摘要：Increasing attention has been paid to develop flexible integrated energy devices, but it remains a big challenge to achieve a common electrode for building both energy conversion and storage devices with high performance. Here, we for the first time selectively functionalize polyaniline(PANI) and platinum(Pt)inside different segments of chemical vapor deposition grown continuous graphene tube, achieving selectively functionalized graphene composite(PANI//Pt@G) fibers. The PANI@G and Pt@G parts could be used as efficient electrodes for supercapacitor with a specific capacitance of 284 m F cm-2 and dye-sensitized solar cell with a power conversion efficiency of 4.73%, respectively. By using a PANI//Pt@G fiber as the common electrode, an integrated energy device with a total energy conversion and storage efficiency of 3.07% is realized. The continuous graphene tubes could be functionalized with other active materials for other flexible and wearable electronics.

摘要：natural anisotropic nanostructures occurring in several organisms have gained more and more attention because of their obvious advantages in sensitivity, stability, security, miniaturization, portability, online use, and remote monitoring. Due to the development of research on nature-inspired bionic structures and the demand for highly efficient, low-cost microfabrication techniques, an understanding of and the ability to replicate the mechanism of structural coloration have become increasingly significant. These sophisticated structures have many unique functions and are used in many applications. Many sensors have been proposed based on their novel structures and unique optical properties. Several of these bio-inspired sensors have been used for infrared radiation/thermal, pH, and vapor techniques, among others, and have been discussed in detail, with an intense focus on several biomedical applications. However, many applications have yet to be discovered. In this review, we will describe these nanostructured materials based on their sources in nature and various structures, such as layered, hierarchical, and helical structures. In addition, we discuss the functions endowed by these structures, such as superhydrophobicity, adhesion, and high strength, enabling them to be employed in a number of applications in biomedical fields, including cell cultivation, biosensors, and tissue engineering.

摘要：With the development of technology,the learning and memory functions of artificial memristor synapses are necessary for realizing artificial neural networks and neural neuromorphic *** to their high scalability performance,nanosheet materials have been widely employed in cellular-level learning,but the behaviors of nociceptor based on nanosheet materials have rarely been ***,we present a memristor with an Al/TiO_(2)/Pt *** electroforming,the memristor device showed a gradual conductance regulation and could simulate synaptic functions such as the potentiation and depression of synaptic *** also designed a new scheme that verifies the pain sensitization,desensitization,allodynia,and hyperalgesia behaviors of real nociceptors in the fabricated *** with these behaviors can significantly improve the quality of intelligent electronic *** fitting showed that the high resistance and low resistance states were consistent with the hopping conduction *** work promises the application of TiO_(2)-based devices in next-generation neuromorphological systems.

摘要：针对两节独立反相集总电极聚合物Y型耦合器电光开关响应速度慢的问题,通过对该器件两节电光区的波导进行推挽极化,设计了一种无偏置行波电极高速电光开关.为了获得低的驱动电压、良好的阻抗匹配和光波与微波间较小的折射率失配,对电极参数做了设计和优化.通过对施加的方波开关信号做傅里叶变换并结合行波传输线理论,给出了一种用于建模和表征器件高频响应的解析分析法.对该器件的数值计算结果表明,在1 550nm中心工作波长下,其3dB状态电压为0 V,开关电压为2.68V,上分支状态电压和下分支状态电压分别为-1.34V和＋1.34V,器件的插入损耗和串扰分别小于3.55和-30dB,10%~90%上升时间和下降时间均为3.90ps,截止开关频率可达128.2GHz.

摘要：Sodium ions(Na+) and ether electrolyte coinserted graphite possesses a considerable volume expansion effect. However, the mechanism fails to clearly explain its stability. In response to this deficiency, the co-inserted reaction is proposed, which is affected by the Lorentz force of the applied electric field under the high-current condition. The Na^(+) ions are separated out, while the ethylene glycol dimethyl ether molecules remain between the graphite layers. This insight provides a reasonable explanation for the extraordinary stability of this material. In situ X-ray diffraction and density functional theory calculations confirm the separation and release of Na+. On the basis of this result, unmodified commercial graphite was stably cycled 6400 times at a current density of up to 10 A g^(-1), and the capacity retention rate was as high as 97.2%. The full battery assembled in the laboratory has a maximum output power of 14,846 W kg^(-1)and an output energy density of 103 W h kg^(-1)(relative to the weight of anodic and cathodic active materials). The new mechanism provides innovative ideas for the design of large-scale energy storage devices.

摘要：TiO_(2)is the dominant and most widely researched photocatalyst for environmental remediation,however,the drawbacks,such as only responding to UV light(<5%of sunlight),low charge separation efficiency,and difficulties in recycling,have severely hindered its practical ***,we synthesized magnetically separable Fe_(3)O_(4)@MoS_(2)@mesoporous TiO_(2)(FMmT)photocatalysts via a simple,green,and template-free solvothermal method combined with ultrasonic *** is found that FMmT possesses a high specific surface area(55.09 m2·g−1),enhanced visible-light responsiveness(~521 nm),and remarkable photogenerated charge separation *** addition,the photocatalytic degradation efficiencies of FMmT for methylene blue(MB),rhodamine B(RhB),and tetracycline(TC)are 99.4%,98.5%,and 89.3%within 300 min,*** corresponding degradation rates are 4.5,4.3,and 3.1 times higher than those of pure TiO_(2)*** to the high saturation magnetization(43.1 A·m^(2)·kg^(−1)),FMmT can achieve effective recycling with an applied magnetic *** improved photocatalytic activity is closely related to the effective transport of photogenerated electrons by the active interlayer MoS_(2) and the electron–hole separation caused by the MoS_(2)@TiO_(2)***,the excellent light-harvesting ability and abundant reactive sites of the mesoporous TiO_(2)shell further boost the photocatalytic efficiency of *** work provides a new approach and some experimental basis for the design and performance improvement of magnetic photocatalysts by innovatively incorporating MoS2 as the active interlayer and integrating it with a mesoporous shell.

