摘要：研究温度对新型体心立方(BCC)基Fe_(3.5)Cr_(1.5)NiAl_(0.8)多组元合金(MCA)中有序椭圆状B2-NiAl纳米析出相的显微组织稳定性和力学性能的影响。采用XRD、EBSD、EPMA和TEM等检测方法对该多组元合金的显微组织和物相组成进行表征。结果表明,所设计的高含量椭圆状B2纳米析出相与BCC基体完全共格且能在1073 K高温下保持稳定,平均粒径为245.509~251.328 nm。铸态和热处理态(873 K≤T≤1073 K)合金具有独特的共格结构,这是由于低错配度的共格析出强化机制可使合金具有较高的屈服强度(809.2~1164.1 MPa)。随着热处理温度的进一步提高(1173 K≤T≤1273 K),B2纳米析出相的平均粒径逐渐粗化,载荷传递强化机制对其屈服强度提高起主要作用。

摘要：A series of shape-persistent polyphenylene dendritic C_(60)derivatives as the electron transport materials were designed and synthesized via a catalyst-free Diels-Alder[4+2]cycloaddition *** increasing hyperbranched scaffolds could effectively enhance the solubility;notably,both first and second generation dendrimers,C_(60)-G1 and C_(60)-G2,demonstrated more than 5 times higher solubilities than pristine C_(60).Furthermore,both simulated and experimental data proved their promising solution-processabilities as electron-transporting layers(ETLs)for perovskite solar *** a result,the planar p-i-n structural perovskite solar cell could achieve a maximum power conversion efficiency of 14.7%with C_(60)-G2.

摘要：With the rapid development of wearable intelligent devices,low-cost wearable strain sensors with high sensitivity and low detection limit are urgently ***,sensing stability of sensor in wet or corrosive environments should also be considered in practical ***,superhydrophobic microcracked conductive paper-based strain sensor was fabricated by coating conductive Ti_(3)C_(2)T_(x) MXene on printing paper via dip-coating process and followed by depositing superhydrophobic candle soot layer on its *** to the ultrasensitive microcrack structure in the conductive coating layer induced by the mismatch of elastic modulus and thermal expansion coefficient between conductive coating layer and paper substrate during the drying process,the prepared paper-based strain sensor exhibited a high sensitivity(gauge factor,GF=17.4)in the strain range of 0–0.6%,ultralow detection limit(0.1%strain)and good fatigue resistance over 1000 cycles towards bending ***,it was also applicable for torsion deformation detection,showing excellent torsion angle dependent,repeatable and stable sensing ***,it displayed brilliant waterproof,self-cleaning and corrosion-resistant properties due to the existence of micro/nano-structured and the low surface energy candle soot *** a result,the prepared paper-based strain sensor can effectively monitor a series of large-scale and small-scale human motions even under water environment,showing the great promising in practical harsh outdoor ***,it also demonstrated good applicability for spatial strain distribution detection of skin upon body movement when assembled into electronic-skin(E-skin).This study will provide great guidance for the design of next generation wearable strain sensor.

摘要：非稠环电子受体(NFREA)具有合成简单和结构修饰灵活的特点,是制备高性能低成本有机太阳电池(OSCs)的理想材料.本工作以不同侧链修饰的二氟苯并三氮唑(ffBTz)作为弱缺电子核(A’),分别设计合成了三种A-D-A’-D-A型NFREA,即ffBTz-BO、ffBTz-EH和ffBTz-C4.其中,ffBTz-EH,由于其合适的侧链长度,在分子结晶度和分子堆积优势取向之间取得了平衡,从而获得了更高的电荷迁移率.并且得益于高效的电荷传输和最合适的相分离形貌,基于ffBTz-EH的OSC获得12.96%的最高能量转换效率,这也是A-D-A’-D-A型NFREA获得的最高效率之一.本研究表明,A’核心上的烷基侧链在调节分子结晶度、活性层形貌和进一步调控器件性能方面起着至关重要的作用,这为未来设计高效低成本的A-D-A’-D-A型非稠环电子受体提供了思路.

摘要：钾离子电池(PIBs)面临的一个关键问题是设计具有先进结构的负极材料,以实现快速电荷传输以提高钾的存储性能.采用碳二亚胺铁(FeNCN)作为阳极,由于其含有一定数量的共价键且在分子水平上具有稳定的结构,使得储钾系统能够实现优异的电化学性能.FeNCN阳极具有高导电性,带隙接近0 eV,并且由于其共价键结构具有良好的结构稳定性.此外,无定形反应产物也为离子扩散提供了多种途径.因此,FeNCN阳极表现出高可逆比容量(在50 mA g^(-1)电流密度下具有600 mA h g^(-1)比容量),显著的倍率性能和长寿命循环(电流密度为500 mA g^(-1)时拥有400 mA h g^(-1)比容量且超过300次循环).通过理论模拟、X射线原位衍射分析和X射线光电子能谱分析揭示了Fe^(2+)和K^(+)之间的转化反应机理.此外,将FeNCN负极与苝-3,4,9,10-四羧酸二酐正极材料匹配,组装成的全电池在198.6 Wkg^(-1)的功率密度下实现了184.7 W h kg^(-1)的超高能量密度,明显高于以往所有铁基负极的PIBs或钾离子混合电容器.

