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摘要:Untreated urea-rich wastewater exerts severeadverse impacts on both the environment and human health,prompting extensive attention towards the urea oxidationreaction (UOR) as a sustainable technology to generate cleanenergy in recent years. UOR has a thermodynamic advantageover oxygen evolution reaction (OER) (1.23 V vs reversiblehydrogen electrode, RHE) and only requires 0.37 V (vs RHE),which is considered as an effective alternative to H_(2) production by water electrolysis. However, the inevitable kineticslowness and complex adsorption/desorption during the processhinder its practical application. Most traditional catalystsutilized for the UOR are comprised of precious metals, resulting in limited economic viability. Inspired by natural ureases, Ni-based catalysts have emerged as promisingalternatives owing to their rich deposits, low cost, and theregulated d orbitals of transition metal Ni, demonstratingconsiderable potential for UOR. Currently, numerous studieshave explored Ni-based hydroxides, oxides, chalcogenides, andphosphides in alkaline solutions. In this review, we will explorethe UOR reaction mechanism and summarize the catalystdesign strategies of various Ni-based catalysts recently, especially Ni-MOF, which has been rarely discussed before. Then,the broad prospects of UOR in practical applications aresummarized. Finally, based on the design strategies and performance comparisons discussed above, the challenges andprospects facing the future development of Ni-based electrocatalysts for the UOR will be presented.
摘要:In order to assure quality and control process in the development of the aircraft collaborative design software, a maturity assessment model is proposed. The requirements designing—house of quality is designed to evaluate the maturity degree of the solution, and the evaluation results can help to manage and control the development process. Furthermore, a fuzzy evaluation method based on the minimum deviation is proposed to deal with the fuzzy information. The quantitative evaluation result of the maturity degree can be calculated by optimizing the semantic discount factor aim for the minimum deviation. Finally, this model is illustrated and analyzed by an example study of the aircraft collaborative design software.
摘要:Water electrolysis technology holds the perfect promise of the hydrogen production,yet control of efficiency and rate of water electrolysis greatly relies on the availability of high-performance electrode materials for kinetic-sluggish oxygen evolution reaction(OER).Accordingly,substantial endeavors have been made to explore advanced electrode materials over the past ***,RuO_(2) and RuO_(2)-based materials have been demonstrated to be promising for OER due to their remarkable electrocatalytic activity and pH-universal ***,the great achievements and progresses of this flourishing spot are comprehensively reviewed,which are started by a general description of OER to understand the reaction mechanism in ***,the key advantages and issues of RuO_(2) towards OER are also introduced,followed by proposing many advanced strategies for further promoting the electrocatalytic OER performance of RuO_(2).Finally,the daunting challenges and future progresses of RuO_(2) electrocatalysts toward practical water oxidation are highlighted,aiming to provide guidance for the fabrication of desirable RuO_(2)-based electrocatalysts toward OER.
摘要:The tensile properties of 2297-T87 Al–Li alloy thick plates at different thickness position and in different direction were analyzed via tensile testing,optical microscopy(OM),X-ray diffraction(XRD),scanning electron microscopy(SEM),energy dispersive spectrometry(EDS),and transmission electron microscopy(TEM).Results indicated that the ultimate tensile strength(UTS)and yield strength(YS)of the alloy decreased firstly and then increased from the 1/8T position to the 1/2T position,whereas elongation to failure(Ef)decreased gradually such that its value along the rolling direction(RD)was higher than those along the transverse direction(TD)at the same thickness *** the 1/8T position to the 3/8T position of the alloy,the UTS and YS along the TD were higher than those along the *** the 1/2T position of the alloy,the UTS,YS,and Ef along the RD were the highest,whereas those along the normal direction(ND)were the *** observations further revealed that the anisotropy of tensile properties was related to grain morphology,crystal texture,second-phase particles,and Li atom segregation.