摘要：基于纳米多晶硅薄膜电阻的多功能传感器由压力传感器和加速度传感器构成。纳米多晶硅薄膜电阻构成的两个惠斯通电桥结构分别设计在方形硅膜表面和悬臂梁根部。采用MEMS技术和CMOS工艺在〈100〉晶向单晶硅片上实现压力/加速度传感器芯片制作,利用内引线技术将芯片封装在一个印刷电路板(PCB)上。在室温下,工作电压为5.0V时,实验结果给出压力传感器灵敏度(a=0)为1.0mV/kPa,加速度传感器灵敏度(p=0)为0.92mV/g,可实现外加压力和加速度的测量,具有较好的灵敏度特性且交叉干扰较弱。

摘要：利用两组串联五环谐振器以及它们与两信道波导的交叉耦合作用,优化设计并模拟了一种超低串扰2×2新型聚合物电光开关.为了表征器件的输出光功率特性,给出了器件结构、分析理论和相关公式.为了在下行端口(drop端口)得到箱型光谱响应以及极低的串扰和插入损耗,优化了微环谐振级数和耦合间距.对器件输出光功率和输出光谱的模拟分析结果显示,器件交叉和直通态间的切换电压为4V,交叉和直通态下两端口间的串扰分别为-66dB和-54.7dB,插入损耗分别为2.34dB和0.24dB.在1GHz方波信号作用下,器件drop端口的上升和下降时间分别为15ps和90ps.由于聚合物微环的弯曲半径仅为19.45μm,因此该器件具有超紧凑的尺寸,其长度和宽度仅为0.407mm,约为马赫-曾德尔干涉仪或者定向耦合器等一般结构聚合物电光开关长度的1/10.依赖于小的封装尺寸和极低的串扰,该器件可以高密度地集成在光电子芯片上,在光片上网络中光信号的控制方面具有潜在的应用.

摘要：设计并制备三种具不同官能团的铱[III]邻菲啰啉配合物:[Ir(ppy)2phen-Br]Cl,[Ir(ppy)2phen-COOH]Cl,[Ir(ppy)2phen-Si]Cl,以及对比参照物[Ir(ppy)2phen-NH2]Cl.其中,ppy为2-苯基吡啶,phen-Br为2-溴-2甲基-N-(1,10-菲啰啉-5-基)丙酰胺,phen-COOH为4-[(1,10-菲啰啉-5-基)氨基]-4-酰基丁烯酸,phen-Si为5-[N,N-二-3-(三乙氧硅)基]酰亚胺-1,10-菲啰啉,phen-NH2为5-氨基-邻菲啰啉,并采用核磁共振(NMR)、质谱(MS)、紫外-可见(UV-Vis)吸收光谱、荧光(PL)光谱法和循环伏安法(CV)等对上述配合物进行了分析和表征.光物理性能研究结果表明:这些配合物在蓝-紫色可见光区域有较强吸收,可发射出明亮的黄色到橙红色荧光,量子效率达到12%以上.相比较于参照物[Ir(ppy)2phen-NH2]Cl(5.78μs),三种新型配合物在量子效率未明显降低甚至提高的前提下,荧光寿命有了显著的提高(9.18–12.00μs).其中,[Ir(ppy)2phen-Br]Cl(1)不但有最高的荧光量子产率(32%)和最长的荧光寿命(12.00μs),而且也具有最好的氧传感性能,I0/I(无氧与纯氧条件下的荧光强度比值)可达到10.91.这使得[Ir(ppy)2phen-Br]Cl有望成为接枝型,较高性能的光学氧传感器的候选氧敏指示剂.除此之外,还通过含时密度泛函理论(TD-DFT)计算对配合物光电性能进行补充说明,理论计算表明:这些配合物是以铱为中心的近似八面体结构,理论计算结果与实际实验数据相一致.

摘要：为了寻找结构新颖的活性分子,采用活性亚结构拼接的方法,设计合成了24个未见文献报道的取代查尔酮-哌嗪衍生物,其结构经~1H NMR、^(13)C NMR和HRMS确证.分别采用小鼠巨噬细胞Raw 264.7炎症模型和噻唑蓝(MTT)法对目标化合物的体外抗炎活性和细胞毒活性进行测试,结果表明,查尔酮母核和哌嗪环上的取代基对化合物的生物活性有明显影响.特别是3,4,5-三甲氧基-4'-[N-(2-氧代丙基)-1-哌嗪基]查尔酮(11)能有效抑制NO的生成(IC50=3.81μmol/L),4-溴-4'-[N-(4'-甲基-2-氧代苯乙基)-1-哌嗪基]查尔酮(25)对三种肿瘤细胞株(Hela,A549和sk-ov-3)均表现出良好的体外细胞毒活性(IC50值分别为0.54,0.05和9.12μmol/L).