摘要：Electrifying the on-board subsystems of aircraft becomes an inevitable process as being faced with the environmental pollution,along with the proposed concept called more electric aircraft(MEA).With the increasing number of on-board power electronic based devices,the distribution system of the aircraft can be regarded as an onboard *** it is known that the load power electronic converters can exhibit constant power load(CPL)characteristics and reduce the system stability,it is necessary to accurately predict and enhance the system stability in designing *** paper firstly analyzes the stability of an on-board DC microgrid with the presence of ***,discusses the reasons behind instability and proposes a control strategy to enhance system ***,the simulation results are worked out to validate the analysis and the effect of the proposed control strategy.

摘要：摩擦发光(ML)是由机械力作用在材料上引起的发光现象。近年来,金属配合物ML材料因其独特的光学发射特性而受到广泛关注,在应力传感、防伪、结构健康监测、医疗健康、结构检测等领域有着广阔的应用前景。本文综述了近年来具有摩擦发光性质的金属配合物材料的研究进展,包括镧系金属配合物和过渡金属配合物。此外,还讨论了摩擦发光的产生机制、设计原理、光物理性质及其应用前景。本综述将为构建金属配合物摩擦发光材料以及拓展其在应力传感、结构检测等方面的应用提供启发和指导。

摘要：Cu−Fe alloys with different Fe contents were prepared by vacuum hot *** hot rolling and aging treatment,the effects of Fe content on microstructure,mechanical properties and electrical conductivity of Cu−Fe alloys were *** results show that,when w(Fe)<60%,the dynamic recrystallization extent of both Cu phase and Fe phase *** w(Fe)≥60%,Cu phase is uniformly distributed into the Fe phase and the deformation of alloy is more *** the increase of the Fe content,the tensile strength of Cu−5wt.%Fe alloy increases from 305 MPa to 736 MPa of Cu−70wt.%Fe alloy,the elongation decreases from 23%to 17%and the electrical conductivity decreases from 31%IACS to 19%*** results provide a guidance for the composition and processing design of Cu−Fe alloys.

摘要：Polyurethane elastomers with covalent adaptable networks(PU-CANs)based on the dynamic urethane bond have attracted remarkable attention owing to their reprocessability,adaptability,and ***,it is still a formidable challenge to achieve excellent dynamics at low temperatures since the urethane bond energy is usually ***,a fluorinated phenolic polyurethane(FPPU)elastomer with CANs based on phenol±carbamate bonds was successfully designed and ***,the effects of fluorine atoms on the mechanical properties,thermal stability,reprocessability,and self-healability,surface free energy,and hydrophobicity of the prepared elastomers were systematically *** FPPU elastomer showed notch-insensitivity,remarkable self-healable efficiency(98%),low dynamic dissociation temperature(60℃),excellent reprocessability,and low surface energy(62 MJ m^(-2))compared with non-fluorinated counterpart phenolic polyurethane elastomer(APPU).Based on the above-mentioned features,FPPU was selected as an elastic substrate to assemble into a triboelectric nanogenerator(TENG)to harvest energy from natural *** TENG exhibited an excellent electrical output performance with a peak open-circuit voltage of 103 V,a peak short-circuit current of 4.7μA and a peak short-circuit charge of 43 *** addition,the TENG possessed high selfcleaning and reprocessing ***,a stretchable and self-healing composite conductor based on FPPU was fabricated for flexible electronic devices.

摘要：为了得到快速施工和利用新材料的预制节段桥墩设计方法，研究了部分钢筋替换为碳纤维筋时预制节段桥墩的水平承载力和破坏等级．首先通过与拟静力试验结果的比较证明了仿真分析的正确性，然后研究了部分普通钢筋替换为碳纤维筋，对拟静力循环荷载和地震地面运动分别作用时预制节段桥墩响应的影响．结果表明：碳纤维筋能提高桥墩水平承载力，增大有效刚度，降低等效粘滞阻尼比和滞回能量耗散．地震时程计算表明：部分普通钢筋替换为碳纤维筋时，使得预制节段桥墩在较强烈地震底面运动下不倒塌．利用绝对能量法分析了桥墩在地震地面运动下的能量吸收和耗散情况，并主要研究了4种桥墩试件在3种不同地震地面运动作用下的输入能量和滞回能量耗散，结果是随着桥墩输入地震能量的增大滞回能量耗散增长缓慢．