摘要：Intercalation transition metal oxides (ITMO)have attracted great attention as lithium-ion battery negative electrodes due to high operation safety,high capacity and rapid ion ***,the intrinsic low electron conductivity plagues the lifetime and cell performance of the ITMO negative *** we design a new carbon-emcoating architecture through single CO_(2)activation treatment as demonstrated by the Nb_(2)O_(5)/C *** structure engineering of the carbon-emcoating Nb_(2)O_(5)/C nanohybrid is achieved in terms of porosity,composition,and crystallographic *** carbon-embedding Nb_(2)O_(5)/C nanohybrids show superior cycling and rate performance compared with the conventional carbon coating,with reversible capacity of 387 m A h g(-1)at 0.2 C and 92%of capacity retained after 500cycles at 1 *** electrochemical mass spectrometry(DEMS) indicates that the carbon emcoated Nb_(2)O_(5)nanohybrids present less gas evolution than commercial lithium titanate oxide during *** unique carbon-emcoating technique can be universally applied to other ITMO negative electrodes to achieve high electrochemical performance.