摘要：Circulators play a significant role in radar and microwave communication *** paper proposes a broadband and highly efficient plasmonic circulator,which consists of spoof surface plasmon polaritons(SSPPs)waveguides and ferrite disks to support non-reciprocal mode *** simulated performance of symmetrically designed circulator shows that it has an insertion loss of roughly 0.5 dB while the isolation and return loss is more than 12 dB in the frequency range of 6.0 GHz–10.0 GHz(relative bandwidth of 50%).Equivalent circuit model has been proposed to explain the operating mechanism of the plasmonic *** equivalent circuit model,numerical simulations,and experimental results are consistent with each other,which demonstrates the good performance of the proposed plasmonic circulator.

摘要：Developing advanced technologies to address the bacterial associated infections is an urgent requirement for metallic implants and ***,we report a novel phosphonate/quaternary amine block polymer as the high-efficiency antibacterial coating for metallic *** pDEMMP-b-pTMAEMA block polymers that bearing identical phosphonate segments(repeat units of 15)but varied cationic segments(repeat units of 8,45,and 70)were precisely *** cationic polymer coatings were constructed on TC4 substrates based on the strong covalent binding between phosphonate group and metallic *** relationship between the segment chain length of the polymer coating and the antibacterial property endowed to the substrates have been established based on quantitative and qualitative *** showed that the antibacterial rate of the modified TC4 surface were 95.8%of *** and 92.9%of *** cells ***,unlike the cationic free polymer or cationic hydrogels,the surface anchored cationic polymers do compromise the viability of the attached C2C12 cells but without significant *** addition,the phosphonate/quate rnary amine block polymers can be easily constructed on titanium,stainless steel,and Ni/Cr alloy with significantly improved antibacterial property,indicating the generality of the block polymer for surface antibacterial modification of bio-metals.

摘要：In this paper,by combining a second-order sliding mode(SOSM)algorithm with the saturation technique,a novel SOSM control scheme has been *** feature of the proposed SOSM controller lies that there is a saturation function imposed on the sliding variable,which could significantly enlarge the domain of attraction for the closed-loop *** geometric method has been utilized to prove that all the sliding variables will be steered to the origin in a finite ***,the relation between the control parameters and the shape of the phase trajectory has also been ***,the proposed method has been applied to the tracking control problem for a robotic manipulator.

摘要：Novel ZrB_(2)-matrix composites were designed and prepared by in-situ introducing SiC and Zr_(2)[Al(Si)]_(4)C_(5) simultaneously for the first *** obtained composites were dense and showed good mechanical properties,especially the strength and toughness,706 MPa and 7.33 MPa·m^(1/2),respectively,coupled with high hardness of 21.3 GPa,and stiffness of 452 *** and Zr_(2)[Al(Si)]_(4)C_(5) constituted a reinforcing system with synergistic effects including grain refinement,grain pull-out as well as crack branching,bridging,and ***,the oxidation results of the composites showed that the oxidation kinetics followed the parabolic law at 1600℃,and the oxidation rate constants increased with the increase of Zr_(2)[Al(Si)]_(4)C_(5) *** formation and evolution model of the oxidation structure was also investigated,and the oxide scale of the composite exhibited a three-layer structure.

摘要：The acceleration autopilot design for skid-to-turn （STT） missile faces a great challenge owing to coupling effect among planes, variation of missile velocity and its parameters, inexistence of a complete state vector, and nonlinear aerodynamics. Moreover, the autopilot should be designed for the entire flight envelope where fast variations exist. In this paper, a design of integrated roll-pitch-yaw autopilot based on global fast terminal sliding mode control （GFTSMC） with a partial state nonlinear observer （PSNLO） for STT nonlinear time-varying missile model, is employed to address these issues. GFTSMC with a novel sliding surface is proposed to nullify the integral error and the singularity problem without application of the sign function. The proposed autopilot consisting of two-loop structure, controls STT maneuver and stabilizes the rolling with a PSNLO in order to estimate the immeasurable states as an output while its inputs are missile measurable states and control signals. The missile model considers the velocity variation, gravity effect and parameters＇ variation. Furthermore, the environmental conditions＇ dynamics are mod- eled. PSNLO stability and the closed loop system stability are studied. Finally, numerical simulation is established to evaluate the proposed autopilot performance and to compare it with existing approaches in the literature.