摘要:Based on Hamiltonian energy theory, this paper proposes a robust nonlinear controller for the wind turbine with doubly fed induction generator (DFIG), such that the closed-loop system can achieve its stability. Furthermore, in the presence of disturbances, the closed-loop system is finite-gain L2 stable by the Hamiltonian controller. The Hamiltonian energy approach provides us a physical insight and gives a new way to the controller design. The simulation results illustrate that the proposed method is effective and has its advantage.
摘要:Considering the complex nonlinear relationship between the material parameters of a concrete faced rock-fill dam(CFRD) and its displacements, the harmony search(HS) algorithm is used to optimize the back propagation neural network(BPNN), and the HS-BPNN algorithm is formed and applied for the inversion analysis of the parameters of rock-fill materials. The sensitivity of the parameters in the Duncan and Chang's E-B model is analyzed using the orthogonal test design. The case study shows that the parameters φ0, K, Rf, and Kb are sensitive to the deformation of the rock-fill dam and the inversion analysis for these parameters is performed by the HS-BPNN algorithm. Compared with the traditional BPNN, the HS-BPNN algorithm exhibits the advantages of high convergence precision, fast convergence rate, and strong stability.
摘要:In this paper,a general method of data transmission system design on PXI platform is *** can be used in readout system design for physical *** aims at providing reusable and general interfaces for customized design of PXI while maintaining the transmission *** has three main features:(1)universal logic hardware interface,(2)ethernet based socket software interface,and(3)specific and simple data transmission *** transmission on PXI bus can be realized with the said two universal interfaces coordinated by this specific *** shows that this method is feasible and *** method can be easily reused in readout system designs for different experiments.
摘要:Two-dimensional covalent organic framework(COF)has distinctive properties that offer potential opportunities for developing advanced electrode *** this work,a core-shell material composed of TAPB-DMTP-COF(TAPB,1,3,5-tris(4-aminophenyl)benzene;DMTP,2,5-dimethoxyterephaldehyde)core and conducting polymer shell,TAPB-DMTP-COF@PANI,was synthesized solvothermally using a polymerization *** structural cha racteristics of the prepared composite were revealed by X-ray diffraction patterns(XRD),fourier transform infrared spectra(FTIR),X-ray photoelectron spectroscopy(XPS),transmission electron microscopy(TEM).The electrochemical analyses were verified by subsequent monitoring of trace levels of *** resultant composite not only facilitated acetaminophen to interact with absorption sites byπ-πstacking effect and hydrogen bonding but also overcame the poor conductivity of *** the optimal conditions,a low limit of detection of 0.032μmol/L and wide linear range of 0.10-500μmol/L were *** electrochemical platform was almost unaffected by other interfering substances,and successfully applied for the practical detection of acetaminophen in commercial tablet,human blood serum and *** enhanced performance makes this COF based core-shell composite a promising material in electrochemical senso r.
摘要:A new kind of two-dimensional optical orthogonal code named ESPC/OCS is constructed,which uses the extend square prime code (ESPC) for time spreading and the one-coincidence sequence(OCS) for wavelength hopping. The performance of ESPC/OCS is analyzed and the mean value of cross-correlation is deduced. Meanwhile the bit error ratio (BER) for codes is simulated and compared. The simulation results show that given p and q,the BER of ESPC/OCS is reduced,and the capacity is enlarged,when the number of hopping codes p is increased. Given OCS (given q and d),when p is changed,only the capacity is changed,but the BER is almost the same. The performance of ESPC/OCS is better than that of PC/ OCS.
摘要:We present a scheme for probabilistic transformation of special quantum states assisted by auxiliary *** our scheme,if quantum states can be rewritten in a particular form,it is possible to transform such states into other states using lowerdimensional unitary operations that can be more easily realized in physical ***,as an important application,we propose a generalized scheme that helps construct faithful quantum channels via various probabilistic channels when considering the existence of nonmaximally-entangled states.
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