injuries infected through seawater immersion and persistently fight infection by forming in situ bacterial vaccines and immune *** the particle,the platform composed of TA and Eu3+exhibited provascularization and antigen presentation *** with near-infrared photothermal effect were introduced to kill the bacteria,promote the recruitment of antigen presentation cells,and ultimately enhance vaccination *** results showed that the particles not only effectively accelerated the healing of injuries by relieving wound inflammation and inhibiting bacteria but also produced a potent vaccination by forming in situ bacterial ***,the M@TA-Eu particles are novel materials for high-grade anti-infection dressing.

摘要：The A–D–A′–D–A-type non-fused ring electron acceptors(NFREAs),consisting of electron-donating unit(D)as the bridge to link electron-accepting units(A and A′),have emerged as promising electron acceptors for organic solar cells(OSCs)and organic photodetectors(OPDs).As the units are linked by the carbon–carbon single bonds,these electron acceptors generally possess feasible synthesis and tunable optoelectronic ***,the recent progress of A–D–A′–D–A-type NFREAs is reviewed,including molecular design,device performance,structure–property relationships,and their applications in OSCs and ***,we discuss the challenges and propose the perspectives for the further development of A–D–A′–D–A-type NFREAs.

摘要：加载控制方式是影响岩石力学性质重要因素之一。采用轴向变形控制和环向变形控制两种加载方式，对花岗岩试样开展变形速率为0.005·s-1条件下的单轴压缩试验，分析两种加载控制方式对花岗岩强度、应力及应变门槛值、能量演化及声发射特性等的影响规律。结果表明，与环向变形控制方式相比，轴向变形控制加载条件下：试样的峰值强度、损伤应力、起裂应力分别高12.8%、15.1%、13.1%；峰值轴向应变、损伤轴向应变及起裂轴向应变分别大12.5%、14.3%、15.2%，而峰值环向应变、起裂环向应变分别小24.2%、16.7%；峰值总能量大23.9%，储能能力Re大2.6%；声发射累计计数及累计能量分别高48.8%、106.1%，声发射b值大14.1%；通过声发射AF-RA值分析发现，两种加载控制方式对裂纹类型的影响不显著。研究结果对于深入揭示脆性岩石破裂机制具有重要意义。

摘要：In this paper, we present a design where a bunched relativistic electron beam traversing inside the rectangular dielectric-loaded （DL） waveguide is used as a high power microwave generation device. Two kinds of methods of calculating the electromagnetic （EM） field excited by a bunched beam are introduced, and in the second method the calculation of EM pulse length is discussed in detail. The desired operating mode is the LSM11 due to its strong interaction with the electron beam. For the designed 7.8 GHz operating frequency, with a 100 nC/bunch drive train of electron bunches separated by 0.769 ns, we find that high gradient （〉 30 MV/m） and high power （〉 160 MW） can be generated. An output coupler is also designed which is able to extract the generated power to standard waveguides with a 94% coupling efficiency.

摘要：A laterally diffused metal-oxide-semiconductor （LDMOS） device design with an enhanced p-well and double p-epitaxial structure is investigated for device ruggedness improvement while keeping its high device per- formance under high frequency. Based upon the device design, radio-frequency （RF） LDMOS transistors for GSM （global system for mobile communication） application have been fabricated by using 0.35/zm CMOS technolo- gies. Experimental data show that the proposed device achieves a breakdown voltage of 70 V, output power of 180 W. The RF linear gain is over 20 dB and the power added efficiency （PAE） is over 70% with the frequency of 920 MHz. In particular, it can pass the 20 ： 1 voltage standing wave ratio （VSWR） load mismatch biased at drain DC supply voltage of 32 V and output power at 10-dB gain compression point （P10dB）. The device ruggedness has been remarkably improved by using the proposed device structure.