摘要：Increasing the local charge density of flexible side-chain cations in the hydrophilic segments of anion exchange membranes(AEMs)is helpful for improving their ***,due to limitations of structural design strategies and available synthetic methods,very few AEMs with more than four flexible side-chain cationic groups in hydrophilic segments have been *** order to further improve the hydroxide conductivity,alkaline stability and dimensional stability,herein we report a series of AEMs containing eight flexible side-chain cations in hydrophilic segments,based on poly(aryl ether sulfone)s(PAES).The synthesis,ion exchange capacity(IEC),water absorption,dimensional swelling,alkaline stability and hydroxide conductivity of the obtained membranes(PAES-8TMA-x)were examined and the relationships between structures and properties of different types of AEMs were also systematically *** resulting AEMs with IEC values of1.76–2.76 mmol g^-1 displayed comprehensively desirable properties,with hydroxide conductivities of 62.7–92.8 m S cm^-1 and dimensional swelling in the range of 8.3%to15.8%at 60℃.The IEC and hydroxide conductivity for a representative sample,PAES-8TMA-0.35,maintained 82.2%and 79.6%of the initial values after being immersed in2 mol L^-1 Na OH at 90℃ for 480 h,*** study expands the design and preparation of AEMs containing high local densities of flexible side chain cations,and provides a new strategy for new AEM materials.

摘要：In order to effectively improve the properties of anion exchange membrane(AEM)materials,a series of novel poly(aryl ether nitrile)s with flexible side-chain-type quaternary phosphonium cations(PAEN-TPP-x)were designed and prepared on the basis of considering the influences of polymer backbone,cationic group species and the connection way between the cations and polymer *** synthetic method,structure and ion-exchange capacity,water absorption,swelling,hydroxide conductivity and alkaline stability of the obtained AEMs were studied.A comparative study with other reported AEMs was also performed for further exploration of the relationship between the structure and *** AEMs with flexible side-chain-type quaternary phosphonium cations displayed good comprehensive *** water uptakes and swelling ratios were in the range of 11.6%–22.7%and 4.4%–7.8%at 60℃,*** had hydroxide conductivity in the range of 28.6–45.8 mS cm^-1 at 60℃.Moreover,these AEMs also exhibited improved alkaline stability,and the hydroxide conductivity for PAEN-TPP-0.35 could remain 82.1%and 80.6%of its initial value at 60 and 90℃in 2 mol L^-1 NaOH solution for480 h,respectively.

摘要：Layered lithium manganese-rich oxides are promising cathode materials for lithium-ion batteries(LIBs),due to the low-cost,abundant manganese source,and large theoretical ***,these layered lithium manganese-rich oxides,e.g.,monoclinic-LiMn0_(2),suffer from poor cycle performance and rate performance because of fast structural degradation with the irreversible layered-to-spinel phase transition and sluggish electrode kinetics during cycling[1,2].

摘要：高体积分数SiC_p/Al复合材料作为电子封装材料使用日益流行,其钎焊具有重要的实际意义。近来,一些新钎料合金和工艺被开发用于高体积分数SiC_p/Al复合材料的钎焊。本文回顾了SiC_p/Al复合材料的物理力学性能和制备工艺,综述了应用于高体积分数SiC_p/Al复合材料的合金钎料、钎焊工艺及其接头微结构与性能,旨在进一步理解它们之间的关联性,以优化接头性能与可靠性。往Al-Si合金中添加Cu、Mg、Ni等合金元素有助于提高钎料合金和钎焊接头的使用性能,如可优化钎料合金的应用温度、接头界面结合和焊缝强度。而表面金属化和超声波振动两种钎焊辅助工艺可通过避免或去除复合材料表面的Al_2O_3和SiO_2氧化膜来改善合金钎料的钎焊性。最后指出,需要进一步加强对合金钎料的优化设计、表面金属化工艺以及焊料/涂层/基材体系之间的润湿性和界面行为的研究。

摘要：单原子位点催化剂(SSCs)由于能够产生丰富的活性物质来清除类芬顿体系中的污染物,而显示出广阔的潜力.然而,在高级氧化工艺中,实现金属原子100%的利用率和减少金属浸出以满足环境安全标准是困难的.在此基础上,利用强极化力获得了Co原子含量极低(~0.17%)的催化剂,提高了金属原子利用率,降低了抗生素消除过程中金属浸出的风险.正如预期,该催化剂具有有限的Co位点,伴随着丰富的缺陷和大量从大孔到中孔再到微孔分布的骨架,实现了快速的四环素降解(0.07133 min^(−1))和优异的归一化速率常数(k per-site,2.4726×10^(5) min^(−1) M^(−1)).实验和理论结果均表明,充分暴露具有丰富C-N缺陷的Co位点,可以提高Co活性位点的电子密度,降低过硫酸盐(PDS)的吸附能,从而优化Co原子对PDS活化的利用.该研究为设计高性能、环境友好的水修复用SSCs提供了有价值的见解.